Nanocomposite SPEEK/Titania Nanosheets (TNS) Proton Exchange Membranes for Fuel Cell Applications

2009 ◽  
Vol 421-422 ◽  
pp. 447-450 ◽  
Author(s):  
Debora Marani ◽  
S. Licoccia ◽  
Enrico Traversa ◽  
Masaru Miyayama
Keyword(s):  
Fuel Cell ◽  
Proton Conductivity ◽  
Water Uptake ◽  
Proton Exchange Membrane ◽  
Composite Membranes ◽  
Proton Exchange Membranes ◽  
Structural Features ◽  
Proton Exchange ◽  
Unique Nature ◽  
Exchange Membrane

SPEEK-based composite membranes containing various amounts of titania nanosheets (TNS) as inorganic fillers were investigated for proton exchange membrane fuel cell applications. The samples were characterized for water uptake, proton conductivity (EIS), and structural features (SEM and XRD). Composites at low inorganic additive contents exhibited improved properties in terms of proton conductivity and water uptake behavior. Best improvements were observed for the composite containing only 0.95 wt% of TNS. This result could be associated to the unique nature of the two dimensional nanostructure of the inorganic additive.

scholarly journals Pore-Filled Proton-Exchange Membranes with Fluorinated Moiety for Fuel Cell Application

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4433
Author(s):  
Hyeon-Bee Song ◽  
Jong-Hyeok Park ◽  
Jin-Soo Park ◽  
Moon-Sung Kang
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Continuous Process ◽  
Oxidation Stability ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Cross Linking ◽  
Polymer Backbone ◽  
Transfer Resistance ◽  
Exchange Membrane

Proton-exchange membrane fuel cells (PEMFCs) are the heart of promising hydrogen-fueled electric vehicles, and should lower their price and further improve durability. Therefore, it is necessary to enhance the performances of the proton-exchange membrane (PEM), which is a key component of a PEMFC. In this study, novel pore-filled proton-exchange membranes (PFPEMs) were developed, in which a partially fluorinated ionomer with high cross-linking density is combined with a porous polytetrafluoroethylene (PTFE) substrate. By using a thin and tough porous PTFE substrate film, it was possible to easily fabricate a composite membrane possessing sufficient physical strength and low mass transfer resistance. Therefore, it was expected that the manufacturing method would be simple and suitable for a continuous process, thereby significantly reducing the membrane price. In addition, by using a tri-functional cross-linker, the cross-linking density was increased. The oxidation stability was greatly enhanced by introducing a fluorine moiety into the polymer backbone, and the compatibility with the perfluorinated ionomer binder was also improved. The prepared PFPEMs showed stable PEMFC performance (as maximum power density) equivalent to 72% of Nafion 212. It is noted that the conductivity of the PFPEMs corresponds to 58–63% of that of Nafion 212. Thus, it is expected that a higher fuel cell performance could be achieved when the membrane resistance is further lowered.

scholarly journals PEMBUATAN DAN KARAKTERISASI MEMBRAN KOMPOSIT KITOSAN-SODIUM ALGINAT TERFOSFORILASI SEBAGAI PROTON EXCHANGE MEMBRANE FUEL CELL (PEMFC)

2016 ◽  
Vol 1 (1) ◽  
pp. 14
Author(s):  
Siti Wafiroh ◽  
Suyanto Suyanto ◽  
Yuliana Yuliana
Keyword(s):  
Fuel Cell ◽  
Sodium Alginate ◽  
Proton Conductivity ◽  
Composite Membrane ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Methanol Permeability ◽  
Water Swelling ◽  
Exchange Membrane

AbstrakDi era globalisasi ini, kebutuhan bahan bakar fosil semakin meningkat dan ketersediannya semakin menipis. Oleh karena itu, dibutuhkan bahan bakar alternatif seperti Proton Exchange Membrane Fuel Cell (PEMFC). Tujuan dari penelitian ini adalah membuat dan mengkarakterisasi membran komposit kitosan-sodium alginat dari rumput laut coklat (Sargassum sp.) terfosforilasi sebagai Proton Exchange Membrane Fuel Cell (PEMFC). PEM dibuat dengan 4 variasi perbandingan konsentrasi antara kitosan dengan sodium alginat 8:0, 8:1, 8:2, dan 8:4 (b/b). Membran komposit kitosan-sodium alginat difosforilasi dengan STPP 2N. Karakterisasi PEM meliputi: uji tarik, swelling air, kapasitas penukar ion, FTIR, SEM, permeabilitas metanol, dan konduktivitas proton. Berdasarkan hasil analisis tersebut, membran yang optimal adalah perbandingan 8:1 (b/b) dengan nilai modulus young sebesar 0,0901 kN/cm2, swelling air sebesar 19,14 %, permeabilitas metanol sebesar 72,7 x 10-7, dan konduktivitas proton sebesar 4,7 x 10-5 S/cm. Membran komposit kitosan-sodium alginat terfosforilasi memiliki kemampuan yang cukup baik untuk bisa diaplikasikan sebagai membran polimer elektrolit dalam PEMFC. Kata kunci: kitosan, sodium alginat, terfosforilasi, PEMFC  AbstractIn this globalization era, the needs of fossil fuel certainly increases, but its providence decreases. Therefore, we need alternative fuels such as Proton Exchange Membrane Fuel Cell (PEMFC). The purpose of this study is preparationand characterization of phosphorylated chitosan-sodium alginate composite membrane from brown seaweed (Sargassum sp.) as Proton Exchange Membrane Fuel Cell (PEMFC). PEM is produced with 4 variations of concentration ratio between chitosan and sodium alginate 8:0, 8:1, 8:2, and 8:4 (w/w). Chitosan-sodium alginate composite membrane phosphorylated with 2 N STPP. The characterization of PEM include: tensile test, water swelling, ion exchange capacity, FTIR, SEM, methanol permeability, and proton conductivity. Based on the analysis result, the optimal membrane is ratio of 8:1 (w/w) with the value of Young’s modulus about 0.0901 kN/cm2, water swelling at 19.14%, methanol permeability about 72.7 x 10-7, and proton conductivity about 4.7 x 10-5 S/cm. The phosphorylated chitosan-sodium alginate composite membrane has good potentials for the application of the polymer electrolyte membrane in PEMFC. Keywords: chitosan, sodium alginate, phosphorylated, PEMFC

