Effect of Silica Fume on the Rheological Properties of Cement Paste with Ultra-Low Water Binder Ratio

The effect of silica fume on the rheological properties of a cement–silica fume–high range water reducer–water mixture with ultra-low water binder ratio (CSHWM) was studied. The results indicate that the W/B ratio and silica fume content have different effects on the rheological parameters, including the yield stress, plastic viscosity, and hysteresis loop area. The shear-thickening influence of CSHWM decreased with the increased silica fume content. When the silica fume content increased from 0% to 35%, the mixture with W/B ratio of 0.19 and 0.23 changed from a dilatant fluid to a Newtonian fluid, and then to a pseudoplastic fluid. When the silica fume content was less than 15%, the yield stress was close to 0. With the increase of silica fume content, the yield stress increased rapidly. The plastic viscosity and hysteresis loop area decreased slightly with the addition of a small amount of silica fume, but increased significantly with the continuous increase of silica fume. Compared with the Bingham and modified Bingham models, the Herschel–Buckley model is more applicable for this CSHWM.

Compressive Strength and Chloride Ion Permeability Test of Concrete Incorporating Fly Ash and GGBS with Diverse Water Binder Ratio

In this study conventional concrete of M40 grade developed with diverse water binder ratio and fixed optimum dosage of 30% mineral admixture fly ash and GGBS with weight of cement .Compression test has been conducted on cube samples and Rapid Chloride permeability test (RCPT) are conducted on cylindrical specimens to acknowledge durability parameter. Compression test results has been enhanced with replacement of supplementary cementitious materials and chloride ion permeability has been reduced with substitution of fly ash and GGBS .incremental of water binder ratio also reduce the permeability value however compression value increased

Effect of the water/binder ratio on the hydration process of Portland cement pastes with silica fume and metakaolin

abstract: The microstructure of cement pastes is important to understand the effect of some parameters in the hydration process. In this context, this study had as objective to evaluate the effect of different water/binder (w/b) ratios in the hydration process of cementitious pastes produced with and without incorporation of silica fume and metakaolin. The pastes were obtained with water/binder ratios of 0.3, 0.4 e 0.5, with replacement, by weight, of Portland cement for silica fume and metakaolin, in the contents of 10% and 20%, respectively. It was performed the X-ray diffraction test of the pastes in the ages of 1, 3, 7, and 28 days, to evaluate the hydration evolution of the cementitious materials. According to the results obtained, it was observed that the cementitious pastes presented similar mineralogical phases, except for the pastes containing metakaolin due to the formation of new aluminate phases. With the increase of the water/binder ratio, the pozzolanic reactions and hydration occurred in greater proportion, standing out the metakaolin with greater reactivity.

Preparation and Freeze-Thaw Resistance of Geopolymer-Based Natural Plant Fiber Composites

Slag, alkaline activator solution and straw fibers were used to manufacture geopolymer-based natural plant fiber composites. In this study, three influences of water glass modulus, fiber content and water-binder ratio on bending strength were studied by orthogonal experiment and single factor analysis. The results indicate that the order of the factors affecting the bending strength is: water-binder ratio > fiber content > water glass modulus. When the water-binder ratio is 0.4, the fiber content is 12%, and the water glass modulus is 1.9, the bending strength of composite is up to 9.1MPa, which exceeds the standard requirements (9MPa) for qualified products specified in the standard (GB/T 24312-2009). The SEM and appearance of specimens indicate that the geopolymer-based natural plant fiber composites have good freeze-thaw resistance.

Optimization of Preparation of Foamed Concrete Based on Orthogonal Experiment and Range Analysis

For the purpose of reducing the energy consumption and construction cost of buildings, the preparation process of geopolymer based foamed concrete, which is a novel material of the wall and roof of building, had been studied in detail. Water glass and sodium hydroxide were used as the alkali activator to excite the mixture consists of slag, fly ash and Kaolin to form the geopolymer matrix, and finally the foams generated using the physical foaming method were filled into the geopolymer matrix to produce geopolymer-based foamed concrete blocks. In the preparation process, firstly one of the four parameters of foam content, water-binder ratio, water glass content, and water glass modulus had been changed separately to study the influence of a single factor on the compressive strength, dry density, thermal conductivity and specific strength of foamed concrete blocks. The experimental results show that the above four factors have different degrees of influence on the concerned performances. Next, some representative combinations of these factors were constructed by orthogonal experiment method, and the influence degree of each combination on the concerned performances was determined by means of range analysis. According to the results of analysis, the most important influencing factor in terms of thermal conductivity was the water-binder ratio, followed by foam content, water glass modulus and water glass content. When the foam content is 1.58%, the water-binder ratio is 0.45, the water glass content is 30%, and the water glass modulus is 1.2, the thermal conductivity of the prepared geopolymer foam concrete reaches 0.044 W/(m·K), which satisfies the expected requirements for heating in severe cold areas.

