The Effect of Various Grinding Aids on the Properties of Cement and Its Compatibility with Acrylate-Based Superplasticizer

The influence of grinding aids (pure triethanolamine and ethylene glycol) on the properties of cements, their compatibility with an acrylate-based superplasticizer and the rheological parameters of mortars were investigated. The presence of surfactants influences the standard properties of cements and the effectiveness of the superplasticizer. The results of the heat of hydration and setting time measurements indicate a delay in the hydration process and an increase in the induction period duration of the surfactant-doped pastes, in relation to the reference sample without grinding aids. Triethanolamine increases early-age compressive strength; the effect was observed for both standard and superplasticizer-containing mortars. The presence of grinding aids decreases the slump flow of mortars and increases rheological parameters such as yield stress (τ0) and viscosity (η).

Research on Shrinkage Inhibition Technology of C50 Steel Shell Immersed Tube Self-Compacting Concrete

The effects of shrinkage reducing agent and expansion agent on workability, strength and shrinkage of C50 self-compacting concrete with steel-shell immersed tube were studied. It is found that the expansive agent can increase the 28d compressive strength of concrete and restrain the shrinkage of concrete, but it can reduce the mixture property of concrete, and the shrinkage reducing agent can reduce the 28d compressive strength of concrete, but it can obviously restrain the shrinkage of concrete and improve the performance of concrete mixture. On the basis that the performance of concrete mixture meets the technical index, when the dosage of shrinkage reducing agent is 1.5%, the performance of concrete mixture is the best, and the drying shrinkage rate of 28d is the smallest. At this time, the properties of C50 steel-shell sunk pipe self-compacting concrete are as follows: slump flow 720mm, T50 2s, pour-down time 2s, v-shaped funnel passing time 6s, 28d compressive strength 59.6 MPa, 28d drying shrinkage 135×10−6.

Influence of Waste Fly Ash on the Rheological Properties of Fresh Cement Paste and the Following Electrical Performances and Mechanical Strengths of Hardened Specimens

Waste fly ash (WFA) is a kind of solid waste without reasonable disposition. The WFA with active substance can promote the cement hydration, therefore, WFA may enhance the mechanical strengths of cement-based materials. In this paper, the rheological properties (slump flow and plastic viscosity) of fresh cement paste with WFA ranging from 0% to 25% by mass ratio of cement were studied. The alternating current (AC) electrical resistance and direct current (DC) resistance time curves were determined. The AC impedance spectroscopy curves of the specimens cured for 1 day and 28 days were obtained. Finally, the mechanical strengths of hardened cement paste cured for 1 day, 3 days, 7 days, and 28 days were tested. The results showed that the slump flow was decreased and the plastic viscosity was increased by the addition of WFA and the increasing curing time. The AC electrical resistance increased in the form of the quadratic function with the cuing age. Meanwhile, the addition of WFA demonstrated an enhancing effect on the electrical conduction of cement paste. The variation rate of DC electrical resistance during the testing time increased with the increasing dosages of WFA and the curing age. The mechanical strengths increased with the addition of curing time and the content of WFA. The increasing rate of mechanical strengths increased with the addition of WFA (0~15%) and decreased with curing time. However, when the dosage of WFA increased from 15% to 25%, the increasing rate decreased.

Workability dan Sifat Mekanik Self Compacting Geopolimer Concrete (SCGC)

The purpose of this study was to investigate the relationship between molarity and workability in Self-Compacting Geopolymer Concrete (SCGC), as well as mechanical properties. Compressive strength and split tensile strength tests are used to characterize the mechanical characteristics in this research. Additionally, the study investigates the optimal molarity for self-compacting geopolymer concrete. Fly ash was used in lieu of cement in this research. On new concrete self-compacting geopolymer, workability is determined using the EFNARC standard, which includes the Slump Flow, V-Funnel, and L-Box tests. ASTM 39/C 39M-99 standard is used to determine the compressive strength of self-compacting concrete geopolymer. On new concrete, workability is determined using the EFNARC standard, which comprises the Slump Flow Test, a V-funnel, and an L-Box. The compressive strength of concrete samples is determined according to the ASTM 39/C 39M – 99 standard. The SNI 03-2491-2002 standard is used to determine the split tensile strength of concrete. At the ages of 7, 14, and 28 days, tests were conducted. The findings indicated that new concrete at 11M-13M satisfied the criteria for SCGC workability. The compressive and split tensile strengths of SCGC grow as the concrete ages. In self-compacting geopolymer concrete, the optimal molarity is 13 M.

