scholarly journals Factors Affecting the Setting Time of Fly Ash-Based Geopolymer

2016 ◽  
Vol 841 ◽  
pp. 90-97 ◽  
Author(s):  
Antoni ◽  
Stephen Wibiatma Wijaya ◽  
Djwantoro Hardjito
Keyword(s):  
Fly Ash ◽  
Initial Temperature ◽  
Ph Value ◽  
Setting Time ◽  
Chemical Properties ◽  
Curing Temperature ◽  
Factors Affecting ◽  
Ph Values ◽  
Physical And Chemical ◽  
And Chemical Properties

Fly ash is a waste from coal burning, that are generated with fluctuation both in its physical and chemical characteristics. This characteristics of fly ash when used in the making of geopolymer concrete will greatly affect the final products obtained. The pH value measured in fly ash, according previous research, can influence the setting time of geopolymer and fly ash with high pH values can cause flash-setting in the concrete. Understanding more clearly about the factors that affect the setting time of fly ash based geopolymer is important for further progress and development of the material. It was found that factors that influence the setting time of geopolymer was not only from the physical and chemical properties of the fly ash itself. Other factors such as composition and mix design, manufacturing process and environmental conditions can also affect its setting time. The experimental results showed that fly ash particle size, CaO and MgO content, in addition to ratio of sodium silicate and sodium hydroxide in the alkali solution, molarity of NaOH, initial temperature of the mixture, curing temperature, and mix volume could potentially influence the setting time of the geopolymer mixture.

scholarly journals Effects of Continuous Cropping of Dictyophora on Soil Physical and Chemical Properties, Microbial Biomass and Enzyme Activity

2021 ◽  
Vol 8 (7) ◽  
pp. 214-220
Author(s):  
Long Tong ◽  
◽  
Hongyan Li ◽  
Xiaoming Liu ◽  
Bin Li ◽  
...  
Keyword(s):  
Enzyme Activity ◽  
Ph Value ◽  
Chemical Properties ◽  
Available Phosphorus ◽  
Continuous Cropping ◽  
Physical And Chemical Properties ◽  
Factors Affecting ◽  
The One ◽  
Physical And Chemical ◽  
And Chemical Properties

The continuous obstacle of Dictyophora indusiata has become the one of the main factors affecting the healthy development of D. indusiata industry. In order to study the effects of continuous cropping of D. indusiata on the soil environment, four treatments were used in this study: no planted (CK), planted for 1 years (1Y), continuous cropping for 2 years (2Y) and continuous cropping for 3 years (3Y), to determined of the yield of D. indusiata, soil physical and chemical properties, microbial content and enzyme activity. The results showed that the yield and soil pH value decreased with the increase of continuous cropping years, and the contents of organic matter, total nitrogen, total phosphorus and total potassium, C/N and C/P also increased with the increase of continuous cropping years. Soil availability decreased with the increase of continuous cropping years, the content of alkaline nitrogen, available phosphorus and available potassium decreased by 12.25%, 28.91% and 24.86% at 3Y compared with 1Y, respectively. The biomass of bacteria, actinomycetes and fungi and the total amount of microorganism in soil increased at 1Y compared with CK, but with the increase of continuous cropping years, the biomass of bacteria and actinomycetes and the total amount of microorganism decreased significantly, while the biomass of fungi increased significantly; the continuous cropping of D. indusiata also decreased the value of bacteria/fungi in soil. The enzyme activities of the soil were higher than those of the unplanted plots, however, the activities of urease, catalase, peroxidase, sucrase, phosphatase and protease decreased with the increase of continuous cropping years. In a word, with the increase of continuous cropping, the acidity of rhizosphere soil increased, the availability of soil nutrients and the activity of soil enzymes decreased, the biomass of soil microorganisms, bacteria and actinomycetes decreased. However, the increase of fungal biomass led to the decline of soil texture.

scholarly journals Influence of the Addition of Calcium Hydroxide Powder on Some Physical and Chemical Properties of the Sealer MTA Fillapex

