Synthesis and Characterization of Ni-Doped ZnO Nanorods Prepared by Hydrothermal Method

2013 ◽  
Vol 785-786 ◽  
pp. 582-585
Author(s):  
Zhi Qiang Wei ◽  
Xiao Juan Wu ◽  
Ling Ling Zhang ◽  
Wang Jun Feng ◽  
Hua Yang
Keyword(s):  
Hydrothermal Method ◽  
Diluted Magnetic Semiconductors ◽  
Magnetic Semiconductors ◽  
Hexagonal Phase ◽  
Zno Nanorods ◽  
X Ray ◽  
Transmission Electron ◽  
Doped Zno ◽  
Diluted Magnetic ◽  
Constituent Elements

Ni-doped ZnO diluted magnetic semiconductors nanorods were successfully synthesized by hydrothermal method. The crystal structure, morphology, constituent elements and optical proprety of the products using this method were investigated via X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray energy dispersive spectrometry (XEDS) and ultraviolet-visible spectroscopy (UV-vis). The experiment results show that the morphology of samples were nanorods with good dispersion, all the diffraction peaks correspond to the wurtzite structure hexagonal phase, no other impurity phase appeare, and the Ni2+ions successfully substituted for the lattice site and generate single-phase Zn1-xNixO. The band gap increases firstly and reduces afterward with the increase of Ni2+contents.

Effects of Fe Doping on the Crystal Structures and Photoluminescence of ZnO Nanorods

2014 ◽  
Vol 636 ◽  
pp. 105-109
Author(s):  
Chun Ping Li ◽  
Hao Ran Ba ◽  
Kun Jin
Keyword(s):  
Diluted Magnetic Semiconductors ◽  
Magnetic Semiconductors ◽  
Zno Nanorods ◽  
Synthesis Method ◽  
Wet Chemical Synthesis ◽  
Transmission Electron ◽  
Doped Zno ◽  
Diluted Magnetic ◽  
Morphology Characterization ◽  
Induced Defects

The 5% Fe-doped ZnO nanorods (Zn0.95Fe0.05O) were prepared successfully by the wet-chemical synthesis method. Structure and morphology characterization were demonstrated by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Laser power dependent photoluminescence (PL) spectra were measured to study the electronic structures of the Fe-doped ZnO-based diluted magnetic semiconductors. The contraction of lattice constant and structured green-yellow-red emissions were analyzed. Such investigations confirmed that the induced defects or impurities originating from Fe ions.

Diluted magnetic semiconductors: Mn/Co-doped ZnO nanorods as case study

2008 ◽  
Vol 18 (43) ◽  
pp. 5208 ◽  
Author(s):  
Igor Djerdj ◽  
Georg Garnweitner ◽  
Denis Arčon ◽  
Matej Pregelj ◽  
Zvonko Jagličić ◽  
...  
Keyword(s):  
Diluted Magnetic Semiconductors ◽  
Magnetic Semiconductors ◽  
Zno Nanorods ◽  
Doped Zno ◽  
Diluted Magnetic ◽  
Co Doped

scholarly journals Optical and Magnetic Properties of Ni Doped ZnS Diluted Magnetic Semiconductors Synthesized by Hydrothermal Method

2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Meirong Wu ◽  
Zhiqiang Wei ◽  
Wenhua Zhao ◽  
Xuan Wang ◽  
Jinlong Jiang
Keyword(s):  
Magnetic Properties ◽  
Hydrothermal Method ◽  
Diluted Magnetic Semiconductors ◽  
Magnetic Semiconductors ◽  
Blue Emission ◽  
Photoluminescence Spectra ◽  
Blue Emission Band ◽  
X Ray ◽  
Optical And Magnetic Properties ◽  
Diluted Magnetic

