Effect of Styrene-Acrylic Emulsion on Crack Resistance of Cement-Based Materials

2021 ◽  
Vol 1036 ◽  
pp. 288-300
Author(s):  
Jun Peng Mei ◽  
Hai Nan Li ◽  
Zhi Dong Xu

In this paper, the brittleness coefficient, elastic modulus-to-strength ratio, drying shrinkage and autogenous shrinkage and cracking sensitivity were used to investigate the effect of styrene-acrylic emulsion (SAE) on crack resistance of cement-based materials under ultralow water binder ratio (0.22). Then the pore structures, hydration products and surface morphology were also studied to explore the mechanism of SAE on improving the crack resistance of cement-based materials. Results show that, the addition of SAE significantly reduces the elastic modulus, brittleness coefficient, elastic strength ratio, drying shrinkage and autogenous shrinkage of the specimen. The cracking susceptibility is also decreased by the incorporation of SAE and when the dosage of SAE was 5%, the initial cracking time would be extended by 43 hours. In addition, incorporation of SAE can reduce the amount of pores that have an adverse effect on shrinkage, refine the microstructure and decrease the calcium hydroxide formation and microcracks of cement-based materials. Such results would be expected to provide guidance on enhancing the anti-cracking ability of high-performance cementitious materials by the dosage of SAE under low water-binder ratio in practical engineering.

2020 ◽  
Vol 2020 ◽  
pp. 1-10
Author(s):  
Shuncheng Xiang ◽  
Yingli Gao ◽  
Caijun Shi

Three polycarboxylates with different comb structures (i.e., the same degree of polymerization in side chains but different main chains) were synthesized via radical polymerization reaction at room temperature. The effect of polycarboxylates on the surface tension and the flowability in cement pastes was determined. The best product was selected to study its effects on the hydration heat evolution, compressive strength, autogenous shrinkage, and drying shrinkage of cement pastes with different kinds and contents of supplementary cementitious materials. The results showed that with the increase of molar ratio between AA and TPEG to 6 : 1, we could synthesis the best product. When the water-binder ratio was 0.4, with the increase of polycarboxylates, the cement hydration heat evolution had been slowed down, and the more the dosage was, the more obvious the effect was. Adding supplementary cementitious materials to cement under the same experimental conditions also played a mitigation role in slowing down the hydration heat. When the water-binder ratio was 0.3, supplementary cementitious materials could increase the strength of cement by 24.5% in maximum; its autogenous shrinkage and drying shrinkage could be decreased, respectively, by 60.1% and 21.9% in the lowest.


2011 ◽  
Vol 462-463 ◽  
pp. 183-187 ◽  
Author(s):  
Yun Feng Li ◽  
Rong Qiang Du ◽  
Fan Ying Kong

The early-age shrinkage cracking of concrete plays an important role to the accelerated deterioration and shortening the service life of concrete structures. Modern concretes are more sensitive to cracking immediately after setting, which is due to material characteristics (lower water/binder ratio and higher cement content) and external environmental fluctuations (humidity and temperature change). Determination of concrete free shrinkage is the basis of shrinkage cracking research. Analytical models of the autogenous shrinkage and drying shrinkage are established in this paper. The calculated results agree well with the experimental results.


2011 ◽  
Vol 306-307 ◽  
pp. 942-945
Author(s):  
Wang Lin Li ◽  
Ying Te Li ◽  
Jian Ying Yu

Concrete lining is commonly used in large channel project to fixup soil slope and prevent channel seepage. Concrete lining is a type of thin plates structure which should have the high compression strength, crack resistance and durability. Two new high performance concrete (HPC) are used in lining project of south main channel of Yellow River-crossing project in east-route of the South-to-North Water Diversion Project. One is flyash HPC with manufactured-sand and the other is HPC with cementitious capillary crystalline waterproofing material (CCCW); meanwhile, the mix proportion of flyash HPC with manufactured-sand and HPC with CCCW are recommended. For flyash HPC with manufactured-sand, the recommendatory water-binder ratio is 0.4 and the recommendatory flyash content is 30%. For HPC with CCCW, the recommendatory water-binder ratio is 0.48 and the recommendatory CCCW content is 1.5%.With the wide application of new HPC, the compression strength, crack resistance and durability of lining concrete are improved, channel seepage discharge is reduced and a large amount of natural building materials are saved.


