EXTRACTION OF BORON FROM CSSC REFERENCE SOILS BY HOT WATER, DILUTE CaCl2 AND MANNITOL-CaCl2 SOLUTIONS

1986 ◽  
Vol 66 (2) ◽  
pp. 377-381 ◽  
Author(s):  
P. A. SCHUPPLI
Keyword(s):  
Key Words ◽  
Soil Samples ◽  
Water Soluble ◽  
Hot Water ◽  
Distilled Water ◽  
Background Color ◽  
Color Development ◽  
Reference Soil ◽  
Highly Correlated

Soils were extracted by hot water, dilute CaCl2, and by mannitol-CaCl2 solutions and boron was determined by either azomethine-H or the curcumin method. Results were strongly method dependent; in particular results by the simplest method, mannitol-CaCl2, were generally lower and not highly correlated (r = 0.64) with those by the recommended procedure. This procedure involves extraction with hot distilled H2O (2:1 solution:soil), centrifugation, filtration, color development with azomethine-H and correction for background color. Extractable boron values by this procedure ranged from 0.1 to 1.4 mg kg−1. Background color can be further reduced by the substitution of 0.02 M CaCl2 for distilled water. Key words: CSSC reference soil samples, hot-water-soluble boron

scholarly journals Effect of Different Doses of Nutrients on Changes of Soil Organic Matter in Rendzic Leptosol

2012 ◽  
Vol 58 (4) ◽  
pp. 131-137
Author(s):  
Vladimír Šimanský ◽  
Erika Tobiašová
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Soil Samples ◽  
Water Soluble ◽  
Hot Water ◽  
Fertilizer Treatment ◽  
Content Increase ◽  
Npk Fertilizer ◽  
Different Doses

Abstract The effect of different doses of NPK fertilizer on the changes in quantity and quality of soil organic matter (SOM) in Rendzic Leptosol was evaluated. Soil samples were taken from three treatments of different fertilization: (1) control - without fertilization, (2) NPK 1 - doses of NPK fertilizer in 1st degree intensity for vine, and (3) NPK 3 - doses of NPK fertilizer in 3rd degree intensity for vine in the vineyard. Soil samples were collected in years 2008-2011 during the spring. The higher dose of NPK fertilizer (3rd degree intensity of vineyards fertilization) was responsible for the higher content of labile carbon (by 21% in 0-0.3 m and by 11% as average of the two depths 0-0.3 m and 0.3-0.6 m). However, by application of a higher dose of NPK (1.39%) in comparison to no fertilizer treatment (1.35%) or NPK 1 (1.35%) the tendency of total organic carbon content increase and hot-water soluble carbon decrease were determined. Fertilization had a negative effect on SOM stability. Intensity of fertilization affected the changes in quantity and quality of SOM; therefore it is very important to pay attention to the quantity and quality of organic matter in productive vineyards.

TOTAL FLUORINE IN CSSC REFERENCE SOIL SAMPLES

1985 ◽  
Vol 65 (3) ◽  
pp. 605-607 ◽  
Author(s):  
P. A. SCHUPPLI
Keyword(s):  
Nitric Acid ◽  
Acid Solution ◽  
Key Words ◽  
Nitric Acid Solution ◽  
Soil Samples ◽  
Solution Technique ◽  
Reference Soil ◽  
Lithium Metaborate ◽  
Canadian Soils ◽  
Fluoride Electrode

Total fluorine was measured in a variety of Canadian soils using the lithium metaborate-nitric acid solution technique in conjunction with the fluoride electrode. Total fluorine ranged from 90 to 1000 mg∙kg−1. Key words: Soil fluorine analysis, fluoride electrode, CSSC reference soil samples

scholarly journals Risk of phosphorus loss in surface runoff from agricultural land in the Baltic Commune of Puck

2019 ◽  
Author(s):  
Stefan Pietrzak ◽  
Grażyna Pazikowska-Sapota ◽  
Grażyna Dembska ◽  
Lidia Anita Dzierzbicka-Glowacka ◽  
Dominika Juszkowska ◽  
...  
Keyword(s):  
Surface Runoff ◽  
Agricultural Land ◽  
Water Extract ◽  
Soil Samples ◽  
Water Soluble ◽  
Organic Soils ◽  
Distilled Water ◽  
Degree Of P Saturation ◽  
P Content ◽  
Mineral Soils

