Bio-Based Hydrogel and Aerogel Composites Prepared by Combining Cellulose Solutions and Waterborne Polyurethane

Hydrogel composites can be prepared from cellulose-based materials and other gel materials, thus combining the advantages of both kinds of material. The aerogel, porous material formed after removing the water in the hydrogel, can maintain the network structure. Hydrogel and aerogel have high application potential. However, low mechanical strength and weight loss of cellulose hydrogel due to the water dehydration/absorption limit the feasibility of repeated use. In this study, cellulose hydrogels were prepared using microcrystalline cellulose (MC), carboxymethyl cellulose (CMC), and hydroxyethyl cellulose (HEC) as raw materials. Waterborne polyurethane (WPU) was added during the preparation process to form cellulose/WPU composite hydrogel and aerogel. The influence of the cellulose type and WPU addition ratio on the performance of hydrogel and aerogel were investigated. The results show that the introduction of WPU can help strengthen and stabilize the structure of cellulose hydrogel, reduce weight loss caused by water absorption and dehydration, and improve its reusability. The mixing of cellulose and WPU at a weight ratio of 90/10 is the best ratio to make the cellulose/WPU composite aerogel with the highest water swelling capacity and heat resistance.

Study of Sorption Kinetics of Doxycycline on pH Sensitive Hydrogel-based Graft Copolymers of Chitosan/Arabinogalactan/ Gummiarabic with Vinyl Monomers

Graft copolymers of natural polysaccharides chitosan (Chs), gummi-arabic (GA) and arabinogalactan (AG) were synthesized with N-vinylpyrrolidone (VPr) (4-vinylpyridine and N-vinylpyrrolidone used as comonomers for chitosan grafting), and then pH-sensitive hydrogels were designing by cross-linked them with N,N-methylene-bis-acrylamide. Effective sorption of doxycycline from aqueous solutions with water-swelling gels has been studied experimentally. The effect of gel dose, initial concentration of doxycycline, pH medium and solution ionic strength of the sorption rate and capacity of the antibiotic was systematically studied. The surface and volume absorption kinetics and isotherms of the process have also been investigated. It was found that the max sorption capacity for swellable gels varies between Chs-graft-VPr/4VPAG/graft-VPrGA/graft-VPr. It has been shown that the sorption mechanism is mainly dominated by physical sorption and to some extent hydrogen bonds and electrostatic interactions.

PREPARATION OF CHITOSAN GRAFT COPOLYMERS AND STUDY OF THEIR WATER-SWELLING PROPERTIES

In this work, graft copolymers of chitosan with trimethylmethacryloxyethylammonium methyl sulfate were synthesized by the method of controlled radical polymerization, and it was found that replacing the dimethylformamide aprotic solvent with water increases the degree of grafting. With the aim of the possible use of chitosan copolymers as a functional component for regulating the water-swelling properties of elastomers, the kinetics of swelling of the samples was investigated. An increase in the degree of swelling of the copolymers in comparison with the initial chitosan was revealed, and the influence of the molecular weight and the conditions of their synthesis was established.

ELASTOMERS WITH A HIGH CONTENT OF MODIFIED CARBOXYMETHYLCELLULOSE

The use of lactam-containing complex salts (LCS) with the functions of dispersants, apparatuses and crosslinking agents made it possible to obtain elastomers with a high (at least 300 wt.% per 100 wt.h. of rubber), containing modified carboxymethyl cellulose for the cuff of a packer device capable of performing the necessary shut-off functions in contact with highly concentrated, at least 25% aqueous solutions of mineral salts - NaCl and CaCl2. The achieved effect is expressed in the ability of LCS to disperse water-swelling polymers (GNP), to have an appreting effect on GNP particles, thereby preventing their agglomeration, as well as to create additional chemisorption bonds in the rubber matrix. As a result, a developed network of interface boundaries is obtained, which contributes to the rapid penetration of aqueous solutions of mineral salts into the array of elastomeric composition.

Successful Field Application of Delayed Water-Swelling, Flexible Gel Particles for In-Depth Waterflood Conformance Improvement in Wide Spacing of Wells with High Temperature and High Salinity

The HD Oilfield, operated by PetroChina, is located in Tarim Basin. It is characterized by high temperature (112 ℃) and high salinity (291000 mg/L), and developed by wide spacing of wells (average 700 m). High vertical and areal heterogeneity lead to early water breakthrough and a poor water sweep efficiency. Effective conformance control is urgently needed, but harsh reservoir conditions, wide well spacing, and discontinuous interlayers pose great challenges for conformance treatments in this field. Because of wide well spacing and discontinuous interlayers, water channeling and crossflow in in-depth part of reservoir could still occur after conformance treatment. To prevent this, in-depth conformance improvement treatments with injecting large volumes of low-cost profile control agents were proposed. To achieve this goal, we designed delayed water-swelling, flexible gel particles that have high deformability and elasticity. Simultaneously, to meet the harsh reservoir conditions, gel particles were designed to have long-term tolerance to high temperature and high salinity. The first treatment was implemented in May 2016, and the total incremental oil by June 2019 was 17347 tons. The treatment validity is more than 36 months, and it keeps being effective. Until now, 9 treatments have been finished. The total incremental oil is 102100 tons until May 2020, and the increment is still going on. The input-output ratio for these 9 treatments is about 8.45, which indicates the treatments were an economic and technical success. In this paper, first we describe the design of gel particles and their properties evaluation by extensive experiments, including water-swelling ability, long-term tolerance to high temperature and high salinity, elasticity, tenacity, injectivity, selectivity, plugging ability, and scouring resistance, etc. Then, we present operation design and control in the field, which is especially important for the success of these treatments. Furthermore, according to production performance as well as the wellhead pressure drop curve, pressure curve of water injection, and water injectivity in injection well, treatment results are discussed in detail to evaluate if the treatment is successful or not. Finally, several important experiences with respect to how to do operation design and field control are summarized. This paper documents a successful case history of in-depth waterflood conformance improvement in wide spacing of wells. These successful field cases together with summarized experience will provide a detailed guide and an updated framework for conformance improvement treatment for operators. In addition, this paper presents an alternative agent, i.e., delayed water-swelling, flexible gel particles, for in-depth waterflood conformance improvement in high temperature and high salinity reservoirs.

