X-Ray Powder Diffraction and Mössbauer Study of Red Mud Residue from Alumina Production

2000 ◽  
Vol 343-346 ◽  
pp. 695-700 ◽  
Author(s):  
G. Budroni ◽  
Giorgio Cocco ◽  
Jian Zhong Jiang ◽  
Giovanni Carturan ◽  
Stefano Enzo
Author(s):  
G. Budroni ◽  
Giorgio Cocco ◽  
Jian Zhong Jiang ◽  
Giovanni Carturan ◽  
Stefano Enzo

2019 ◽  
Vol 23 (5 Part A) ◽  
pp. 2561-2568
Author(s):  
Yi Man ◽  
Jun-Xiao Feng ◽  
Zhan-Min Yang ◽  
Zeng-Lu Song ◽  
Chao Yang

The disposal of red mud, which is the by-product obtained from alumina production, has brought about environmental pollution because of its caustic nature as well its metal and alkaline contents. Red mud-coal composite pellets were directly reduced to deal with red mud. The influences of reduction temperature and gas composition on the reaction were studied. Experiment results indicated that the optimum reaction parameters were a temperature of 1100?C and an H2 atmosphere. Reduction degrees in H2 and CO atmospheres were significantly higher than those in N2 atmosphere. Reduction did not strictly follow the Fe2O3 ? Fe3O4 ? FeO ? Fe sequence in N2 atmosphere, and this phenomenondid not occur in H2 atmosphere. This gas?solid combination reduction process is appropriate for recovering Fe from Bayer red mud. Meanwhile, the microstructure and phase transformation of the reduction process were investigated via scanning electron microscopy and X-ray diffraction.


2015 ◽  
Vol 73 (4) ◽  
pp. 899-908 ◽  
Author(s):  
A. Alighardashi ◽  
H. R. Gharibi ◽  
Sh. Raygan ◽  
A. Akbarzadeh

Red mud (RM) is the industrial waste of alumina production and causes serious environmental risks. In this paper, a novel activation procedure for RM (mechano-chemical processing) is proposed in order to improve the nitrate adsorption from water. High-energy milling and acidification were selected as mechanical and chemical activation methods, respectively. Synthesized samples of adsorbent were produced considering two parameters of activation: acid concentrations and acidification time in two selected milling times. Optimization of the activation process was based on nitrate removal from a stock solution. Experimental data were analyzed with two-way analysis of variance and Kruskal–Wallis methods to verify and discover the accuracy and probable errors. Best conditions (acceptable removal percentage > 75) were 17.6% w/w for acid concentrate and 19.9 minutes for acidification time in 8 hours for milling time. A direct relationship between increase in nitrate removal and increasing the acid concentration and acidification time was observed. The adsorption isotherms were studied and compared with other nitrate adsorbents. Characterization tests (X-ray fluorescence, X-ray diffraction, Fourier transform infrared spectrophotometry, dynamic light scattering, surface area analysis and scanning electron microscopy) were conducted for both raw and activated adsorbents. Results showed noticeable superiority in characteristics after activation: higher specific area and porosity, lower particle size and lower agglomeration in structure.


2019 ◽  
Vol 69 (333) ◽  
pp. 180 ◽  
Author(s):  
I. Gonzalez-Triviño ◽  
J. Pascual-Cosp ◽  
B. Moreno ◽  
M. Benítez-Guerrero

Red mud (bauxite residue) is an alkaline suspension that is the by-product of alumina production via the Bayer process. Its elevated annual production and the global inventory of red mud determine its valorisation. Granite can be used as a source of fluxing oxides for the ceramic industry, as can the flake-shaped waste generated during the flaming of granite. In this work, a set of ceramic pieces made of red mud and granite waste are prepared and characterised via X-ray diffraction, a hardness test, electron scanning microscopy, a leaching test, and determining open porosity, water absorption, bulk density and flexural strength of the samples. The main crystalline phases in the high-temperature fired products are hematite, pseudobrookite and anorthite; the presence of magnetite reveals their ferrimagnetic character. All samples present high mechanical properties. Leaching results are below critical levels established by regulations.


1996 ◽  
Vol 44 (8) ◽  
pp. 3105-3113 ◽  
Author(s):  
S. Enzo ◽  
R. Frattini ◽  
R. Gupta ◽  
P.P. Macrì ◽  
G. Principi ◽  
...  

2007 ◽  
Vol 2007 (suppl_26) ◽  
pp. 61-66 ◽  
Author(s):  
B. Peplinski ◽  
B. Adamczyk ◽  
G. Kley ◽  
K. Adam ◽  
F. Emmerling ◽  
...  

2013 ◽  
Vol 12 (10) ◽  
pp. 719-726
Author(s):  
R. Ayadi ◽  
Mohamed Boujelbene ◽  
T. Mhiri

The present paper is interested in the study of compounds from the apatite family with the general formula Ca10 (PO4)6A2. It particularly brings to light the exploitation of the distinctive stereochemistries of two Ca positions in apatite. In fact, Gd-Bearing oxyapatiteCa8 Gd2 (PO4)6O2 has been synthesized by solid state reaction and characterized by X-ray powder diffraction. The site occupancies of substituents is0.3333 in Gd and 0.3333 for Ca in the Ca(1) position and 0. 5 for Gd in the Ca (2) position.  Besides, the observed frequencies in the Raman and infrared spectra were explained and discussed on the basis of unit-cell group analyses.


2020 ◽  
Author(s):  
Luzia S. Germann ◽  
Sebastian T. Emmerling ◽  
Manuel Wilke ◽  
Robert E. Dinnebier ◽  
Mariarosa Moneghini ◽  
...  

Time-resolved mechanochemical cocrystallisation studies have so-far focused solely on neat and liquid-assisted grinding. Here, we report the monitoring of polymer-assisted grinding reactions using <i>in situ</i> X-ray powder diffraction, revealing that reaction rate is almost double compared to neat grinding and independent of the molecular weight and amount of used polymer additives.<br>


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