Application of an Improved Empirical Model for Rheology Prediction of Cement Pastes Modified with Filler from Manufactured Sand

There is a need for simple but precise prediction models for proportioning concrete with manufactured sand, for use in ready-mix concrete production. For the last two decades, the particle-matrix model has been used in Norway for proportioning and prediction of concrete flow based on the properties and proportions of two concrete phases: coarse particles and filler modified cement paste (matrix). This paper presents experimental testing of 117 cement pastes of which 107 contain filler, i.e. particles < 125 microns, from manufactured sand. Based on compositions and properties of ingoing materials in these mixes, an empirical equation is developed that predicts the rheological properties plastic viscosity, yield stress, flow resistance ratio and mini slump flow. Optimization by regression analysis provides a practical microproportioning equation that readily can be used as input in concrete proportioning with the particle-matrix model. The equation provides a coefficient of determination R2 = 0.98 for plastic viscosity, R2 = 0.95 for mini slump flow, R2 = 0.91 for flow resistance ratio and R2 = 0.80 for yield stress.

Evaluations of All-in-One, Polycarboxylate-Based Superplasticizer with Viscosity Modifying Agents for the Application of Normal-Strength, High-Fluidity Concrete

High fluidity concrete exhibits an excellent self-compacting property. However, the application of typical high-fluidity concrete is limited in the normal strength range (18~35 MPa) due to the large amount of binder. Therefore, it is important to solve these problems by adding a viscosity modifying agent (VMA) with a superplasticizer (PCE), which helps to improve the fluidity of the concrete. In addition, the rheology and stability of the concrete with VMA can be improved by preventing bleeding and segregation issues. Current studies focused on the physical phenomena of concrete such as the fluidity, rheological properties, and compressive strength of normal-strength, high-fluidity concrete (NSHFC) with different types of a polycarboxylate-based superplasticizer (NPCE). The obtained results suggested that the combinations of all-in-one polycarboxylate-based superplasticizers (NPCE) did not cause any cohesion or sedimentation even stored for a long time. The combination of three types of VMA showed the best fluidity (initial slump flow of 595~630 mm) without any segregation and bleeding, and the compressive strength at 28 days was also found to be the highest: 34–37 MPa. From these results, the combination of PCE (2.0%) + HPMC (0.3%) + WG (0.1%) + ST (0.1%) showed an 18% higher plastic viscosity and -4.4% lower yield stress than Plain.

Studi Pemanfaatan Prekursor Fly Ash Lokal pada Self Compacting Geopolymer Concrete (SCGC)

Beton merupakan suatu material yang banyak digunakan dalam dunia konstruksi. Namun, setiap produksi beton menimbulkan dampak buruk pada pemanasan global. Semen sebagai bahan pengikat beton dapat menyumbang emisi CO2 sebanyak 8% dalam setiap produksinya. Proses pengecoran pada beton juga dapat menghasilkan polusi suara akibat penggunaan alat vibrator. Para peneliti terus berupaya menghasilkan beton yang lebih ramah lingkungan. Self Compacting Geopolymer Concrete (SCGC) merupakan kombinasi baru antara beton geopolimer dan Self Compacting Concrete (SCC) yang masih terus diteliti dan dikembangkan hingga saat ini. SCGC merupakan beton ramah lingkungan karena tidak menggunakan semen portland sebagai bahan pengikatnya. Penggunaan beton SCGC tidak memerlukan vibrator karena memiliki sifat flowability yang baik. Penelitian ini menggunakan bahan pengikat berupa material pozzolan yang mengandung senyawa kimia berupa SiO2 dan Al2O3. Tahapan penelitian ini dilakukan dengan mencari metode curing dan mix design optimal dalam penyusunan SCGC. Pengujian XRF perlu dilakukan dalam penelitian ini untuk mengetahui kandungan senyawa kimia pada fly ash Tjiwi Kimia. Beberapa pengujian beton segar SCGC diperoleh hasil berupa slump flow 690 mm, T50 2,4 detik, v-funnel 8,35 mm, dan rasio l-box 0,84. Sifat mekanik beton diuji berdasarkan kuat tekan, kuat tarik belah, dan kuat lentur dengan hasil rata-rata sebesar 27,05 MPa, 6,32 MPa, 1,91 MPa.