A Comparison Study on the Magneto-Responsive Properties and Swelling Behaviors of a Polyacrylamide-Based Hydrogel Incorporating with Magnetic Particles

This work investigates the mechanical properties, microstructures, and water-swelling behavior of a novel hydrogel filled with magnetic particles. The nanoparticles of magnetite (Fe3O4) and the micro-particles of carbonyl iron (CI) were selected and filled into a polyacrylamide (PAAM) hydrogel matrix to create two types of magnetic hydrogels. The isotropy and anisotropy of magnetic hydrogels are also presented in this study. The isotropic samples were cured without applying a magnetic field (MF), and the anisotropic samples were cured by applying an MF in the direction perpendicular to the thickness of the samples. The effects of the size, content, and inner structures of magnetic particles on the magneto-responsive and swelling properties of magnetic hydrogels were investigated. It was found that the magnetorheological (MR) effect of anisotropic samples was apparently higher than that of isotropic samples, and the hydrogels with CI exhibited a noticeable MR effect than those with Fe3O4. The storage modulus can be enhanced by increasing the filler content and size, forming an anisotropic structure, and applying an external MF. In addition, the magnetic hydrogels also have a swelling ability that can be tuned by varying the content and size of the particle fillers.

Fast Reduced Graphene-Based Membranes with High Desalination Performance

Graphene-oxide (GO) membrane with notable ions sieving properties has attracted significant attention for many applications. However, because of the water swelling of GO membrane, the rejection of monovalent metal cations is generally low. In this work, we developed a fast and facile method to fabricate a kind of reduced GO membranes using the thermal treatment method at 160 °C for only one minute, which denoted as fast reduced GO membrane (FRGO). Surprising, the FRGO membrane represents high ion sieving ability and ultrahigh water/ions selectivity, compared with other reduced GO membranes with similar average interlayer spacings, and even superior to most of GO-based membranes reported in literature. Building on these findings, we provide a new light on fabricating of energy- and environment-related high desalination performance of GO-based membranes as well as a new insight into the transport mechanism within 2D laminar nanochannels.

Long-Term Integrity Testing of Water-Swelling and Oil-Swelling Packers

As easy oil in many fields is dwindling, there is increasing stress worldwide on innovative enhanced oil recovery (EOR) techniques. One forward-looking EOR approach is the workover method. It tries to convert currently weak horizontal wells to maximum reservoir contact (MRC) wells, or abandoned vertical wells to horizontal ones or power water injectors. Where conventional techniques fail, swelling elastomer seals and packers provide effective water shutoff and zonal isolation in even very complex environments, resulting in significant savings in rig time and development cost. One major issue of interest is the service life of elastomer seals and packers. It can be attempted to predict the probable working life based on the theory of accelerated testing. However, this forecast will not be very dependable for swelling elastomers as the material performance is substantially different from other rubber-type polymers. A full-scale test rig (one of its kind in the world) was therefore designed and fabricated at Sultan Qaboos University (SQU), in collaboration with a regional petroleum development company, for long-term service life assessment of actual full-size water-swelling and oil-swelling packers.

Preparation and Characterisation of Sustainable Wood Plastic Composites Extracted from Municipal Solid Waste

Municipal solid waste (MSW) contains plastic waste that can be used as a sustainable green substitute to reduce oil footprints, CO2 emissions, and environmental pollution. This study aims to recycle plastic waste by manufacturing wood-plastic composites and to improve its mechanical properties by using additives, coupling agents, and lubricants. These composites are prepared by mixing 40–70% of wood flour with 20–25% of a polymer matrix. Wood was degraded at 220 °C, and then the composites were processed at 50 °C. The manufacturing process carried out in the study involved wood waste meshing, drying, shredding, drying, trimming, filling, blending, compounding, and extrusion moulding. The compounding of composites was accomplished in twin-screw extruders. Once the mixture was uniformly mixed, its final shape was given by a two-step extrusion moulding. Previously, researchers aimed at enhancing the mechanical properties of the composites, but our research focus was to improve their durability for different industrial applications. The results suggest that the impact strength is 17 MPa with 50% of wood powder ratio while the maximum value for the tensile strength is 32.5 MPa. About 50% of an increase in wood powder resulted in 8.1% bending strength increase from 26.1 to 32.8 MPa. Reducing the plastic matrix and the wood-particles water swelling ratio resulted in better mechanical properties. The wood species also affected the mechanical properties with their excellent dimensional stability and less variability. A high proportion of wood fibre tends to increase its steady-state torque and viscosity. The mechanical properties against different wood-flour proportions indicate that composite materials exhibit superior water swelling behaviour and extrusion quality.