Preparation and Characterization of Proton Exchange Membrane Based on Sulfonated Poly(arylene ether sulfone)/Polyacrylonitrile (SPAES/PAN)

2014 ◽  
Vol 577 ◽  
pp. 53-57
Author(s):  
Hang Wei ◽  
Guang Li
Keyword(s):  
Oxidative Stability ◽  
Proton Conductivity ◽  
Water Uptake ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Arylene Ether ◽  
Blend Membranes ◽  
Exchange Membrane ◽  
Sulfonated Poly

Sulfonated poly (arylene ether sulfone) s (SPAESs) exhibit good proton conductivity, thermal and mechanical properties, could act as candidates of proton exchange membranes for fuel cells. At the same time, the poor oxidative stability and excessive swelling ratio of SPAESs bring limitations for its further use. In this article, PAN was employed to mix with SPAES, and then SPAES/PAN blend membranes were prepared from the blend solution by casting. The water uptake, dimensional and oxidative stability, proton conductivity were measured with respect to the addition content of PAN, the phase morphology of the resultant SPAES/PAN were also observed by SEM. The results explained that the corporation of PAN into SPAES could reduce the water uptake and improve the oxidative stability of the obtained membranes compared with the pristine SPAES membrane. That the PAN phase distributed as separated domains in SPAES matrix was found, the interaction between SPAES and PAN may be present, which is responsible for the improvement of dimensional and oxidative stability. Although the proton conductivity of the blend membranes became reduced with increase of PAN content in the SPAES/PAN blend, the conductivity of 0.0265S/cm at 30°C could still be reached, satisfying the requirement for proton exchange membrane Fuel Cell

scholarly journals Amino-functionalized mesoporous silica based polyethersulfone–polyvinylpyrrolidone composite membranes for elevated temperature proton exchange membrane fuel cells

RSC Advances ◽  
2016 ◽  
Vol 6 (89) ◽  
pp. 86575-86585 ◽  
Author(s):  
Jin Zhang ◽  
Shanfu Lu ◽  
Haijin Zhu ◽  
Kongfa Chen ◽  
Yan Xiang ◽  
...  
Keyword(s):  
Elevated Temperature ◽  
Proton Exchange Membrane ◽  
State Of The Art ◽  
Composite Membranes ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
High Proton Conductivity ◽  
Functionalized Mesoporous Silica ◽  
High Proton ◽  
Exchange Membrane

It is important to find alternative membranes to the state-of-the-art polybenzimidazole based high temperature proton exchange membranes with high proton conductivity at elevated temperature but with simple synthesis procedures.

Investigation on the performance decay of proton exchange membrane basing on sulfonated heterocyclic poly(aryl ether ketone)s in Fenton’s reagent

2021 ◽  
Author(s):  
Qian Liu ◽  
Shouhai Zhang ◽  
Zhaoqi Wang ◽  
Jianhua Han ◽  
Ce Song ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Proton Exchange Membranes ◽  
Proton Conduction ◽  
Proton Exchange ◽  
Aryl Ether ◽  
Potential Applications ◽  
Aryl Ether Ketone ◽  
Ether Ketone ◽  
Exchange Membrane

Sulfonated N-heterocyclic poly(aryl ether)s proton exchange membranes have potential applications in the fuel-cell field for their favorable proton conduction capacity and stability. This paper investigates the changes in mass and...

The Control of Humidification and Dew Condensation by Using of On/Off Control of the Bubble Humidifier in the PEMFC

2012 ◽  
Vol 155-156 ◽  
pp. 856-860
Author(s):  
Young Guan Jung ◽  
Ho Sang Choi ◽  
Du Hee Kim ◽  
Dae Heum Park
Keyword(s):  
Fuel Cell ◽  
Proton Conductivity ◽  
Proton Exchange Membrane ◽  
Performance Enhancement ◽  
Flow Channel ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Visualization Experiment ◽  
And Performance ◽  
Exchange Membrane

The performance of Proton Exchange Membrane Fuel Cell (PEMFC) is known to be influenced by different operating conditions such as temperature, pressure, and humidification of the reactant gases. Especially, the humidification is essential for the electrolysis and performance enhancement of PEMFC, because the proton conductivity depends on the hydration of proton exchange membrane. In this study, the humidification experiment has been done concerning ON/OFF control of the humidification for PEMFC, by using of the bubble humidifiers which are usually difficult to approximation control the humidity. Also, in order to verify the dew condensation, the visualization experiment has been done at a flow channel of PEMFC stack. As the results, it is possible to approximation control the humidity by using of the solenoid on/off valve in the bubble humidifier. The dew condensation is also verified through such experiment. The problems, such as the approximation control of humidity and dew condensation, were then resolved in such a useful manner.

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