Estimation of the Filled Two-Component Cold Curing Polymer System Performance as a Coating for Protecting Concrete Surfaces from the Aggressive Environment Exposure

2021 ◽  
Vol 1043 ◽  
pp. 73-80
Author(s):  
Renata Burkhanova ◽  
Natalya Evstafyeva ◽  
Talgat Akchurin ◽  
Igor Stefanenko

A filled two-component polymer cold curingsystem (FTCPS) is discussed in the article. To assess its corrosion resistance and durability, the indexes of reagent resistance were determined in accordance with the sorption method. What is optimal, since this value depends on the parameters of mass transfer, the intensity of the reaction, the size of the product, the duration of exposure to aggressive media and other factors. As aggressive media were taken: water, 5% hydrochloric acid solution, 25% aqueous ammonia solution, 10% sodium hydroxide solution, saturated sodium chloride solution. The exposure time was 360 days. Reagent resistance evaluation of the developed FTCPScompositionswas carried out on the basis of guidelines for determining the anticorrosive properties of protective coatings of concrete and laboratory test methods. Changes in the mass of the samples and their reagent resistance as a result of exposure to chemical reagents simulating an aggressive environment during operation were evaluated. The change in the index of reagent resistance in laboratory conditions did not go beyond the value of 0.80, which makes it possible to ensure reliable protection and operation of polymer-coated products under conditions of exposure to these aggressive environments.

Author(s):  
Ольга Владимировна Неёлова ◽  
Людмила Муратовна Кубалова ◽  
Анна Петровна Деревщикова

Представлен обзор по методам испытаний кремний органических полимерных композиций, применяемых в качестве защитных покрытий в современном электронном приборостроении. A review is given of testing methods for organosilicon polymer compositions used as protective coatings in modern electronic instrumentation.


Author(s):  
N.I. Konstantinova ◽  
◽  
N.V. Smirnov ◽  
O.V. Krivoshapkina ◽  
O.I. Molchadskiy ◽  
...  

Fiber cement finishing materials are widely used in the construction of industrial buildings and structures due to the complex of valuable operational properties. In the Russian market there are fiber-cement panels with a variety of design solutions for their coloring and application of protective coatings. Fiber cement board is a strong and moisture-resistant composite material made from a cement-sand mixture, reinforcing cellulose fibers and special additives. Not being a non-combustible material, the fiber cement boards in accordance with the current mandatory requirements, as a decorative, finishing and facing material for walls and ceilings have restrictions on their use. Existing domestic requirements regarding the methodology for assessing the combustibility of fiber cement products largely narrow the field of using these materials. Therefore, it is advisable to develop the proposals for amending the test methods and the regulatory framework governing their fire-safe extended scope. In the course of this work execution, the main provisions of the regulatory and methodological framework that establish the requirements for the fire-safe use of fiber cement materials are analyzed. Experimental complex studies of fire hazard properties of various types of samples of the fiber cement finishing panels and slabs were carried out. It is established that fiber-cement materials belong to the class of the least fire-hazardous materials. Advisability is determined concerning the introduction to the national regulatory practice of GOST R «Building materials. Test method for fire hazard under thermal exposure with a single burner (SBI)». Classification parameters of the group of non-combustible materials NG2 were established to amend GOST R 57270—2016 (method 1). Classification parameters of the group of non-combustible materials NG2 for making changes in GOST R 57270—2016 (method 1) are established. Proposals were developed to expand the scope of application of the materials and products made of fiber cement as enclosing structures, partitions, and decorative finishes (cladding) in the buildings and structures.


2020 ◽  
Vol 10 (15) ◽  
pp. 5190
Author(s):  
Danutė Vaičiukynienė ◽  
Dalia Nizevičienė ◽  
Aras Kantautas ◽  
Vytautas Bocullo ◽  
Andrius Kielė

There is a growing interest in the development of new cementitious binders for building construction activities. In this study, biomass bottom ash (BBA) was used as aluminosilicate precursor and phosphogypsum (PG) was used as a calcium source. The mixtures of BBA and PG were activated with the sodium hydroxide solution or the mixture of sodium hydroxide solution and sodium silicate hydrate solution. Alkali activated binders were investigated using X-ray powder diffraction (XRD), X-ray fluorescence (XRF) and scanning electron microscopy (SEM) test methods. The compressive strength of hardened paste and fine-grained concrete was also evaluated. After 28 days, the highest compressive strength reached 30.0 MPa—when the BBA was substituted with 15% PG and activated with NaOH solution—which is 14 MPa more than control sample. In addition, BBA fine-grained concrete samples based on BBA with 15% PG substitute activated with NaOH/Na2SiO3 solution showed higher compressive strength compered to when NaOH activator was used −15.4 MPa and 12.9 MPa respectfully. The NaOH/Na2SiO3 activator solution resulted reduced open porosity, so potentially the fine-grained concrete resistance to freeze and thaw increased.


2021 ◽  
Vol 33 (1) ◽  
Author(s):  
Andrea Brunelli ◽  
Loris Calgaro ◽  
Elena Semenzin ◽  
Virginia Cazzagon ◽  
Elisa Giubilato ◽  
...  

AbstractThe development of highly innovative techniques and technologies to enhance performance and technical sustainability of materials used in the field of cultural heritage conservation is providing conservators with innovative nanocomposites materials, including protective coatings, by merging the performances of engineered nanoparticles (NPs) with conventional chemicals. However, the human health and environmental risks that may potentially arise from these new materials are still largely unknown, requiring an adequate assessment and management along their entire life cycle. Concerns could emerge due to the leaching of the material containing NPs or of the NPs alone, especially during their use (exposure of the treated object to, e.g., heavy or acid rain) and disposal (when the wasted product is processed in, e.g., waste water treatment plants). To date, no standard leaching test methods have been specifically developed for nano-enabled products, with the consequent lack of data on the NPs potential exposure also in the field of cultural heritage. Therefore, an extensive review over the last 10 years by querying to the Scopus database “nanoparticles”, “leaching” and “coatings” has been herein reported to clearly highlight (i) the standard test methods used or adapted to estimate the NPs leaching from nano-based coatings; (ii) the available studies in which the NPs leaching from nano-based coatings was estimated without following any specific standard test method; (iii) the works focusing on other nanocomposite materials performances than leaching, in which standard test methods were applied, potentially useful to indirectly estimate NPs leaching. All the information gathered by this bibliographic search have been used to identify the most promising leaching tests for NPs estimation to be applied in the field of cultural heritage, especially for both large, e.g., building façades, and small, e.g., bronze works of art, surface areas from which the leaching of nano-based materials could be significant in terms of human health and ecological risks, based also on the (eco)toxicity of the leachate. The derived information can thus ultimately support effective risk management of innovative nano-enabled products, including the implementation of Safe by Design approaches.


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