Diluted magnetic semiconductors Zn1-xNixS with different consistency ratio (x = 0, 0.01, 0.03, 0.05, and 0.07) were successfully synthesized by hydrothermal method using ethylenediamine as a modifier. The influence of Ni doping concentration on the microstructure, morphology, and optical and magnetic properties of undoped and Ni doped ZnS nanocrystals was characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), X-ray energy dispersive spectrometry (XEDS), ultraviolet-visible spectroscopy (UV-vis), Fourier transform infrared spectroscopy (FT-IR), photoluminescence spectra (PL), and the vibrating sample magnetometer (VSM), respectively. The experiment results show the substitution of Ni2+ on Zn2+ sites without changing the hexagonal wurtzite structure of ZnS and generate single-phase Zn1-xNixS with good crystallization. The lattice constant causes distortion and decreases with the increase of Ni2+ doped concentration. The appearance of the samples is one-dimensional well-dispersed nanorods. UV-vis spectra reveal the band gap of all Zn1-xNixS samples greater than that of bulk ZnS (3.67 eV), and blue shift phenomenon occurs. The photoluminescence spectra of undoped and doped samples possess the broad blue emission band in the range of 400–650 nm; the PL intensities of Zn1-xNixS nanorods increase with the increase of Ni content comparing to pure ZnS and reach maximum for x = 0.03. Magnetic measurements indicated that the undoped ZnS samples are superparamagnetic, whereas the doped samples exhibit ferromagnetism.

Zn0.9Co0.1O/ MCM-41 Composite: Synthesis and Magnetism

2011 ◽  
Vol 266 ◽  
pp. 80-83
Author(s):  
W. B. Liu ◽  
Ying Tang Zhang ◽  
X. X. Li ◽  
S. X. Liu ◽  
Z. Y. Chen ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Diluted Magnetic Semiconductors ◽  
Pore Diameter ◽  
Magnetic Semiconductors ◽  
Sol Gel ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Diluted Magnetic ◽  
Mcm 41

Cobalt doped zinc oxide diluted magnetic semiconductors (DMSs) were assembled in MCM-41 template by sol-gel method. Samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), physisorption, as well as the magnetism measurement. It was found that the wurtzite symmetry of the MCM-41 pores was not changed while the pore diameter became smaller after the DMSs deposited into the pores. The Zn0.9Co0.1O-MCM-41 presents a superparamagnetic behavior between 80K and 300K, while Zn0.9TM0.1O-MCM-41 (TM=Mn, Fe, Ni) samples are paramagnetic at the same temperature range.

Ferromagnetism and Luminescence of Diluted Magnetic Semiconductors GaGdN and AlGdN

2008 ◽  
Vol 1111 ◽  
Author(s):  
Shuichi Emura ◽  
Masahiro Takahashi ◽  
Hiroyuki Tambo ◽  
Akira Suzuki ◽  
Tetsuya Nakamura ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Diluted Magnetic Semiconductors ◽  
Magnetic Semiconductors ◽  
Magnetic Circular Dichroism ◽  
Peak Position ◽  
Magnetic Characteristics ◽  
Sharp Line ◽  
X Ray ◽  
Diluted Magnetic ◽  
X Ray Absorption

AbstractThe magnetic characteristics of the dilute magnetic system GaGdN are investigated by mainly soft-X-ray magnetic circular dichroism (MCD) in energy range of 1160 – 1240 eV. The strong MCD signals up to 30 % at 15K are observed. The temperature dependence of its intensity is not on simple Curie-Weiss curve and depicts three-step curve. A step around 40 – 100K suggests a new magnetic phase. The luminescence spectrum of GaGdN at low temperature is divided into three parts consisting of two broad bands around 432 nm and 503 nm and a sharp peak at 652 nm. This sharp line is assigned to the intra-transition of f – f orbital owing to the weak temperature dependence of the intensity and peak position. AlGdN grown by molecular beam epitaxy produces luminescence at 318.5 nm. X-ray absorption fine structure is examined to survey the occupancy of the Gd ion in the grown specimens.

