Impacts of Surface-Active Agents on the Crystal Structure of Nano Manganese Oxide

2013 ◽  
Vol 798-799 ◽  
pp. 125-129
Author(s):  
Fu Yun Li ◽  
Jing Wang ◽  
Ying Yang Qin ◽  
Li Zhen Yang

The nano manganese oxides were prepared with the hydrothermal method by adding surface-active agent. The influence of the type and addition amount of surface-active agent on the preparation of nano manganese oxides was studied. The products were characterized with XRD. Experimental results show that MnOOH is obtained at 180°C with the addition of N,N,N-trimethyl-1-dodecanaminium bromide, and Mn3O4is obtained at 180 °C with OP Emulsifier or Tween-80 added. Different addition amount of surface-active agent would have diverse effects on the purity of products.

1956 ◽  
Vol 104 (1) ◽  
pp. 1-13 ◽  
Author(s):  
Robert L. Hirsch ◽  
Aaron Kellner

Mice rendered hyperlipemic by means of intravenous or subcutaneous injections of triton WR 1339 were found to have an increase in the total amount of cholesterol in their bodies. This observation indicates that the injected surface-active agent affects the metabolism of cholesterol and brings about hyperlipemia by augmenting the synthesis of lipides, or by interfering with their degradation or excretion, or by some combination of these factors. The implications of the findings for the pathogenesis of the hyperlipemia induced by triton are discussed further in the accompanying paper (16).


2012 ◽  
Vol 534 ◽  
pp. 298-303
Author(s):  
Wei Niu ◽  
Zhong An Jiang ◽  
Ju Shi Chen

In order to reduce dust produced during the blasting, effective measures according to smoke components and properties are required to be taken. The experiment adopted a number of base materials and surface-active agents to reduce the dust in smoke. Besides, corresponding additives were adopted to reduce poisonous and harmful gases during the blasting. Experiments focused on wettability and surface tension, using contrast experiment to determine optimal base material and surface-active agent, and also studied the influence of additives on their performance. The experimental results suggested that: sodium chloride was the optimal base material, sodium dodecyl benzene sulfonate was the optimal surface-active agent, and copper sulphate and ammonium chloride as additives had almost no influence on performance of surface-active agent and base material. Therefore, adding this dustfall agent to the water bag during the blasting can effectively reduce the concentration of smoke.


2011 ◽  
Vol 335-336 ◽  
pp. 28-31
Author(s):  
Yu Ying Zheng ◽  
Wen Jun Ji ◽  
Jun Li ◽  
Hui Min Huang ◽  
Ming Sun

Nano-compounds of ZrO2/CNTs were prepared by hydrothermal method. The ZrO2/CNTs nano-compounds were characterizated by XRD, TEM, BET and Zeta potentials. The results showed that perfect hydrothermal temperature was 180°C, hydrothermal time was 11h, pH was 9.5. It is showed by the analysis of TEM and Zeta potential, adding surfacant CTBA, the surface of nano-tube and Zr(OH)4colloids take different charge, and they adsorpt each other. And ZrO2particles were successfully coated on the CNTs in surface-active agent of CTBA.


2021 ◽  
Vol 901 ◽  
pp. 35-39
Author(s):  
Sukannika Tubtimsri ◽  
Yotsanan Weerapol

The amorphous solid dispersions (ASDs) containing amino methacrylate copolymer and surface-active agents were prepared to improve the nifedipine (NDP) dissolution. The different types of surface-active agent i.e., polysorbates 80, sodium lauryl sulfate (SLS) and polyethylene glycol (PEG) 400 were used. In order to evaluate the ASDs formulation,powder X-ray diffractometry and thermal analysis to characterize NDP crystallinity in ASDs and the dissolution study of NDP have been performed to compare the dissolution profiles. The ASDs were kept for 6 months to investigate the stability. In the X-ray diffraction pattern, no peak was observed in all samples of ASDs. No peak was found in sample of all ASDs from the thermograms. These results suggest that the drug may be molecularly dispersed in matrix of amino methacrylate copolymer. The drug dissolution at 120 min, from ASDs without surface-active agent and NDP powder were 58.31% and 17.95%, respectively. The dissolved NDP from ASDs composed of SLS, polysorbate 80 and PEG400 were 96.25%, 88.86% and 75.32%, respectively. These results may occur due to the reduction of surface tension, the addition of the low amount of high efficiency of surface-active agent e.g., SLS (compared with PEG400 and polysorbate 80) provided the higher NDP dissolution. The content analysis of NDP in selected ASDs was studied at the end of 3 and 6 months, the NDP content remained unchanged after storage.