Background. Risk assessment of Phosphorus (P) losses in surface runoff from agricultural land is the basic measure that should be used as a part of actions taken to counteract the water eutrophication in watercourses and water reservoirs. To assess this risk, a new method has been recently developed based on the determination of degree of P saturation (DPS) which depends on P content in soil determined with the use of distilled water (water-soluble P – WSP). Methods. Based on DPS method, the risk of P losses in surface runoff from agricultural land in Puck Commune (Baltic Sea Coast) was assessed and a critical analysis of assessment results was carried out. The research was conducted on mineral and organic soils from 50 and 11 separate agricultural plots with a total area of 133.82 and 37.23 ha, respectively. In collected soil samples, P content was determined using distilled water (all soil samples), Egner-Riehm method (mineral soils) and extract of 0.5 mol HCl ∙ dm-3 (organic soils). The results of determinations P content in water extract from soils were converted to DPS values, which were classified by appropriate limit intervals. Results & Discussion. It was found that on 96.7% of tested agricultural parcels (96% plots with mineral soils and 100% plots with organic soils) there was a potentially high risk of P losses from soil by surface runoff. At the same time, it was ascertained that in soils from 62% of agricultural plots, there was a large deficiency of plant available P. Due to the above, as well as due to the lack of connection with other factors affecting the P losses in surface runoff such as type of crop and area inclination, it was considered that the assessment based on the DPS index may be unreliable.

scholarly journals A Low-Cost Assembly for Extraction of Hot Calcium Chloride Extractable Boron from Soil Samples

Agropedology ◽  
2019 ◽  
Vol 30 (2) ◽  
Author(s):  
P.C. Srivastava ◽  
◽  
S.P. Pachauri ◽  
Keyword(s):  
Low Cost ◽  
Calcareous Soils ◽  
Soil Samples ◽  
Water Soluble ◽  
Hot Water ◽  
Condenser Tube ◽  
Reflux Condenser ◽  
Hot Plate ◽  
Indian Agriculture ◽  
Different Soils

Among micronutrients, boron (B) occupies a prime place next to zinc (Zn) in Indian Agriculture. Acidic soils, coarse-textured soils subjected to leaching in high rainfall areas, and calcareous soils are likely to be deficient in B (Srivastava and Gupta 1996). According to an estimate based on soil testing of more than two lakh samples drawn from 508 districts of India indicated that 23.2 percent of soil samples are deficient in B (Shukla et al. 2019). Though there are several methods for the analysis of B in soils yet hot water-soluble B (Berger and Truog 1940; Gupta 1967) or dilute CaCl2 extractable B (Cartwright et al. 1983; Adams et al. 1991) are widely adopted for different soils all over the World (Diana 2008). The assembly adopted for the extraction of hot water soluble or dilute CaCl2 extractable B is costly as it requires the use of low B glass or quartz boiling flask equipped with a condenser tube for refluxing (Parker and Gardner 1981) which generally poses difficulty in handling and maintenance. Schuppli (1986) used a Teflon Erlenmeyer flask (125 ml) capacity attached to a Teflon reflux condenser to extract hot water-soluble B from soils, and an asbestos mat was placed between the hot plate and the flask to prevent damage to the Teflon flask. This publication proposes a low-cost assembly to extract hot water-soluble or hot CaCl2 extractable B in soils.

scholarly journals Carbon fraction concentrations in a haplic Luvisol as affected by tillage

2014 ◽  
Vol 60 (No. 6) ◽  
pp. 262-266 ◽  
Author(s):  
J. Horáček ◽  
E. Strosser ◽  
V. Čechová
Keyword(s):  
Cultural Practices ◽  
Fulvic Acids ◽  
Soil Samples ◽  
Water Soluble ◽  
Hot Water ◽  
Protection Measures ◽  
Humus Substances ◽  
Conventional Ct ◽  
Soluble Carbon

