Dioctyl Phthalate Esters Wastewater Treatment by Fenton Reagent / Fly Ash Combined Process

2013 ◽  
Vol 777 ◽  
pp. 122-126
Author(s):  
Li Ping Wang ◽  
Xin Ying Li ◽  
Xiang Mei Li
Keyword(s):  
Fly Ash ◽  
Removal Efficiency ◽  
Phthalate Esters ◽  
Dioctyl Phthalate ◽  
Cod Removal ◽  
Fenton Reagent ◽  
Combined Process ◽  
Cod Removal Efficiency ◽  
Simulated Wastewater ◽  
Better Than

Used Fenton reagent and fly ash combined process to treat dioctyl phthalate (DOP) simulated wastewater. Influences of pH, concentration of H2O2, Fe2+ concentration, fly ash dosage and other factors effect of COD were studied. The results showed that, under the synergies of the fly ash, Fenton reagent on the COD removal efficiency was better than Fenton reagent used alone. When the pH was 5, H2O2 concentration was 1.2 g/L, Fe2+ concentration was 1.0g/L, fly ash dosage was 4 g, and COD removal efficiency reached 83.21%.

Textile Wastewater Treatment Using Combined Process of Biological Wriggle Bed and Ozone Biological Aerated Filter

2012 ◽  
Vol 441 ◽  
pp. 589-592
Author(s):  
Zhi Min Fu ◽  
Yu Gao Zhang ◽  
Xiao Jun Wang
Keyword(s):  
Wastewater Treatment ◽  
Removal Efficiency ◽  
Textile Wastewater ◽  
Cod Removal ◽  
Biological Aerated Filter ◽  
Combined Process ◽  
Cod Removal Efficiency ◽  
Aerated Filter ◽  
Textile Wastewater Treatment

A combined process of biological wriggle bed and ozone biological aerated filter was utilized to treat textile wastewater. Results showed that COD removal efficiency was almost 90.4%. The average effluent COD was 85.87 mg/L. The effluent colority was 64-32 times. This study indicated that the combined process is potentially useful for treating textile wastewater.

scholarly journals Treatment of oilfield wastewater by combined process of micro-electrolysis, Fenton oxidation and coagulation

2017 ◽  
Vol 76 (12) ◽  
pp. 3278-3288 ◽  
Author(s):  
Zhenchao Zhang
Keyword(s):  
Reaction Time ◽  
Removal Efficiency ◽  
Treatment Process ◽  
Cod Removal ◽  
Fenton Oxidation ◽  
Oily Wastewater ◽  
Optimum Conditions ◽  
Combined Process ◽  
Cod Removal Efficiency ◽  
Optimized Conditions

Abstract In this study, a combined process was developed that included micro-electrolysis, Fenton oxidation and coagulation to treat oilfield fracturing wastewater. Micro-electrolysis and Fenton oxidation were applied to reduce chemical oxygen demand (COD) organic load and to enhance organic components gradability, respectively. Orthogonal experiment were employed to investigate the influence factors of micro-electrolysis and Fenton oxidation on COD removal efficiency. For micro-electrolysis, the optimum conditions were: pH, 3; iron-carbon dosage, 50 mg/L; mass ratio of iron-carbon, 2:3; reaction time, 60 min. For Fenton oxidation, a total reaction time of 90 min, a H2O2 dosage of 12 mg/L, with a H2O2/Fe2+ mole ratio of 30, pH of 3 were selected to achieve optimum oxidation. The optimum conditions in coagulation process: pH, cationic polyacrylamide dosage, mixing speed and time is 4.3, 2 mg/L, 150 rpm and 30 s, respectively. In the continuous treatment process under optimized conditions, the COD of oily wastewater fell 56.95%, 46.23%, 30.67%, respectively, from last stage and the total COD removal efficiency reached 83.94% (from 4,314 to 693 mg/L). In the overall treatment process under optimized conditions, the COD of oily wastewater was reduced from 4,314 to 637 mg/L, and the COD removal efficiency reached 85.23%. The contribution of each stage is 68.45% (micro-electrolysis), 24.07% (Fenton oxidation), 7.48% (coagulation), respectively. Micro-electrolysis is the uppermost influencing process on COD removal. Compared with the COD removal efficiency of three processes on raw wastewater under optimized conditions: the COD removal efficiency of single micro-electrolysis, single Fenton oxidation, single coagulation is 58.34%, 44.88% and 39.72%, respectively. Experiments proved the effect of combined process is marvelous and the overall water quality of the final effluent could meet the class III national wastewater discharge standard of petrochemical industry of China (GB8978-1996).

