Pseudocapacitive Behavior of Ni(OH)2/NiO Hierarchical Structures Grown on Carbon Fiber Paper

2017 ◽  
Vol 266 ◽  
pp. 177-181 ◽  
Author(s):  
Luigi A. Dahonog ◽  
Joey D. Ocon ◽  
Mary Donnabelle L. Balela

Transition metal oxides and hydroxides, specifically nickel (Ni), are currently being studied for their pseudocapacitive behaviors due to their high specific capacitance and efficient redox reactions. In this study, nickel oxide (NiO) and nickel hydroxide [Ni (OH)2] hierarchical structures were grown on carbon fiber paper via hydrothermal treatment for a binder-free electrode for pseudocapacitor. Cyclic voltammetry was employed to determine the influence of annealing temperature on the specific capacitance of NiO-and/or Ni (OH)2 – carbon fiber electrodes. The NiO – carbon fiber electrode annealed at 400°C exhibited the highest specific capacitance of about 1993.12 F/g at a scan rate of 2 mV/s. The carbon fibers were fully covered by NiO platelets which possibly provide efficient transport of electrolyte, enhancing the capacitance.

2019 ◽  
Vol 7 (22) ◽  
pp. 13495-13505 ◽  
Author(s):  
Cheong Hoon Kwon ◽  
Yongmin Ko ◽  
Dongyeeb Shin ◽  
Seung Woo Lee ◽  
Jinhan Cho

Au nanoparticle-coated highly conductive carbon fiber electrodes for high-power glucose-biofuel cells were developed based on a layer-by-layer assembling method.


2020 ◽  
Vol 4 (3) ◽  
pp. 1320-1331 ◽  
Author(s):  
Rohit G. Jadhav ◽  
Devraj Singh ◽  
Shaikh M. Mobin ◽  
Apurba K. Das

A binder-free electrodeposited organic–inorganic multifunctional nanohybrid electrode exhibits high specific capacitance with electrocatalytic water splitting performance.


2015 ◽  
Vol 17 (44) ◽  
pp. 29874-29879 ◽  
Author(s):  
MinHo Yang ◽  
Seok Bok Hong ◽  
Bong Gill Choi

Hierarchical core/shell structured arrays of MnO2@polyaniline nanosheets synthesized on the surface of carbon fiber paper, showed high specific capacitance, high rate capability, and good cycle life.


MRS Advances ◽  
2020 ◽  
pp. 1-8
Author(s):  
D. Guragain ◽  
C. Zequine ◽  
R. Bhattarai ◽  
J. Choi ◽  
R. K. Gupta ◽  
...  

ABSTRACT The binary metal oxides are increasingly used as supercapacitor electrode materials in energy storing devices. Particularly NiCo2O4 has shown promising electrocapacitive performance with high specific capacitance and energy density. The electrocapacitive performance of these oxides largely depends on their morphology and electrical properties governed by their energy band-gaps and defects. The morphological structure of NiCo2O4 can be altered via the synthesis route, while the energy band-gap could be altered by doping. Also, doping can enhance crystal stability and bring in grain refinement, which can further improve the much-needed surface area for high specific capacitance. Given the above, this study evaluates the electrochemical performance of Ca-doped Ni1-xCaxCo2O4 (0 ≤ x ≤ 0.8) compounds. This stipulates promising applications for electrodes in future supercapacitors.


2017 ◽  
Vol 28 (17) ◽  
pp. 12747-12754 ◽  
Author(s):  
Feng Huang ◽  
Aihua Yan ◽  
Yanwei Sui ◽  
Fuxiang Wei ◽  
Jiqiu Qi ◽  
...  

2018 ◽  
Vol 11 (02) ◽  
pp. 1850034 ◽  
Author(s):  
Congcong Hong ◽  
Xing Wang ◽  
Houlin Yu ◽  
Huaping Wu ◽  
Jianshan Wang ◽  
...  

Manganese dioxide nanowires (MnO2 NWs) anchored on carbon fiber cloth (CFC) were fabricated through a simple hydrothermal reaction and used as integrated electrodes for supercapacitor. The morphology-dependent electrochemical performance of MnO2 NWs was confirmed, yielding good capacitance performance with a high specific capacitance of 3.88[Formula: see text][Formula: see text] at a charge–discharge current density of 5[Formula: see text][Formula: see text] and excellent stability of 91.5% capacitance retention after 3000 cycles. Moreover, the composite electrodes were used to fabricate supercapacitors, which showed a high specific capacitance of 194[Formula: see text][Formula: see text] at a charge–discharge current density of 2[Formula: see text][Formula: see text] and high energy density of 0.108[Formula: see text][Formula: see text] at power density of 2[Formula: see text][Formula: see text], foreboding its potential application for high-performance supercapacitor.


2015 ◽  
Vol 51 (38) ◽  
pp. 8066-8069 ◽  
Author(s):  
Shichao Du ◽  
Zhiyu Ren ◽  
Jun Zhang ◽  
Jun Wu ◽  
Wang Xi ◽  
...  

A large-area, self-supported Co3O4 nanocrystal/carbon fiber electrode for oxygen and hydrogen evolution reaction was fabricated via thermal decomposition of the [Co(NH3)n]2+–oleic acid complex and subsequent spray deposition.


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