Effects of Different Content of Phosphorus Slag Composite Concrete: Heat Evolution, Sulphate-Corrosion Resistance and Volume Deformation

Phosphorus slag (PS) and limestone (LS) composite (PLC) were prepared with a mass ratio of 1:1. The effects of the content of PLC and the water/binder ratio on the mechanical properties, durability and dry shrinkage of concrete were studied via compressive strength, electric flux, sulfate dry/wet cycle method, saturated drainage method, isothermal calorimeter, adiabatic temperature rise instrument and shrinkage deformation instrument. The results show that PLC can greatly reduce the adiabatic temperature rise of concrete. The adiabatic temperature rise is 55 °C with 33 wt.% PLC, 10 °C lower than that of the control sample. The addition in the content of PLC does not affect the long-term strength of concrete. When the water/binder ratio decreases by 0.1–0.15, the long-term strength of concrete with PLC increases by about 10%, compared with the control group. At the age of 360 days, the chloride permeability of L-11 (i.e., the content of PLC was 20%, the water/binder ratio was 0.418) and L-22 (i.e., the content of PLC was 33%, the water/binder ratio was 0.39) decrease to the “very low” grade. The strength loss rate of L-11 and L-22 after 150 sulfate dry/wet cycles is about 18.5% and 19%, respectively, which is 60% of the strength loss rate of the control sample. The drying shrinkage of L-11 and L-22 reduces by 4.7% and 9.5%, respectively, indicating that PLC can also reduce the drying shrinkage.

Fracture Characterization of Ultra-High Performance Concrete Notched Beams under the Influence of Different Material Factors Based on Acoustic Emission Technique

Acoustic emission (AE) technology is widely used in structural health monitoring. Glass sand (GS) made from waste glass is a promising replacement aggregate for quartz sand (QS) in ultra-high performance concrete (UHPC). This paper addresses the effects of different factors including water-binder ratio, length of basalt fiber (BF) and ratio of GS replacing QS on the fluidity and flexural strength of UHPC notched beam under four-point flexural loads. Meanwhile, the fracture characteristics of UHPC notched beam were characterized through acoustic emission (AE) technique. The results show that water-binder ratio and replacement ratio of GS present a positive correlation with work performance of UHPC, while length of BF exhibits a negative one. The flexural strength of UHPC notched beams can be improved by the decrease of the water-binder ratio and fiber length. The effect of water-binder ratio on flexural strength is the most significant, while the addition of GS presents the minimum one. The fracture characteristics of UHPC notched beams could be favorably characterized by AE parameters. Through the analysis and comparison of the evolution of AE parameters, the differences in fracture properties of UHPC notched beams with different flexural strengths can be realized. Through this study, the fluidity and flexural performance of UHPC produced by replacing QS with GS were demonstrated, which is beneficial to the cleaner production of UHPC. Meanwhile, the AE technique presented great potential for fracture characterization of UHPC notched beam, which also provided a promising method for real-time monitoring of cracking in the diagnosis of UHPC structures.

The Rapid Chloride Migration Test in Assessing the Chloride Penetration Resistance of Normal and Lightweight Concrete

Chloride-induced corrosion has been one of the main causes of reinforced concrete deterioration. One of the most used methods in assessing the chloride penetration resistance of concrete is the rapid chloride migration test (RCMT). This is an expeditious and simple method but may not be representative of the chloride transport behaviour of concrete in real environment. Other methods, like immersion (IT) and wetting–drying tests (WDT), allow for a more accurate approach to reality, but are laborious and very time-consuming. This paper aims to analyse the capacity of RCMT in assessing the chloride penetration resistance of common concrete produced with different types of aggregate (normal and lightweight) and paste composition (variable type of binder and water/binder ratio). To this end, the RCMT results were compared with those obtained from the same concretes under long-term IT and WDT. A reasonable correlation between the RCMT and diffusion tests was found, when slow-reactive supplementary materials or porous lightweight aggregates surrounded by weak pastes were not considered. A poorer correlation was found when concrete was exposed under wetting–drying conditions. Nevertheless, the RCMT was able to sort concretes in different classes of chloride penetration resistance under distinct exposure conditions, regardless of the type of aggregate and water/binder ratio.