scholarly journals Study of the Effect of Activated Carbon Cathode Configuration on the Performance of a Membrane-Less Microbial Fuel Cell

Catalysts ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 619
Author(s):  
M. L. Jiménez González ◽  
Carlos Hernández Benítez ◽  
Zabdiel Abisai Juarez ◽  
Evelyn Zamudio Pérez ◽  
Víctor Ángel Ramírez Coutiño ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Removal Efficiency ◽  
Internal Resistance ◽  
Cod Removal ◽  
The Other ◽  
Cod Removal Efficiency ◽  
Water Recirculation ◽  
Better Than

In this paper, the effect of cathode configuration on the performance of a membrane-less microbial fuel cell (MFC) was evaluated using three different arrangements: an activated carbon bed exposed to air (MFCE), a wetland immersed in an activated carbon bed (MFCW) and a cathode connected to an aeration tower featuring a water recirculation device (MFCT). To evaluate the MFC performance, the efficiency of the organic matter removal, the generated voltage, the power density and the internal resistance of the systems were properly assessed. The experimental results showed that while the COD removal efficiency was in all cases over 60% (after 40 days), the MFCT arrangement showed the best performance since the average removal value was 82%, compared to close to 70% for MFCE and MFCW. Statistical analysis of the COD removal efficiency confirmed that the performance of MCFT is substantially better than that of MFCE and MFCW. In regard to the other parameters surveyed, no significant influence of the different cathode arrangements explored could be found.

Study of Printing and Dyeing Wastewater Treatment by Membrane Bioreactor Enhanced by Bio-Ferric

2011 ◽  
Vol 183-185 ◽  
pp. 1456-1461 ◽  
Author(s):  
Shi Feng Ji ◽  
Chun Mei Gao ◽  
Hong Yang ◽  
Ming Chu ◽  
Chun Feng Wang
Keyword(s):  
Removal Efficiency ◽  
Membrane Bioreactor ◽  
Ferric Hydroxide ◽  
Cod Removal ◽  
Printing And Dyeing Wastewater ◽  
Sludge Flocs ◽  
Cod Removal Efficiency ◽  
N Removal ◽  
Sludge Minimization ◽  
Better Than

Bio-ferric membrane bioreactor(MBR) was made through adding ferric hydroxide to traditional MBR and forming bio-ferric sludge. Through analyzing treatment efficiency of dyeing and printing wastewater in bio-ferric MBR and traditional MBR respectively, the results showed: COD removal efficiency in bio-ferric MBR was more better than that in traditional MBR which increased 10% or so, but the influence of HRT on COD removal efficiency wasn’t evident; Via changing SRT, it was obtained: bio-ferric MBR could operate in longer SRT while treatment effect couldn’t be impacted that could discharge less sludge than traditional MBR which coule get sludge minimization; bio-ferric sludge flocs could provide better survival environment for nitrobacteria that made NH3-N removal efficiency stable. The experiment illuminated: the biochemical and physical function of bio-ferric sludge could strengthen the holistic stability of the system.

Treatment Textiles Wastewater Using Anoxic Filter Bed and Biological Wriggle Bed-Ozone Biological Aerated Filter

2012 ◽  
Vol 518-523 ◽  
pp. 2961-2964
Author(s):  
Zhi Min Fu ◽  
Yu Gao Zhang ◽  
Xiao Jun Wang
Keyword(s):  
Removal Efficiency ◽  
Textile Wastewater ◽  
Cod Removal ◽  
Organic Polymer ◽  
Biological Aerated Filter ◽  
Polymer Carrier ◽  
Cod Removal Efficiency ◽  
Aerated Filter ◽  
Filter Bed ◽  
Better Than

Organic polymer carrier was utilized to treat textile wastewater. Results showed that COD removal efficiency was almost 82.8%. The average effluent COD concentration was 132.6 mg/L. The effluent colority was about 200 times. Experiment indicated that ceramic granular carrier was better than polymer carrier when ultlized to treat textil wastewater.

