A novel technique is developed to simultaneously measure hot surface and gas temperatures based on passive absorption/emission spectroscopy (PAS). This non-intrusive, in situ technique is the extension of multi-wavelength pyrometry to also measure gas temperature. The PAS technique uses hot surface (e.g., turbine blade) as the radiation source, and measures radiation signals at multiple wavelengths. Radiation signals at wavelengths with minimum interference from gas (mostly from water vapor and CO2) can be used to determine the hot surface temperature, while signals at wavelengths with gas absorption/emission can be used to determine the gas temperature in the line-of-sight. The detection wavelengths are optimized for accuracy and sensitivity for gas temperature measurements. Simulation results also show the effect of non-uniform gas temperature profile on measurement results. High pressure/temperature tests are conducted in single nozzle combustor rig to demonstrate sensor proof-of-concept. Preliminary engine measurement results shows the potential of this measurement technique. The PAS technique only requires one optical port, e.g., existing pyrometer or borescope port, to collect the emission signal, and thus provide practical solution for gas temperature measurement in gas turbine engines.