Influence of Curing Temperature on the Mechanical Properties of Alkali-Activated Bottom Ash Geopolymer Mortar

2011 ◽  
Vol 488-489 ◽  
pp. 198-201 ◽  
Author(s):  
Gum Sung Ryu ◽  
Si Hwan Kim ◽  
Kyung Taek Koh ◽  
Su Tae Kang ◽  
Jang Hwa Lee

The fabrication of Portland cement causes numerous problems accompanying the large exhaustion of gas. Even if fly ash, an industrial by-product produced in thermoelectric power plants, is recycled in concrete by partial replacing of cement, more than 50% remains still discharged in marine and ashore landfills and, continue to provoke environmental problems. Recently, active research has been dedicated to alkali-activated concrete that does not use cement as binder. This alkali-activated concrete as a cement zero concrete activated by alkali solution using bottom ash rich in Si and Al instead of cement is effective in reducing gas exhaustion. This study is a basic research for the fabrication of concrete without cement and using 100% of bottom ash among the industrial by-products. Therefore, the purposes are to develop cement zero concrete by evaluating the mechanical properties by age according to the change of the molar concentration and ratio (SH/SS) of the alkali-activator and the curing temperature, and to investigate the reaction mechanism. From the test results, the compressive strength increased with larger molar concentration and the optimal curing temperature was 60°C. In addition, the measurement of the leaching according to the molar concentration of fly ash having similar chemical composition showed that the leaching of Si4+ and Al3+ increased. Compared to 6M, the leached quantities of Si4+ and Al3+ were twice larger for 9M and 12M. The formation of gel at the surface of fly ash indicated that fly ash was more activated in higher alkaline environment.

Alkali-activated concrete (AAC) is mounting as a feasible alternative to OPC assimilated to reduce greenhouse gas emanated during the production of OPC. Use of pozzolana results in gel over-strengthening and fabricate less quantity of Ca(OH)2 which provide confrontation to concrete against hostile environment. (AAC) is potential due to inheriting the property of disbursing CO2 instantly from the composition. Contrastingly an option to ordinary Portland cement (OPC), keeping this fact in mind the goal to evacuate CO2 emits and beneficiate industrial by-products into building material have been taken into consideration. Production of alkali-activated cement emanates CO2 nearly 50-80% less than OPC. This paper is the general assessment of current report on the fresh and hardened properties of alkali-activated fly ash (AAF), alkali-activated slag (AAS), and alkali activated slag and fly ash (AASF) concrete. In the recent epoch, there has been a progression to blend slag with fly ash to fabricate ambient cured alkali-activated concrete. Along with that the factors like environmental friendliness, advanced studies and investigation are also mandatorily required on the alkali activated slag and fly ash concrete. In this way, the slag to fly ash proportion impacts the essential properties and practical design of AAC. This discusses and reports the issue in an intensive manner in the following sections. This will entail providing a good considerate of the following virtues like workability, compressive strength, tensile strength, durability issues, ambient and elevated-temperature curing of AAC which will improve further investigation to elaborate the correct test methods and to commercialize it.


2010 ◽  
Vol 452-453 ◽  
pp. 721-724
Author(s):  
Gum Sung Ryu ◽  
Hyun Jin Kang ◽  
Su Tae Kang ◽  
Gyung Taek Koh ◽  
Jang Hwa Lee

Recently, research on alkali-activated concrete that does not use cement as binder has been actively conducted. This alkali-activated concrete is a cement zero concrete which, instead of cement, is activated by alkali solution using fly ash known to be rich of Si and Al and enables to reduce effectively the emission of CO2 gas. This paper presents a basic study for the manufacture of cementless concrete using 100% of fly ash. To that goal, the mechanical characteristics of cementless concrete is evaluated according to the age and the variation of the molar concentration of the alkali activator with focus on the identification of the reaction mechanism. The experimental results show that larger molar concentration elutes larger quantities of Si4+ and Al3+. Specifically, approximately twice larger quantities of Si4+ and Al3+ were eluted for molar concentrations of 9M and 12M than 6M. The formation of gel at the surface of fly ash appeared to be caused by the stronger activation of fly ash in higher alkali environment. The resulting compressive strengths per age indicated that the strength of concrete could be controlled according to the molar concentration of NaOH. Moreover, results also demonstrated that a molar concentration of 9M for NaOH seems to be appropriate to secure a strength superior to 40MPa as the reference for high strength concrete in ordinary concrete.