Remediation of Contaminated Surface Water by Permeable Reactive Barriers (PRBs): Lab-Scale Experiments with Four Industrial Wastes as Reactive Media

2013 ◽  
Vol 295-298 ◽  
pp. 1850-1854
Author(s):  
Li Cui ◽  
Rui Gao ◽  
Fang Qin Cheng ◽  
Jian Feng Li ◽  
Xu Ming Wang
Keyword(s):  
Fly Ash ◽  
Removal Efficiency ◽  
Steel Slag ◽  
Cod Removal ◽  
Permeable Reactive Barriers ◽  
Industrial Wastes ◽  
Column Tests ◽  
Cod Removal Efficiency ◽  
Initial Ph ◽  
Reactive Media

Four industrial wastes: iron scraps, ceramsite, fly ash and steel slag were studied as reactive media for COD removal from the Fenhe River. Leaching tests demonstrated that iron scraps and ceramsite were relatively stable compared to steel slag and fly ash. Ca2+ was the main leaching ion. Batch experiment results showed that iron scraps and steel slag had better COD removal efficiency than ceramsite and fly ash. It was also found that the initial pH was important for COD removal and the COD removal efficiency of iron scraps was linearly correlated with the initial pH (R2=0.982). Compared to batch experiments, COD removal was much higher in column tests, which were about 70%, 54%, 46% for iron scraps, steel slag and ceramsite respectively.

Enhanced COD Removal Efficiency by Using an Electro-Shocking Biofilm

2014 ◽  
Vol 1073-1076 ◽  
pp. 693-695
Author(s):  
Zhen Wei Ni ◽  
Yin Mei Wang ◽  
Wen Ping Cao
Keyword(s):  
Removal Efficiency ◽  
Direct Current ◽  
Removal Rate ◽  
Cod Removal ◽  
Experimental Results ◽  
Biofilm Reactors ◽  
Cod Removal Efficiency ◽  
Simulated Wastewater

Two parallel biofilm reactors were developed and applied for treating the simulated wastewater. The experimental results showed that compared with a without electric-shocking biofilm, and a mean removal rate of COD increased by 18.82% by shocking of direct current. Which suggested that the electro-shocking can significantly increase the removal rate of COD.

scholarly journals Investigation of Heavy Metal Effects on the Anaerobic Co-Digestion Process of Waste Activated Sludge and Septic Tank Sludge

2019 ◽  
Vol 2019 ◽  
pp. 1-9
Author(s):  
Quang-Minh Nguyen ◽  
Duy-Cam Bui ◽  
Thao Phuong ◽  
Van-Huong Doan ◽  
Thi-Nham Nguyen ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Activated Sludge ◽  
Removal Efficiency ◽  
Biogas Production ◽  
Cod Removal ◽  
Septic Tank ◽  
Waste Activated Sludge ◽  
Digestion Process ◽  
Cod Removal Efficiency

The effect of copper, zinc, chromium, and lead on the anaerobic co-digestion of waste activated sludge and septic tank sludge in Hanoi was studied in the fermentation tests by investigating the substrate degradation, biogas production, and process stability at the mesophilic fermentation. The tested heavy metals were in a range of concentrations between 19 and 80 ppm. After the anaerobic tests, the TS, VS, and COD removal efficiency was 4.12%, 9.01%, and 23.78% for the Cu(II) added sample. Similarly, the efficiencies of the Zn(II) sample were 1.71%, 13.87%, and 16.1% and Cr(VI) efficiencies were 15.28%, 6.6%, and 18.65%, while the TS, VS, and COD removal efficiency of the Pb(II) added sample was recorded at 16.1%, 17.66%, and 16.03% at the concentration of 80 ppm, respectively. Therefore, the biogas yield also decreased by 36.33%, 31.64%, 31.64%, and 30.60% for Cu(II), Zn(II), Cr(VI), and Pb(II) at the concentration of 80 ppm, compared to the raw sample, respectively. These results indicated that Cu(II) had more inhibiting effect on the anaerobic digestion of the sludge mixture than Zn(II), Cr(VI), and Pb(II). The relative toxicity of these heavy metals to the co-digestion process was as follows: Cu (the most toxic) > Zn > Cr > Pb (the least toxic). The anaerobic co-digestion process was inhibited at high heavy metal concentration, which resulted in decreased removal of organic substances and produced biogas.

scholarly journals Combined treatment of hydroxypropyl guar gum in oilfield fracturing wastewater by coagulation and the UV/H2O2/ferrioxalate complexes process