Changes of soil organic matter (SOM) parameters were investigated in a haplic Luvisol with medium-heavy texture. Soil samples were taken from several layers at minimum (MT) and conventional (CT) tillage plots of a field experiment in Sitzenhof (Germany). All cultural practices except for tillage (crop rotation, fertilizing, protection measures, etc.) were identical over the whole time of the experiment. The concentrations of oxidizable carbon C<sub>ox</sub> and its constituents (humic acids (HA), fulvic acids (FA), and hot-water soluble carbon) are comparable in layers&nbsp;15&ndash;20 cm in both variants. In 0&ndash;15 cm and 30&ndash;55 cm layers, these concentrations were higher in the MT variant. A similar trend was observed in the colour quotient values of humic substances Q4/6, which indicates increasing condensation of humus substances (HS) at deeper layers in both variants, and it is also confirmed by a humic to fulvic acids ratio HA:FA. Concentrations of SOM fractions were higher (except 15&ndash;20 cm layers) in the MT than CT treatment throughout the profile, especially below the 30 cm depth. The SOM did not accumulate markedly in the surface layer of long-term MT treatment.

scholarly journals Status of Sulphur and Boron in Soils of North Gujarat Region of India

Agropedology ◽  
2019 ◽  
Vol 30 (2) ◽  
Author(s):  
V. P. Ramani ◽  
◽  
K.C. Patel ◽  
Dileep Kumar ◽  
K. P. Patel ◽  
...  
Keyword(s):  
Large Scale ◽  
Mean Value ◽  
Soil Samples ◽  
Water Soluble ◽  
Hot Water ◽  
Low Fertility ◽  
Fertility Level ◽  
S Deficiency ◽  
Nutrient Index ◽  
North Gujarat

The soils of North Gujarat region's were assessed for its Sulphur and Boron status due to its visible deficiency in plants. Study was conducted in three districts viz., Sabarkantha, Mehsana and Patan from which 60, 110 and 52 villages were selected and soils samples were collected with geo-tagging. A total of 1332 surface soil samples (Sabarkantha 360, Mehsana 660 and Patan 312) were collected from these respective districts. Analysis of these soil samples showed a wide variation in soil pH (6.04-9.72) from slightly acidic to alkaline. Organic carbon (OC) content ranged from 1.0 to 7.1 g kg-1, about 90, 65 and 74% of soil samples were found to be under the low OC in Mehsana, Sabarkantha and Patan districts, respectively. Available S content ranged from 1.7 to 68.5 mg kg-1 with a mean value of 15.6, 14.7 and 14.9 mg kg-1 in Mehsana, Sabarkantha and Patan districts, respectively. S deficiency in soils of all three districts was 18.1, 25.5 and 16.9 per cent, which appeared in medium-fertility class level as per Nutrient Index Value (NIV). The high magnitude of S deficiency was noticed in soils of Idar taluka (43.9 %) followed by Khedbrahma taluka (40.9%) of Sabarkantha district, showing medium-fertility class. Further, these samples were also found deficient in hot water-soluble boron (HWS-B) and it ranged from 0.06 to 3.12 mg kg-1 with a mean value of 0.44, 0.45 and 0.44 mg kg-1 in districts of Mehsana, Sabarkantha and Patan, respectively. The NIV indicated B fertility level of low to high. Per cent deficiency of B recorded about 29.4, 17.9 and 19.2 per cent in all three districts. A large scale of B deficiency was noticed in Satlasna taluka (52.4 %) of Mehsana district, which showed low fertility class.

scholarly journals Risk of phosphorus loss in surface runoff from agricultural land in the Baltic Commune of Puck

2019 ◽  
Author(s):  
Stefan Pietrzak ◽  
Grażyna Pazikowska-Sapota ◽  
Grażyna Dembska ◽  
Lidia Anita Dzierzbicka-Glowacka ◽  
Dominika Juszkowska ◽  
...  
Keyword(s):  
Surface Runoff ◽  
Agricultural Land ◽  
Water Extract ◽  
Soil Samples ◽  
Water Soluble ◽  
Organic Soils ◽  
Distilled Water ◽  
Degree Of P Saturation ◽  
P Content ◽  
Mineral Soils