2012 ◽  
Vol 3 (2) ◽  
pp. 180-183
Author(s):  
Marcelo Ferrarezi de Andrade ◽  
Renato de Toledo Leonardo ◽  
Edson Alves de Campos ◽  
Milton Carlos Kuga ◽  
Marco Antonio Hungaro Duarte ◽  
...  
Keyword(s):  
Calcium Hydroxide ◽  
Calcium Release ◽  
Ph Value ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Ph Values ◽  
The One ◽  
Physical And Chemical ◽  
The Impact ◽  
And Chemical Properties

ABSTRACT Objective This study evaluated the flow, pH and calcium release of MTA Fillapex (G1) or Fillapex plus 10% in weight of calcium hydroxide powder (G2), compared to AH Plus (G3) and Sealapex (G4). Materials and methods The flow test was performed according to ISO 6876:2001 requirements. The sealers were placed into plastic tubes and immersed in deionized water. After 24 hours, 7, 14 and 28 days, the water of each tube was removed and tested to evaluate the pH values and the level of released calcium. Calcium release values were analyzed statistically by Kruskal Wallis and Dunn tests and pH values analyzed by ANOVA and Tukey tests (α = 5%). Results G1 presented higher flow among all sealers. The addition of 10% calcium hydroxide into MTA Fillapex reduced the flow (p < 0.05) but, in a level, that is lower than the one recommended for ISO norms. G2 and G4 presented pH values and calcium release higher than G3 (p < 0.05) in all periods. G1 presented pH value higher than G3 (p < 0.05), except in 7 days period (p > 0.05). G4 presented higher pH values than G1 and G2, but the calcium release was similar for all periods (p > 0.05). G3 presented lower calcium release among all groups (p < 0.05). Conclusion The addition of 10% calcium hydroxide in MTA Fillapex caused reduction in flow and no negative interference in pH and/or calcium release. However, the obtained flow is different from ISO requirements. Clinical relevance MTA Fillapex presents levels of flow above the ISO norms. The addition of calcium hydroxide is a suggestion for solving this problem, but the impact of these procedures should be carefully evaluated. How to cite this article Keine KC, Guiotti FA, Leonardo RT, Kuga MC, Duarte MAH, de Campos EA, de Andrade MF. Influence of the Addition of Calcium Hydroxide Powder on Some Physical and Chemical Properties of the Sealer MTA Fillapex. World J Dent 2012;3(2):180-183.

Monitoring of Fluctuations in the Physical and Chemical Properties of a High-Calcium Fly Ash

1987 ◽  
Vol 113 ◽  
Author(s):  
Scott Schlorholtz ◽  
Ken Bergeson ◽  
Turgut Demirel
Keyword(s):  
Fly Ash ◽  
Chemical Properties ◽  
Operating Conditions ◽  
Physical And Chemical Properties ◽  
X Ray Diffraction ◽  
X Ray ◽  
Morphological Studies ◽  
High Calcium ◽  
Physical And Chemical ◽  
And Chemical Properties

ABSTRACTThe physical and chemical properties of fly ash produced at Ottumwa Generating Station have been monitored since April, 1985. The fly ash is produced from burning a low sulfur, sub-bituminous coal obtained from the Powder River Basin near Gillette, Wyoming. One-hundred and sixty samples of fly ash were obtained during the two year period. All of the samples were subjected to physical testing as specified by ASTM C 311. About one-hundred of the samples were also subjected to a series of tests designed to monitor the self-cementing properties of the fly ash. Many of the fly ash samples were subjected to x-ray diffraction and fluorescence analysis to define the mineralogical and chemical composition of the bulk fly ash as a function of sampling date. Hydration products in selected hardened fly ash pastes, were studied by x-ray diffraction and scanning electron microscopy. The studies indicated that power plant operating conditions influenced the compressive strength of the fly ash paste specimens. Mineralogical and morphological studies of the fly ash pastes indicated that stratlingite formation occurred in the highstrength specimens, while ettringite was the major hydration product evident in the low-strength specimens.