Fabrication, characterization and magnetic properties of Na-doped ZnO nanorods

2016 ◽  
Vol 09 (03) ◽  
pp. 1650039 ◽  
Author(s):  
Jingyuan Piao ◽  
Li-Ting Tseng ◽  
Kiyonori Suzuki ◽  
Jiabao Yi
Keyword(s):  
Magnetic Measurements ◽  
Zno Nanorods ◽  
X Ray Diffraction ◽  
Paramagnetic Resonance ◽  
X Ray ◽  
Shallow Donors ◽  
Na Doping ◽  
Transmission Electron ◽  
Doped Zno ◽  
Electron Paramagnetic

Na-doped ZnO nanorods have been fabricated through a hydrothermal method. X-ray diffraction (XRD) and transmission electron microscopy (TEM) analyses indicate that the d spacing of ZnO increases with increasing doping concentration, suggesting the effective incorporation of dopant Na in the samples. Electron paramagnetic resonance (EPR) measurements indicate that there are shallow donors in pure ZnO samples and the shallow donors are strongly prohibited by Na doping. In addition, the resonance at g = 2.005 suggests the formation of Zn vacancies. Magnetic measurements indicate that pure ZnO is paramagnetic and Na doping leads to ferromagnetism at room temperature. Moreover, 0.5% Na-doped ZnO nanorods exhibits the largest saturation magnetization.

Anomalous Ferromagnetism and Electron Microscopy Characterization of High-Quality Neodymium Oxychlorides Nanocrystals

NANO ◽  
2016 ◽  
Vol 11 (03) ◽  
pp. 1650034
Author(s):  
Xinliang Zheng ◽  
Juan Feng ◽  
Jiarui Zhang ◽  
Hongna Xing ◽  
Jiming Zheng ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Diluted Magnetic Semiconductors ◽  
Magnetic Semiconductors ◽  
X Ray Diffraction ◽  
High Quality ◽  
Selected Area Electron Diffraction ◽  
Transmission Electron ◽  
Diluted Magnetic ◽  
Microscopy Characterization

High-quality neodymium oxychlorides nanocrystals with cubic shape were synthesized by a nonhydrolytic thermolysis route. The morphology and crystal structure of the neodymium oxychlorides nanocubes were characterized by transmission electron microscopy at the nanoscale. Transmission electron microscope (TEM) image shows that the neodymium oxychlorides nanocrystals are nearly monodispersed with cube-like shape. X-ray diffraction (XRD) and selected area electron diffraction (SAED) patterns of numerous neodymium oxychlorides nanocubes suggest a pure crystal phase with tetragonal PbFCl matlockite structure. HRTEM image of individual neodymium oxychlorides nanocubes indicate that each nanocubes have a single-crystalline nature with high quality. Unlike the anti-ferromagnetism of the bulk, the neodymium oxychlorides nanocubes show clearly anomalous ferromagnetic characteristic at room temperature. This finding provides a new platform for the exploration of diluted magnetic semiconductors, rare earth-based nanomaterials and so on.

Characteristic of Al-Doped ZnO Nanorods by a Hydrothermal Process

2010 ◽  
Vol 434-435 ◽  
pp. 646-648 ◽  
Author(s):  
Jenn Kai Tsai ◽  
Ju Yu Wei ◽  
Yi Chi Chen ◽  
You Cheng Jheng ◽  
Teen Hang Meen
Keyword(s):  
Electron Microscopy ◽  
Zno Nanorods ◽  
Hydrothermal Process ◽  
Zinc Nitrate ◽  
Diffraction Field ◽  
Si Substrate ◽  
X Ray ◽  
Transmission Electron ◽  
Dilute Aqueous Solution ◽  
Doped Zno

In this study, well-aligned single-crystalline zinc oxide (ZnO) nanorods arrays were synthesized on Si substrate by simple hydrothermal process in dilute aqueous solution which consisting of zinc nitrate tetrahydrate (Zn(NO3)2•4H2O) and hexamethyltetramine (C6H12N4, HMT) at 90 °C, in the autoclave. ZnO thin film was pre-deposited on Si substrate by the sputter deposition to serve as the seed layer. Aluminum nitrite (Al(NO3)3) also has been mixed into reaction solution. Al doped ZnO nanorod arrays were fabricated successfully. ZnO nanorods were characterized by high resolution X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, energy dispersive x-ray spectroscopy, and photoluminescence measurement.

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