2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Hong-zhu Quan ◽  
Hideo Kasami

In order to improve the durability of fly ash concrete, a series of experimental studies are carried out, where durability improving admixture is used to reduce drying shrinkage and improve freezing-thawing resistance. The effects of durability improving admixture, air content, water-binder ratio, and fly ash replacement ratio on the performance of fly ash concrete are discussed in this paper. The results show that by using durability improving admixture in nonair-entraining fly ash concrete, the compressive strength of fly ash concrete can be improved by 10%–20%, and the drying shrinkage is reduced by 60%. Carbonation resistance of concrete is roughly proportional to water-cement ratio regardless of water-binder ratio and fly ash replacement ratio. For the specimens cured in air for 2 weeks, the freezing-thawing resistance is improved. In addition, by making use of durability improving admixture, it is easier to control the air content and make fly ash concrete into nonair-entraining one. The quality of fly ash concrete is thereby optimized.


Author(s):  
Chinnu Mariam Ninan ◽  
K P Ramaswamy ◽  
R Sajeeb

Cementitious materials are highly susceptible to rapid and severe degradation by a wide range of acids that are found immensely in ground water, sewage systems, industrial effluents, acid rain etc. which may cause microstructure deterioration. The factors influencing acid attack is generally categorised as material related factors and test related factors. Material related factors can be either related to acid solution or concrete mixture composition. Composition of concrete mixture greatly impacts the acid resistance of concrete. Factors related to composition of concrete mixture are type of cement, type and proportion of binders, water binder ratio, aggregate binder ratio and mineralogical nature of the aggregates. Even though the type of cement influences acid attack, the magnitude of variation is negligible. Consumption of calcium hydroxide and refinement of pore structure makes the use of supplementary cementitious materials favourable for acid resistance. Decrease in water binder ratio and increase in aggregate binder ratio reduces the porosity of concrete and thereby improves the acid resistance of concrete. Calcareous aggregates are preferred for concretes exposed to acids having less soluble salts and not preferred for acids forming soluble salts. This paper highlights the influence of composition of concrete mixture on acid resistance of concrete. A proper formulation of concrete is expected to enhance its acid resistance.


2011 ◽  
Vol 675-677 ◽  
pp. 61-64
Author(s):  
Yu Zhu ◽  
Ying Zi Yang ◽  
Yan Yao

In order to investigate flowability and drying shrinkage of ECC, mini-slump flow deformation test and drying shrinkage are employed to analyse the influence of fly ash on the flowability and shrinkage of ECC. The water-binder ratio is kept at 0.25. The replacement ratio of cement by fly ash is 50%, 60%, 70% and 80%, respectively. The experimental results show that fluidity of fresh cment paste increases obviously as the fly ash becomes larger. The drying shrinkage of ECC specimens is greatly reduced as the content of fly ash increases from 50% to 80%. The measured drying shrinkage strian of ECC specimens with 80% fly ash at 28 days is less than 1000×10-6. 25% reduction of drying shrinkage of ECC is found when the fly ash content increases from 50% to 80%.


2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Shunbo Zhao ◽  
Changyong Li ◽  
Mingshuang Zhao ◽  
Xiaoyan Zhang

Steel fiber reinforced lightweight-aggregate concrete (SFRLAC) has many advantages applied in structural engineering. In this paper, the autogenous shrinkage and drying shrinkage of SFRLAC for up to 270 days were measured, considering the effects of types of coarse and fine aggregates with the changes of water-to-binder ratio and volume fraction of steel fiber, respectively. The properties of mix workability, apparent density, and compressive strength of SFRLAC were also reported and discussed in relation to above factors. Test results show that the development of autogenous and drying shrinkage of SFRLAC was fast within 28 days and tended to be steady after 90 days. The development of autogenous shrinkage of SFRLAC reduced with the increasing water-to-binder ratio and by using the expanded shale with higher soundness and good water absorption, especially at early age within 28 days; the later drying shrinkage was reduced and the development of drying shrinkage was slowed down with the increasing volume fraction of steel fiber obviously; manufactured sand led to less autogenous shrinkage but greater drying shrinkage than fine lightweight aggregate in SFRLAC. The regularities of autogenous shrinkage and drying shrinkage of SFRLAC expressed as the series of hyperbola are analyzed.


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