2017 ◽  
Vol 77 (3) ◽  
pp. 565-575 ◽  
Author(s):  
Zhenchao Zhang
Keyword(s):  
Removal Efficiency ◽  
Guar Gum ◽  
Combined Treatment ◽  
Cod Removal ◽  
Treated Wastewater ◽  
Spectra Analysis ◽  
Hydroxypropyl Guar ◽  
Coagulation Process ◽  
Cod Removal Efficiency ◽  
Hydroxypropyl Guar Gum

Abstract Hydroxypropyl guar gum is considered to be a main component of oilfield fracturing wastewater (OFW). This work is intended to optimize the experimental conditions for the maximum oxidative degradation of hydroxypropyl guar gum by the coagulation and UV/H2O2/ferrioxalate complexes process. Optimal reaction conditions were proposed based on the chemical oxygen demand (COD) removal efficiency and UV_vis spectra analysis. The overall removal efficiency of COD reached 83.8% for a dilution ratio of raw wastewater of 1:2, pH of 4 and FeCl3 loading of 1,000 mg/L in the coagulation process; the dosage of H2O2 (30%,v/v) was 0.6% (v/v) and added in three steps, the n(H2O2)/n(Fe2+) was 2:1, n(Fe2+)/n(C2O42−) was 3:1 and pH was 4 in the UV/H2O2/ferrioxalate complexes process; pH was adjusted to 8.5–9 by NaOH and then cationic polyacrylamide (CPAM) of 2 mg/L was added in the neutralization and flocculation process. The decrease in COD during the coagulation process reduced the required H2O2 dosage and improved efficiency in the subsequent UV/H2O2/ferrioxalate complexes process. Furthermore, COD removal efficiency significantly increased by more than 13.4% with the introduction of oxalate compared with UV/Fenton. The UV_vis spectra analysis results indicated that the coagulation and UV/H2O2/ferrioxalate complexes process could efficiently remove the hydroxypropyl guar gum dissolved in OFW. An optimal combination of these parameters produced treated wastewater that met the GB8978-1996 Integrated Wastewater Discharge Standard level III emission standard.

Electrocoagulation and nanofiltration integrated process application in purification of bilge water using response surface methodology

2016 ◽  
Vol 74 (3) ◽  
pp. 564-579 ◽  
Author(s):  
Ceyhun Akarsu ◽  
Yasin Ozay ◽  
Nadir Dizge ◽  
H. Elif Gulsen ◽  
Hasan Ates ◽  
...  
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Removal Efficiency ◽  
Cod Removal ◽  
Positive Sign ◽  
Aluminum Electrode ◽  
Integrated Process ◽  
Bilge Water ◽  
Cod Removal Efficiency ◽  
Initial Ph

Marine pollution has been considered an increasing problem because of the increase in sea transportation day by day. Therefore, a large volume of bilge water which contains petroleum, oil and hydrocarbons in high concentrations is generated from all types of ships. In this study, treatment of bilge water by electrocoagulation/electroflotation and nanofiltration integrated process is investigated as a function of voltage, time, and initial pH with aluminum electrode as both anode and cathode. Moreover, a commercial NF270 flat-sheet membrane was also used for further purification. Box–Behnken design combined with response surface methodology was used to study the response pattern and determine the optimum conditions for maximum chemical oxygen demand (COD) removal and minimum metal ion contents of bilge water. Three independent variables, namely voltage (5–15 V), initial pH (4.5–8.0) and time (30–90 min) were transformed to coded values. The COD removal percent, UV absorbance at 254 nm, pH value (after treatment), and concentration of metal ions (Ti, As, Cu, Cr, Zn, Sr, Mo) were obtained as responses. Analysis of variance results showed that all the models were significant except for Zn (P > 0.05), because the calculated F values for these models were less than the critical F value for the considered probability (P = 0.05). The obtained R2 and Radj2 values signified the correlation between the experimental data and predicted responses: except for the model of Zn concentration after treatment, the high R2 values showed the goodness of fit of the model. While the increase in the applied voltage showed negative effects, the increases in time and pH showed a positive effect on COD removal efficiency; also the most effective linear term was found as time. A positive sign of the interactive coefficients of the voltage–time and pH–time systems indicated synergistic effect on COD removal efficiency, whereas interaction between voltage and pH showed an antagonistic effect.

Sign in / Sign up

Export Citation Format

Share Document