2019 ◽  
Vol 23 (9) ◽  
pp. 3875-3888 ◽  
Author(s):  
Anant Lal Murmu ◽  
Anamika Jain ◽  
Anjan Patel

2021 ◽  
Vol 295 ◽  
pp. 113140
Author(s):  
Sarah Fernando ◽  
Chamila Gunasekara ◽  
David W. Law ◽  
M.C.M. Nasvi ◽  
Sujeeva Setunge ◽  
...  

2016 ◽  
Vol 857 ◽  
pp. 400-404
Author(s):  
Tian Yu Xie ◽  
Togay Ozbakkaloglu

This paper presents the results of an experimental study on the behavior of fly ash-, bottom ash-, and blended fly and bottom ash-based geopolymer concrete (GPC) cured at ambient temperature. Four bathes of GPC were manufactured to investigate the influence of the fly ash-to-bottom ash mass ratio on the microstructure, compressive strength and elastic modulus of GPC. All the results indicate that the mass ratio of fly ash-to-bottom ash significantly affects the microstructure and mechanical properties of GPCs


2018 ◽  
Vol 761 ◽  
pp. 73-78 ◽  
Author(s):  
Matej Špak ◽  
Pavel Raschman

Alkali-activated materials based on fly ash are widely developed and also produced on the present. Some of fly ashes are not suitable for production of alkali-activated materials because of their inconvenient chemical composition. Alumina-silicates are the most important components that are needed to accomplish the successful reaction. The proper content of amorphous phase of alumina-silicates and its proportion as well should be provided for the final composition of alkali-activated materials. The influence of pure aluminum oxide powder as well as raw milled natural perlite on mechanical properties and durability of alkali-activated mortars was investigated. These minerals were used as partial replacement of fly ash coming from black coal combustion. In addition, the mortars were prepared by using different alkali activators.


2021 ◽  

Concrete is the most versatile, durable and reliable material and is the most used building material. It requires large amounts of Portland cement which has environmental problems associated with its production. Hence, an alternative concrete – geopolymer concrete is needed. The general aim of this book is to make significant contributions in understanding and deciphering the mechanisms of the realization of the alkali-activated fly ash-based geopolymer concrete and, at the same time, to present the main characteristics of the materials, components, as well as the influence that they have on the performance of the mechanical properties of the concrete. The book deals with in-depth research of the potential recovery of fly ash and using it as a raw material for the development of new construction materials, offering sustainable solutions to the construction industry.


2021 ◽  
Vol 904 ◽  
pp. 413-418
Author(s):  
Wilasinee Kingkam ◽  
Sasikarn Nuchdang ◽  
Dussadee Rattanaphra

Coal fly ash (CFA) and bottom ash (BA) obtained from coal fired power plants in Thailand and local supplier were characterized using XRF, XRD and N2 adsorption-desorption techniques. Their possibilities for conversion of palm oil into biodiesel were investigated. Selected CFA was also modified with lanthanum (La) at different La loading and the influence of La loading on biodiesel conversion was evaluated. The resulted showed that the Class C CFA as contained large amount of CaO (free lime) could catalyze the transesterification to achieve the highest FAME content of 89% under the operation conditions; the reaction temperature of 200 °C, the reaction pressure of 39 bars, the catalyst loading of 5 wt% of oil, the molar of oil to methanol of 1:30 and the stirring speed of 600 rpm for 5 h. The addition of La on the Class C CFA had a negative effect on conversion of palm oil. The FAME content decreased gradually from 89 to 62% with increasing La loading from 0 to 1 wt%.


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