Evaluation of Al-Hf Coating on Ferritic Steels by CVD-FBR Technology in Steam Oxidation

2008 ◽  
Vol 595-598 ◽  
pp. 359-366
Author(s):  
F.J. Bolívar ◽  
L. Sánchez ◽  
M.P. Hierro ◽  
J.A. Trilleros ◽  
F.J. Pérez
Keyword(s):  
Atmospheric Pressure ◽  
Electron Probe ◽  
Ferritic Steel ◽  
Power Plants ◽  
Protective Coatings ◽  
Steam Oxidation ◽  
Ferritic Steels ◽  
Steam Turbines ◽  
Creep Properties ◽  
Good Oxidation Resistance

The steels with chromium contents between 9 and 12%wt are used for power plants with advanced steam conditions. These steels possess good creep properties similar to the 9% Cr steels as well as good creep and good oxidation resistance at temperatures between 500-600°C. In the last years efforts have been made to develop coatings for protection against oxidation in order to allow operation of steam turbines at 650°C. In this study, Al-Hf protective coatings were deposited by CVD-FBR on the ferritic steel HCM-12A followed by a diffusion heat treatment, and were shown to be protective at 650°C under steam for at least 3000 hours of laboratory steam exposure under atmospheric pressure. The morphology and composition of the coatings were characterized by techniques, including scanning electron microscopy (SEM), electron probe microanalysis, and Xray diffraction (XRD). The results showed a substantial increase of steam oxidation protection afforded by Al-Hf coating deposited by the CVD-FBR process.

Evaluation of Si Coating on Ferritic Steels by CVD-FBR Technology in Steam Oxidation

2009 ◽  
Vol 289-292 ◽  
pp. 413-420 ◽  
Author(s):  
F.J. Bolívar ◽  
L. Sánchez ◽  
M.P. Hierro ◽  
F.J. Pérez
Keyword(s):  
Power Plants ◽  
Protective Coatings ◽  
Steam Oxidation ◽  
Steam Turbines ◽  
X Ray Diffraction ◽  
Steam Power ◽  
Factors Affecting ◽  
Steam Power Plants ◽  
Temperature And Pressure ◽  
Major Factors

The development of new power generation plants firing fossil fuel is aiming at achieving higher thermal efficiencies of the energy conversion process. The major factors affecting the efficiency of the conventional steam power plants are the temperature and, to a lesser extent, the pressure of the steam entering the turbine. The increased operating temperature and pressure require new materials that have major oxidation resistance. Due to this problem, in the last years numerous studies have been conducted in order to develop new coatings to enhance the resistance of steels with chromium contents between 9 and 12% wt against steam oxidation in order to allow operation of steam turbines at 650 0C. In this study, Si protective coatings were deposited by CVD-FBR on ferritic steel P-91. These type of coatings have shown to be protective at 650 0C under steam for at least 3000 hours of laboratory steam exposure under atmospheric pressure. Morphology and composition of coatings were characterized by different techniques, such as scanning electron microscopy (SEM), electron probe microanalysis, and X-ray diffraction (XRD). The results show a substantial increase of steam oxidation protection afforded by Si coating by CVD-FBR process.

Al-Mn CVD-FBR Protective for Steam Corrosion Applications

2008 ◽  
Vol 595-598 ◽  
pp. 351-358
Author(s):  
Eugene N'Dah ◽  
F.J. Bolívar ◽  
L. Sánchez ◽  
M.P. Hierro ◽  
Sofia Tsipas ◽  
...  
Keyword(s):  
Oxidation Resistance ◽  
Atmospheric Pressure ◽  
Ternary Phase ◽  
Ternary Phase Diagram ◽  
Protective Coatings ◽  
Steam Turbines ◽  
Phase Constitution ◽  
Experimental Procedure ◽  
Thermo Calc Software ◽  
Initial Process

Ferritic steels are usually used in boiler or supercritical steam turbines which operate at temperatures between 600-650°C under pressure. Protective coatings are often applied in order to increase their oxidation resistance and protect them against degradation. In this study new Al-Mn protective coatings were deposited by CVD-FBR on P92 ferritic steel. The initial process parameters were optimized by thermodynamic calculations using Thermo-Calc software. Then, those parameters were used in the experimental procedure to obtain Al-Mn coatings at low temperature and atmospheric pressure. Co-deposition was achieved at moderate temperatures in order to maintain the substrates` mechanical properties. The coatings` microstructure and phase constitution was characterized. Fe-Al intermetallic coatings containing Cr and Mn were obtained. The phase constitution is discussed with reference to the Fe-Al-Mn ternary phase diagram. The effect of diffusion heat treatment on the phase transformations as well as the steam oxidation resistance of these coatings at 650°C and 800°C was investigated.

scholarly journals Steam Oxidation of Aluminide-Coated and Uncoated TP347HFG Stainless Steel under Atmospheric and Ultra-Supercritical Steam Conditions at 700 °C

Coatings ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 839
Author(s):  
Alina Agüero ◽  
Ignacio Baráibar ◽  
Marcos Gutiérrez ◽  
Satu Tuurna ◽  
Aki Toivonen ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Atmospheric Pressure ◽  
Protective Coatings ◽  
Oxidation Mechanism ◽  
Steam Oxidation ◽  
Austenitic Steels ◽  
Protective Oxide ◽  
Microstructural Investigation ◽  
Aluminide Coatings ◽  
Significant Difference

