Photocatalytic degradation of 1,2-dichloroethane using immobilized PAni-TiO2 nanocomposite in a pilot-scale packed bed reactor

2019 ◽  
Vol 155 ◽  
pp. 72-83 ◽  
Author(s):  
Mahdi Mohsenzadeh ◽  
Seyed Ahmad Mirbagheri ◽  
Samad Sabbaghi
2011 ◽  
Vol 109 (3) ◽  
pp. 637-646 ◽  
Author(s):  
Amber R. Boles ◽  
Teresa Conneely ◽  
Robert McKeever ◽  
Paul Nixon ◽  
Klaus R. Nüsslein ◽  
...  

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Colin Awungacha Lekelefac ◽  
Johannes Hild ◽  
Peter Czermak ◽  
Michael Herrenbauer

The synthesis of immobilized catalyst on porous glass support material via the sol-gel route is reported. TiO2-P25-SiO2+ Pt, TiO2-P25-SiO2, TiOSO4_30.6 wt%, and ZnO + TiO2-P25-SiO2catalysts were synthesized and a comparative study is done regarding morphology of coatings, degradation rates, reaction rates, dissolved carbon (DC), formation of peaks, and fluorescence of products formed from the photocatalytic degradation of lignin sulfonate obtained from a local paper plant. Through simultaneous reaction-extraction pathways applying dialysis filtration and highly porous polystyrene divinylbenzene adsorbent resin (HR-P) for solid phase extraction (SPE), an attempt has been made to isolate smaller molecules produced from photocatalytic degradation. Moreover relatively high lignin sulfonate (0.5 g/L) concentrations are used in the reactions. UV-Vis spectroscopy revealed a faster reduction in the concentration values for the aliphatic moiety compared to the aromatic moiety. Peaks were observed by both fluorescence spectroscopy and HPLC suggesting the production of new substances and fluorophores.


Author(s):  
Francesco Spennati ◽  
Salvatore La China ◽  
Giovanna Siracusa ◽  
Simona Di Gregorio ◽  
Alessandra Bardi ◽  
...  

This study demonstrated that a microbial community dominated by fungi can be selected and maintained in the long-term under non-sterile conditions, in a pilot-scale packed-bed reactor fed with tannery wastewater. During the start-up phase, the reactor, filled with 0.6 m3 of polyurethane foam cubes, was inoculated with a pure culture of Aspergillus tubingensis and Quebracho tannin, a recalcitrant compound widely used by tannery industry, was used as sole carbon source in the feeding. During the start-up, fungi grew attached as biofilm in carriers that filled the packed-bed reactor. Subsequently, the reactor was tested for the removal of chemical oxygen demand (COD) from an exhaust tanning bath collected from tanneries. The entire experiment lasted 121 days and average removals of 29% and 23% of COD and dissolved organic carbon (DOC) from the tannins bath were achieved, respectively. The evolution of the microbial consortium (bacteria and fungi) was described through biomolecular analyses along the experiment and also developed as a function of the size of the support media.


2000 ◽  
Vol 16 (4) ◽  
pp. 589-594 ◽  
Author(s):  
M.-P. Bousquet ◽  
R.-M. Willemot ◽  
P. Monsan ◽  
E. Boures

1990 ◽  
Vol 22 (9) ◽  
pp. 9-16 ◽  
Author(s):  
S. R. Harper ◽  
C. C. Ross ◽  
G. E. Valentine ◽  
F. G. Pohland

Wastewater from a typical poultry processing plant in the southeastern U.S.A. was treated on site with a pilot-scale anaerobic packed-bed reactor. The reactor had a working volume of 3.2 m3, was filled with 15-cm diameter polyethylene random-pack media, and was operated at 35°C with a retention time of 21 hours and at a loading rate of 2.8 kgCOD/m3d−1. Under these conditions, treatment efficiencies were sufficient to meet typical surcharge-free municipal discharge requirements, with effluent soluble COD of 440 mg/L, soluble BOD5 of 190 mg/L, fats, oil and grease (FOG) of 10 mg/L, and total suspended solids of 140 mg/L. Results from pilot operation are compared to those of previous laboratory-scale studies, where similar results were obtained with less than half of the hydraulic retention time. Differences in treatment on pilot vs. laboratory scale were largely due to differences in wastewater variability and reactor operation. Recommendations for future studies to reduce the costs of treatment, including emphasis on types of low-cost packing, amounts of packing media, and heating requirements are presented.


2004 ◽  
Vol 50 (6) ◽  
pp. 141-148
Author(s):  
J.-H. Bae ◽  
I.-S. Lee ◽  
M.-S. Jang ◽  
K.-H. Ahn ◽  
S.-H. Lee

Nitrogen removal efficiency of a pilot-scale system consisted of Modified Ludzack-Ettinger (MLE) followed by sulfur-utilizing denitrification (SUDNR) process was evaluated with a landfill leachate. For SUDNR, a down-flow mode sulfur packed bed reactor (SPBR) filled with sulfur and limestone particles was used. Although total nitrogen removal efficiency of the MLE process was about 80% at the recycle ratio of 4, effluent contained 350-450 mg/L NO3--N. Up to a loading rate of 1.2 kg NO3--N/m3-day, the SPBR could achieve complete removal of nitrate, and nitrate removal rate was kept to that level even at higher loading rate. When a COD/N ratio of MLE process was maintained at 2 instead of 4, more organics with molecular weight less than 500 were utilized for heterotrophic denitrification although denitrification was not complete with the lack of electron donors. Clogging in the SPBR, mainly by the accumulation of nitrogen gas in the pores, could easily be removed by introducing the effluent in an upward direction for 1 min at 1 hr intervals. The proposed treatment system could achieve nitrate free effluent with a slight increase in chemical cost. Furthermore, depending on further COD removal requirement after biological treatment, the proposed treatment system can be an economical solution.


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