Regulation of Mechanical Properties of Advanced PCM Products with the Aid of Catalysts

2020 ◽  
Vol 992 ◽  
pp. 415-420
Author(s):  
I.V. Zaychenko ◽  
V.V. Bazheryanu ◽  
A.G. Kim

The article considers the problem of the effect of uneven curing caused by the temperature gradient across the thickness of the material on the anisotropy of the strength properties of polymer composite materials. The effect of catalysts on the curing of the epoxy binder EDT-69N, used for the manufacture of multilayer polymer composite materials, was studied. According to dielectric spectrometry, the accelerating effect of the selected compounds on the curing process of the EDT-69N epoxy binder during fiberglass molding has been proved. The possibility of controlling the curing process using catalysts to reduce the influence of the temperature gradient on the anisotropy of the strength properties of the matrix in the manufacture of polymer composite materials is shown.

2021 ◽  
pp. 28-34
Author(s):  
E. A. Kosenko ◽  
◽  
P. E. Demin ◽  

The mechanical properties of polymer composite materials largely depend on the interfacial phenomena occurring on the interface between the matrix and reinforcing material. The addition of components to the matrix of polymer composite materials that retain their viscoelastic state during the molding process of the products makes possible to locally change the deformation-and-strength properties of a finished product, adapting it to the specified operating conditions. The viscoelastic components in the hybrid matrix form the third phase of the polymer composite material. Increasing the efficiency of interfacial layers of polymer composite materials with various types of hybrid matrices is the most important task of their development. The samples for microanalysis of the polymer composite material structure with various types of hybrid matrices were molded using the prepreg technology by vacuum molding on the basis of BT400 biaxial basalt fabric. Technical wax, anaerobic (Loctite 638) and organosilicon (Yunisil-9628) polymer materials were selected as the viscoelastic components of the hybrid matrix. In order to explain the reasons for the change in the deformation-and-strength properties of the obtained basalt plastics with various viscoelastic components in the composition of the hybrid matrix, microanalysis of their structure was carried out. A mechanism for choosing a scheme for the location of viscoelastic components in a matrix of polymer composite materials based on the provisions of combinatorial optimization is described.


The expanding range of components intended for manufacturing products of polymer composite materials is often not accompanied by comprehensive information on the characteristics and recommended technological curing modes. The relevance and practical significance of this investigation are based on the need to predict rational technological modes for curing products of polymer composite materials based on the low-viscosity epoxy binder Etal-Inject-SLM, which is in demand in the manufacture of products from polymer composite materials by cold curing. The purpose of this investigation is to determine kinetic patterns, which allow for predicting the time and degree of curing of the low-viscosity epoxy binder Etal-Inject-SLM for various isothermal curing conditions. The method of differential scanning calorimetry was used to measure the thermal effect of the curing reaction of the Etal-Inject-SLM epoxy binder at various heating rates. Based on the experimental calorimetric data and using the model-free (non-prior) Friedman method, using the specialized software Netzsch Kinetics Neo, the parameters characterizing the formal kinetic laws of the curing process were calculated. This allowed for plotting isothermal and iso-conversion thermokinetic diagrams necessary for predicting the time and degree of curing of the Etal-Inject-SLM binder at different temperatures and curing times. This results can be useful for optimizing technological processes in which the low-viscosity epoxy binder Etal-Inject-SLM is used.


A study review of aging polymer composite materials (PCM) under different heat-moisture conditions or water exposure with the sequential or parallel influence of static or cyclic loads in laboratory conditions is presented. The influence of tension and bending loads is compared. Conditions of the different load influence on parameters of carbon-reinforced plastics and glass-reinforced plastics are discussed. Equipment and units for climatic tests of PCM under loading are described. Simulation examples of indices of mechanical properties of PCM under the influence of environment and loads are shown.


A study review of aging polymer composite materials (PCM) under different heat-moisture conditions or water exposure with the sequential or parallel influence of static or cyclic loads in laboratory conditions is presented. The influence of tension and bending loads is compared. Conditions of the different load influence on parameters of carbon-reinforced plastics and glass-reinforced plastics are discussed. Equipment and units for climatic tests of PCM under loading are described. Simulation examples of indices of mechanical properties of PCM under the influence of environment and loads are shown.


Author(s):  
I. V. Zlobina

Based on studies of the microstructure of the matrix of cured polymer composite materials and the area of its contact interaction with reinforcing fibers, the hypothesis of its structuring in the microwave electromagnetic field with an increase in the contact interaction surfaces due to an increase in the number of agglomerates with small transverse dimensions and a decrease in porosity in the macro- and mesopore regions is substantiated. These effects can be used as a basis for increasing the strength characteristics and uniformity of their values after exposure to a microwave electromagnetic field. The results of this work can be used in the development of technologies for finishing hardening of products made of carbon and fiberglass for various transport and energy systems.


Author(s):  
Alsaid Mazen ◽  
Ali Salamekh

In the last decades there is increasing the need to apply polymer composite materials in different industries, particularly in shipbuilding. There are developing single structures made from polymer composite materials to be used on board ships. The article focuses on technology of manufacturing slabs from polymer composite materials to carry out mechanical testing in the laboratory special standard units. Mechanical properties of polymer composite materials depend on molding technologies. There has been described a technology of sample manufacturing from polymer composite materials reinforced with glass fiber mat with fiberglass plastics. The technique of testing the specified samples for tensile strength has been considered. The sizes and shapes of the samples as well as the technological parameters of the manufacturing process have been validated, depending on the standard requirements and the technological features of the testing machine. The physical and mechanical properties of the components that make up the composite materials are considered. The sequence of stacking layers for preparation of plates from composite materials is indicated. The dimensions of the plates for cutting out finished samples are determined, depending on the method of production. The way of laying plates from composite materials has been chosen on the base of economic considerations and conditions of accessibility. The obtained results of mechanical properties can be used in solving problems of application of polymer composite materials in shipbuilding, for example, in manufacturing superstructures of some dry cargo vessels.


Author(s):  
S. Anilkumar ◽  
K. Arumugam ◽  
Venkata Ramarao Mutyala ◽  
K. Kodanda Ram ◽  
T.S. Krishna Kumar

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