Nonlinear Optical and Electro-Optic Properties of Organic Compounds

2020 ◽  
pp. 139-180
Author(s):  
Ch. Bosshard ◽  
K. Sutter ◽  
Ph. Prêtre ◽  
J. Hulliger ◽  
M. Flörsheimer ◽  
...  
2013 ◽  
Vol 4 (10) ◽  
pp. 1937 ◽  
Author(s):  
Keisuke Isobe ◽  
Hiroyuki Kawano ◽  
Akiko Kumagai ◽  
Atsushi Miyawaki ◽  
Katsumi Midorikawa

1989 ◽  
Vol 175 ◽  
Author(s):  
R. Lytel ◽  
G.F. Lipscomb

AbstractRecent developments in the application of electro-optic polymer materials to perform multi-functional roles in integrated optic device applications are summarized and future requirements for practical field operation are discussed.


Author(s):  
Xiaohui Li ◽  
Chenxi Zhang ◽  
yamin wang ◽  
Mingqi An ◽  
Zhipeng Sun

The hydrazone organic compounds with strong conjugation effect have superior characteristics such as high nonlinear optical sensitivity, short response time, unique electronic spectrum and photothermal stability. The conjugated structure of...


Author(s):  
M. Saravanan

The crystals N-(2-chlorophenyl)-(1-propanamide) (NCP) appropriate for nonlinear optical (NLO) and electro–optic appliances were grown full-fledged by the slow cooling method. The solubility and metastable zone width range of NCP specimen were studied. The specimen crystallizes in the monoclinic crystal system with noncentrosymmetric space group of P21. The crystal morphology study also elucidates supplementary excellence of the as-grown NCP crystal. The optical precision in the whole visible region was found to be superior for NLO claim. The crystallinity of the full-fledged crystal is determined by etching and HRXRD. Laser harm threshold and photoluminescence studies delegate the grown crystal comprises extremely less imperfections. The mechanical deeds of NCP sample at assorted temperatures were examined to decide the hardness solidity of the grown specimen. The piezoelectric behavior and the comparative second harmonic generation for assorted particle sizes of the material were also deliberate. The third-order nonlinear ocular possessions of NCP crystal specimen were determined by [Formula: see text]-scan method. The optical homogeneity of the solitary crystal was assessed using customized channel spectrum technique. The thermal structures of NCP solitary crystal have been studied using photopyroelectric method. The half-wave voltage of the full-fledged crystal was intended from the electro–optic experimentation. Photoconductivity nature of the grown crystal outlined consummate inducing dipoles due to strong incident radiation and further revealed the nonlinear deeds of the grown material.


2020 ◽  
pp. 89-104
Author(s):  
Ch. Bosshard ◽  
K. Sutter ◽  
Ph. Prêtre ◽  
J. Hulliger ◽  
M. Flörsheimer ◽  
...  

2020 ◽  
Vol 8 (27) ◽  
pp. 9226-9235 ◽  
Author(s):  
Fenggang Liu ◽  
Songmin Mo ◽  
Zhaofen Zhai ◽  
Meishan Peng ◽  
Shuangke Wu ◽  
...  

In this work, we developed a series of nonlinear optical chromophores J1–J4 with the same julolidinyl-based donor and tricyanovinyldihydrofuran acceptor with different modified isophorone-derived bridges.


1992 ◽  
Vol 247 ◽  
Author(s):  
J. W. Wu ◽  
J. F. Valley ◽  
M. Stiller ◽  
S. Ermer ◽  
E. S. Binkley ◽  
...  

ABSTRACTUsing polyimide as host in a guest-host electro-optic (EO) thin film a thermally stable poled electro-optic response is demonstrated at temperatures at 150 °C and 300 °C. Electric field poling during curing process including imidization (170 -230 °C) and densification (340 -380 °C) accounts for the highly thermally stable EO response. As a room temperature curing process, chemical imidization is employed as a novel curing process. Dehydration occurring through imidization of the polyamic acid is completed chemically after poling rather than thermally during poling. After thermal aging at 155 °C (above the poling temperature) chemically imidized samples retain over 30% of their original poling induced EO signal while similarly poled samples, which have not been chemically imidized, produce a null EO response. For a class of polyimides possessing aliphatic structure, the thermoplastic behavior of cured guest-host polyimide system allowed the electric field poling at temperatures above the glass transition temperature (Tg). One example of polyimide doped with 10% nonlinear optical molecules exhibits Tg near 200 °C, leading to an excellent thermal stability of the poled EO response with a depoling knee-temperature of 150°C.


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