1977 ◽  
Vol 232 (3) ◽  
pp. H331-H334 ◽  
Author(s):  
R. W. Millard ◽  
H. Baig ◽  
S. F. Vatner

The cardiovascular effects of two concentrations of Tween 80 (polyoxyethylene sorbitan mono-oleate), a surface-active agent commonly used to prevent aggregation of radionuclide-labeled microspheres, were examined in conscious dogs. Two types of adverse reactions were noted. The first (Type A) consisted of reductions in cardiac dimensions as well as hypotension and tachycardia. The second (Type B) was less severe and involved only a decrease in cardiac dimensions with no change in left ventricular systolic pressure or heart rate. A 10% dextran solution with .05 +/- .02% Tween 80 injected into the left atrium caused systemic and/or cardiac alterations in all four dogs studied. Administration of a lower concentration of Tween 80 (0.01 +/- 0.005%), which was the minimum concentration necessary to prevent aggregation of microspheres, induced adverse reactions in 6 of 41 dogs studied. Subsequent administration of this concentration of Tween 80 on the same day rarely induced adverse reactions. Thus, care must be exercised in application of microsphere techniques to organ blood flow measurements when Tween 80 is used to prevent microsphere aggregation, since this surface-active agent causes profound alterations in cardiac dynamics in concentrations normally employed in experiments involving microsphere techniques.


1974 ◽  
Vol 52 (12) ◽  
pp. 2571-2574 ◽  
Author(s):  
Frank L. Binder

Tieghemiomyces parasiticus, a biotrophic haustorial mycoparasite, makes excellent axenic growth on a glycerol – casein hydrolysate medium, while growth on a glucose – casein hydrolysate medium is equivalent to that of a control medium containing only the nitrogen source. A comparison of 14C-glucose and 14C-glycerol uptake indicates these substrates enter this mycoparasite at significantly different rates. Incorporation of 14C-glucose is extremely slow and limited, while 14C-glycerol incorporation is very rapid. Excellent axenic growth of this mycoparasite occurs when a glucose – casein hydrolysate medium is supplemented with the surface-active agent Tween 80. These findings suggest that the inability of glucose to support growth results from the inability of this substrate to readily enter the vegetative hyphae of this mycoparasite when cultured axenically.


1971 ◽  
Vol 45 (3) ◽  
pp. 527-544 ◽  
Author(s):  
F. I. P. Smith ◽  
Alex D. D. Craik

Craik (1968) has previously examined the stability of horizontal liquid films when an air stream flows over the liquid surface and when the surface is contaminated by an insoluble surface-active agent. The present theoretical work extends this investigation to examine the role of soluble surface-active agents for cases where the liquid Reynolds number is small. This role is found to be a rather complex one which, under suitable conditions, may be either stabilizing or destabilizing.Related experimental work is described which yields results in qualitative agreement with the theoretical analysis.


2013 ◽  
Vol 437 ◽  
pp. 1089-1092
Author(s):  
Wei Lin Cui ◽  
Wu Ju Xu ◽  
Ling Jian Song

Because of alkaline declining the sweep efficiency, causing scale formation problem in the reservoir and the well bottom and the tubular pipes, so polymer/surfactant compound flooding technology is the emphasis in the research of enhanced recovery. So the articles study the regulation of different kinds of surface active agents at different temperature by MARS Rheometer. The testing result showed that the variation of viscocity under the interaction between the surface active agent and association polymer according to “three stage” model .The linear viscoelastic region of stress decrease when different surface active agents are put into polymer liquor, and the higher frequency, the better elasticity of polymer liquor. The hydrophobic association between the surface active agents and polymer decrease with a higher temperature, but the ionic surfactant is aggravate. The systematic study of binary system rheology can contribute to correctly understand and apply binary system.


2021 ◽  
pp. 209-220
Author(s):  
Anjali Goel ◽  
Shikha Shikha ◽  
Shivani Shivani ◽  
Sudha Tomar

Nickel based bimetallic nanocrystals, iridium-nickel play an imperative role in catalysis, electrocatalysis, and magnetic applications. In the present work Ir-Ni bimetallic nanoalloys were synthesized by modified polyol reduction method with different cationic, anionic, and non-ionic surface active agents like CTAB, SDS, TSC, and PVP. The non-ionic surface active agent PVP produced a better effect on nanoparticle size than cationic and anionic surfactants. The synthesized bimetallic nanocrystals were characterized by UV-Vis, XRD, FTIR, FESEM, and HRTEM techniques. XRD and FTIR verify the nature of synthesized bimetallic nanocrystals and the interaction between stabilizers and nanoparticles. HRTEM studies reveal that the PVP stabilized Ir-Ni (3:1) and Ir-Ni (1:1) bimetallic nanocrystals are small in size and less dispersed. Particle size range of these nanoparticles is from (1.77-2.36) nm. FESEM images show that nanoparticles are in quasi spherical shape. EDX analysis indicates that the resultant particles are core shell structure with Ni core and Ir shell.


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