Fresh, Durability and Mechanical Behavior of Self Consolidating Concrete Incorporating Fly Ash and Admixture under Hot Weather

The self-consolidating concrete (SCC) become the material of choice by concrete industry due to its superior properties. However, these properties need to be verified under hot weather conditions. The paper investigates the behavior of SCC under hot weather. Six SCC mixtures were prepared under high temperatures. The SCC mixtures incorporated polycarboxylate admixture at different dosages and prolonged mixed for up to 2 hours at 30 °C and 40 °C. The cement paste was replaced with 20% of fly ash (FA). The fresh properties were investigated using slump flow, T50, and VSI tests. The compressive strength was measured at 3, 7, and 28 days. The durability of SCC mixtures was evaluated by conducting rapid chloride penetration and water absorption tests.

Effects of Induction-Furnace Slag on Strength Properties of Self-Compacting Concrete

Indiscriminate waste disposal poses a severe environmental challenge globally. Recycling of industrial wastes for concrete production is currently the utmost effective way of managing wastes for a cleaner environment and sustainable products. This study investigates the strength characteristics of self-compacting concrete (SCC) containing induction furnace slag (IFS) as a supplementary cementitious material (SCM). The materials utilized include 42.5R Portland cement, induction furnace slag as an SCM ranging from 0 to 50 % by cement weight at 10 % interval, river sand, granite, water and superplasticizer. The fresh properties were tested for filling ability, passing ability and segregation resistance, the strength characteristics measured include compressive strength, splitting tensile strength, flexural strength and Schmidt/rebound number. The oxide compositions and microstructural analysis of SCC were investigated using x-ray fluorescence analyser (XRF) and scanning electron microscopy equipped with energy-dispersive x-ray spectroscopy (SEM-EDS), respectively. Empirical correlations were statistically analyzed using MS-Excel tool. The filling ability characteristic was determined via both the slump flow test and the T50cm slump flow time test. Moreover, the passing ability characteristic was determined using L-Box test. The segregation resistance characteristic was determined using V-funnel at T5minutes test. The results of the fresh properties showed a reduction in the slump flow with increasing IFS content. On the other hand, the T50cm slump flow increased with increasing IFS content. Furthermore, the L-Box decreased with higher IFS content. On the contrary, the V-funnel at T5minutes increased considerably with greater IFS content. The strength test results revealed that the strength properties increased to 20 % IFS, with a value of 66.79 N/mm2 compressive strength at 56 days, giving a rise of 12.61 % over the control. The SCC microstructural examinations revealed the amorphous and better interface structures with increasing IFS content in the mix. The empirical correlations revealed that linear relationships exist among the measured responses (fresh and strength properties). Ultimately, IFS could be utilized as a sustainable material in producing self-compacting concrete.

Particle Size Effect of Oyster Shell on Mortar: Experimental Investigation and Modeling

In order to solve the problem of lack of natural river sand, crushed waste oyster shells (WOS) were used to replace river sand. By replacing 20% river sand, WOS mortar with different particle sizes of WOS were made for the experiment. Through experimental observation, the initial slump and slump flow loss rate were studied. The effects of different particle sizes and curing times on the compressive strength, flexural strength, static elastic modulus, and dry shrinkage of WOS mortar were analyzed. The relationship formulas between the compressive strength, flexural strength, particle size, and curing age were proposed. The results showed that the setting time and slump flow decreased with a decrease in the particle size of WOS. It was also found that the mortar with fine crushed WOS had high compressive strength, flexural strength, and static elastic modulus at both early and long-term curing age. A formula was proposed to describe the development of the compressive strength with the particle size of WOS and curing time, and the relations among these mechanical properties were discussed. Furthermore, drying shrinkage increased when WOS was used and could not satisfy the standard requirement of 0.075%. In contrast, the addition of fine WOS and double-dose sulfonated naphthalene-formaldehyde superplasticizer (SNF SP) reduced the shrinkage rate of the mortar by 8.35% and provided better workability and mechanical properties for mortar.