Influence of Fluidized Fly Ash on the Selected Physical-Mechanical Properties of the Autoclaved Aerated Concrete

2014 ◽  
Vol 899 ◽  
pp. 409-414 ◽  
Author(s):  
Alena Struhárová ◽  
Stanislav Unčík ◽  
Svetozár Balkovic ◽  
Mária Hlavinková
Keyword(s):  
Mechanical Properties ◽  
Fly Ash ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Amorphous Phases ◽  
Autoclaved Aerated Concrete ◽  
Aerated Concrete ◽  
Free Cao ◽  
Physical And Chemical ◽  
And Chemical Properties

Fluidized fly ash has different physical and chemical properties compared to fly ash emerging from classic combustion. It contains amorphous phases resulting from a dehydration of clay minerals as well as unreacted sorbent of CaCO3, free CaO and anhydrite (CaSO4). Work targets the possibilities of production of an autoclaved aerated concrete (AAC) from fluidized fly ash, and its influence on particular physical-mechanical properties of autoclaved aerated concrete.

scholarly journals PEMAKAIAN FLY-ASH SEBAGAI CEMENTITIOUS PADA BETON MUTU TINGGI DENGAN STEAM CURING (THE USE OF FLY-ASH AS CEMENTITIOUS ON HIGH-STRENGTH CONCRETE WITH STEAM CURING)

2014 ◽  
Vol 10 (2) ◽  
Author(s):  
Erwin Rommel ◽  
Yunan Rusdianto
Keyword(s):  
Fly Ash ◽  
Precast Concrete ◽  
Chemical Properties ◽  
High Strength ◽  
Steam Curing ◽  
Initial Strength ◽  
Speed Up ◽  
Physical And Chemical ◽  
And Chemical Properties

Erwin Rommel1 & Yunan Rusdianto2Jurusan Teknik Sipil Fakultas Teknik Universitas Muhammadiyah MalangAlamat Korespondensi :Jalan Raya Tlogomas 246 Malang 65144email : [email protected] HP 08123314432ABSTRACTThe use of fly-ash as cementitious will be made to utilize physical and chemical properties offly-ash that has a dominan of silica and good of modulus fines. The use of steam curing will be donein this study which can speed up the cycle of making concrete. This is advantageous in the productionof precast concrete and velocity field construction.The research was conducted by making concrete cube 15x15x15 cm for 80 pieces and thentested the compressive strength and absorption of concrete. Achieve the quality of concrete madewith the provision of K600 with giving the fly-ash respectively 7.5%, 15% and 30% by weight ofcement.The results of the research obtained by the use of fly-ash as much as 7.5% as a cementitiousthat was given to the steam curing will provide the initial strength of concrete reached 47% ofcompressive strength at 28 days. While the effect of giving fly-ash in concrete has not seen absorptionsignificantly when compared to concrete without fly-ash.Key word : concrete, fly-ash, steam curing

Application of a-SiO2 Rich Additives in Cement Paste

2015 ◽  
Vol 749 ◽  
pp. 362-367 ◽  
Author(s):  
Jaroslav Pokorný ◽  
Milena Pavlíková ◽  
Eva Navrátilová ◽  
Pavla Rovnaníková ◽  
Zbyšek Pavlík ◽  
...  
Keyword(s):  
Cement Paste ◽  
Bending Strength ◽  
Setting Time ◽  
Chemical Properties ◽  
Xrd Analysis ◽  
Fast Reaction ◽  
Cement Pastes ◽  
Matrix Density ◽  
Physical And Chemical ◽  
And Chemical Properties

The effect of a-SiO2 of various origin on the properties of cement paste with incorporated different silica containing materials is experimentally studied in the paper. For the applied a-SiO2 materials, basic physical and chemical properties are accessed, together with their chemical composition. Amount of amorphous phase of SiO2 in particular siliceous materials is determined using XRD analysis. Matrix density, bulk density, total open porosity, compressive and bending strength are measured for all developed pastes with incorporated a-SiO2 containing materials, together with initial and final setting time of fresh mixtures. The obtained data give evidence on a high and fast reaction activity of tested siliceous materials which results in a significant improvement of porosity and mechanical strength of a-SiO2 modified cement pastes.

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