Background. Risk assessment of Phosphorus (P) losses in surface runoff from agricultural land is the basic measure that should be used as a part of actions taken to counteract the water eutrophication in watercourses and water reservoirs. To assess this risk, a new method has been recently developed based on the determination of degree of P saturation (DPS) which depends on P content in soil determined with the use of distilled water (water-soluble P – WSP). Methods. Based on DPS method, the risk of P losses in surface runoff from agricultural land in Puck Commune (Baltic Sea Coast) was assessed and a critical analysis of assessment results was carried out. The research was conducted on mineral and organic soils from 50 and 11 separate agricultural plots with a total area of 133.82 and 37.23 ha, respectively. In collected soil samples, P content was determined using distilled water (all soil samples), Egner-Riehm method (mineral soils) and extract of 0.5 mol HCl ∙ dm-3 (organic soils). The results of determinations P content in water extract from soils were converted to DPS values, which were classified by appropriate limit intervals. Results & Discussion. It was found that on 96.7% of tested agricultural parcels (96% plots with mineral soils and 100% plots with organic soils) there was a potentially high risk of P losses from soil by surface runoff. At the same time, it was ascertained that in soils from 62% of agricultural plots, there was a large deficiency of plant available P. Due to the above, as well as due to the lack of connection with other factors affecting the P losses in surface runoff such as type of crop and area inclination, it was considered that the assessment based on the DPS index may be unreliable.

Characterization of dissolved organic matter (DOM) extracted from soils by hot water percolation (HWP)

2010 ◽  
Vol 59 (1) ◽  
pp. 99-108 ◽  
Author(s):  
M. Takács ◽  
Gy. Füleky
Keyword(s):  
Organic Matter ◽  
Humic Acid ◽  
Natural Organic Matter ◽  
Extraction Methods ◽  
Soil Samples ◽  
Hot Water ◽  
Soil Extracts ◽  
Water Percolation ◽  
Soil Humic Acid

The Hot Water Percolation (HWP) technique for preparing soil extracts has several advantages: it is easily carried out, fast, and several parameters can be measured from the same solution. The object of this study was to examine the possible use of HWP extracts for the characterization of soil organic matter. The HPLC-SEC chromatograms, UV-VIS and fluorescence properties of the HWP extracts were studied and the results were compared with those of the International Humic Substances Society (IHSS) Soil Humic Acid (HA), IHSS Soil Fulvic Acid (FA) and IHSS Suwannee Natural Organic Matter (NOM) standards as well as their HA counterparts isolated by traditional extraction methods from the original soil samples. The DOM of the HWP solution is probably a mixture of organic materials, which have some characteristics similar to the Soil FA fractions and NOM. The HWP extracted organic material can be studied and characterized using simple techniques, like UV-VIS and fluorescence spectroscopy.

Solubility Enhancement of the Poorly Water-Soluble Antiulcer Drug Famotidine by Inclusion Complexation

2013 ◽  
Vol 6 (1) ◽  
pp. 1983-1989 ◽  
Author(s):  
Shabnam Ain ◽  
V Gupta ◽  
Babita K ◽  
Q Ain ◽  
J Dahiya
Keyword(s):  
Inclusion Complex ◽  
Dissolution Rate ◽  
Phosphate Buffer ◽  
Physical Mixture ◽  
Water Soluble ◽  
Molar Ratio ◽  
Phase Solubility ◽  
Distilled Water ◽  
Physicochemical Interaction ◽  
Mixture Phase

Aqueous solubility is a critical factor for optimum drug delivery. In the present study, we investigated the potential of drug-cyclodextrin complexation as an approach for improving the solubility and bioavailability of famotidine, an H2-receptor antagonist and acid reducing drug which has poor solubility and bioavailability. Solubility improvement of drug by β-cyclodextrin was done by simple complexation approach using physical, kneading and co-precipitation methods and compared with physical mixture. Phase solubility profile indicated that the solubility of famotidine was significantly increased in presence of β-cyclodextrin and shows a linear graph with β-cyclodextrin indicating formation of inclusion complexes in a 1:1 molar ratio. β-Cyclodextrin-famotidine mixture have maximum stability constant 1477.6 M-1. The inclusion complex ratio 1:1 of kneading mixture was selected based on drug release profile and compared with physical mixture. Further characterization was done by  using Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) to identify the physicochemical interaction between drug and carrier and its effect on dissolution. Dissolution rate studies for selected inclusion complex was performed in 0.1 N HCl (pH 1.2), phosphate buffer (pH 7.5) and distilled water (pH 6.8) and compared these to pure drug profile which was found to be 2.34 fold increase in distilled water, 1.83 fold in HCl and 2.01 fold in phosphate buffer (pH 7.5). These results suggest that the kneaded complex of famotidine with β-cyclodextrin as hydrophilic complexation agent can substantially enhance the solubility and dissolution rate. Such complex has promising potential to improve the bioavailability of famotidine.  

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