The efficiency of ultra-supercritical (USC) steam power plants is limited by the materials properties, in particular, the steam oxidation resistance of the currently used steels at temperatures higher than 600 °C. Under these conditions, steam oxidation results in the development of thick oxide scales which spall and can accumulate in tube bends leading to blockage, overheating and premature creep rupture, as well as erosion of downstream components such as steam valves and turbine blades. Most published work related to oxidation testing is carried out at atmospheric pressure, with significantly less testing of austenitic steels in supercritical steam, and rarely including protective coatings. Indeed, the effect of high-pressure steam in the oxidation process is not quite understood at present. This paper covers a comparison of the behaviour of TP347HFG stainless steel at 700 °C under atmospheric pressure and 25 MPa, with and without slurry-applied diffusion aluminide coatings. The results show a very protective behaviour of the aluminide coatings, which develop a very thin Al-rich protective oxide, and no significant difference between the two environments. In contrast, the uncoated steel exhibited a different behaviour. Indeed, under atmospheric pressure after 3000 h, very thin scales, rich in Cr and not surpassing 5 to 10 µm in thickness, covered the samples along with some much thicker Fe-rich oxide nodules (up to 150 µm). However, under 25 MPa, a thick multilayer scale with a non-homogeneous thickness oscillating between 10 to 120 µm was present. A microstructural investigation was undertaken on the oxidised uncoated and coated substrates. The results suggest that pressure increases the oxidation rate of the chromia former steels but that the oxidation mechanism remains the same. A mechanism is proposed, including early detachment of the outer growing scales under supercritical pressure.

The Effect of Co and Cu on the Creep Properties of High Chromium (12%Cr) Ferritic Steel

2011 ◽  
Vol 311-313 ◽  
pp. 944-947
Author(s):  
Xi Xun Shen ◽  
Jun Liang Liu ◽  
Zhou Xu
Keyword(s):  
Ferritic Steel ◽  
Fracture Behavior ◽  
Prior Austenite ◽  
Ferritic Steels ◽  
Creep Properties ◽  
High Chromium ◽  
Δ Ferrite ◽  
Fracture Behaviors ◽  
The Matrix ◽  
Austenite Grains

In this paper, three kinds of 12% Cr ferritic steels without Co and Cu, with 3%Co and with 3%Cu are produced. The addition Co and Cu lead to an evident increase in creep-resistant of the ferritic steel, and furthermore also markedly affect the fracture behavior. Microstructures were studied by comparing three kinds of the 12% ferritic steels to better understand different in those creep behaviors and fracture behaviors. It was found that the addition of Co and Cu not only inhibit the formation δ-ferrite but also are benefit for the growth of prior austenite grains. Additionally, the part of the added Cu precipitates in the matrix of the ferritic steel. These changes in microstructure and the solution of Co and Cu strengthen the ferritic steel.

Microanalysis of precipitates in a ferritic steel

1978 ◽  
Vol 36 (1) ◽  
pp. 618-619
Author(s):  
J.M. Titchmarsh
Keyword(s):  
Ferritic Steel ◽  
Particle Identification ◽  
Energy Dispersive ◽  
Objective Lens ◽  
Ferritic Steels ◽  
Replica Technique ◽  
X Ray ◽  
Large Numbers ◽  
Scanning Transmission ◽  
Made In

The advances in recent years in the microanalytical capabilities of conventional TEM's fitted with probe forming lenses allow much more detailed investigations to be made of the microstructures of complex alloys, such as ferritic steels, than have been possible previously. In particular, the identification of individual precipitate particles with dimensions of a few tens of nanometers in alloys containing high densities of several chemically and crystallographically different precipitate types is feasible. The aim of the investigation described in this paper was to establish a method which allowed individual particle identification to be made in a few seconds so that large numbers of particles could be examined in a few hours.A Philips EM400 microscope, fitted with the scanning transmission (STEM) objective lens pole-pieces and an EDAX energy dispersive X-ray analyser, was used at 120 kV with a thermal W hairpin filament. The precipitates examined were extracted using a standard C replica technique from specimens of a 2¼Cr-lMo ferritic steel in a quenched and tempered condition.

Fault diagnosis method of peak-load-regulation steam turbine based on improved PCA-HKNN artificial neural network

2021 ◽  
pp. 1748006X2110105
Author(s):  
Yifan Wu ◽  
Wei Li ◽  
Deren Sheng ◽  
Jianhong Chen ◽  
Zitao Yu
Keyword(s):  
Neural Network ◽  
Fault Diagnosis ◽  
Steam Turbine ◽  
Power Plants ◽  
Peak Load ◽  
Clean Energy ◽  
Steam Turbines ◽  
Peak Shaving ◽  
Diagnosis Method ◽  
Load Regulation

Clean energy is now developing rapidly, especially in the United States, China, the Britain and the European Union. To ensure the stability of power production and consumption, and to give higher priority to clean energy, it is essential for large power plants to implement peak shaving operation, which means that even the 1000 MW steam turbines in large plants will undertake peak shaving tasks for a long period of time. However, with the peak load regulation, the steam turbines operating in low capacity may be much more likely to cause faults. In this paper, aiming at peak load shaving, a fault diagnosis method of steam turbine vibration has been presented. The major models, namely hierarchy-KNN model on the basis of improved principal component analysis (Improved PCA-HKNN) has been discussed in detail. Additionally, a new fault diagnosis method has been proposed. By applying the PCA improved by information entropy, the vibration and thermal original data are decomposed and classified into a finite number of characteristic parameters and factor matrices. For the peak shaving power plants, the peak load shaving state involving their methods of operation and results of vibration would be elaborated further. Combined with the data and the operation state, the HKNN model is established to carry out the fault diagnosis. Finally, the efficiency and reliability of the improved PCA-HKNN model is discussed. It’s indicated that compared with the traditional method, especially handling the large data, this model enhances the convergence speed and the anti-interference ability of the neural network, reduces the training time and diagnosis time by more than 50%, improving the reliability of the diagnosis from 76% to 97%.

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