Corrosion Inhibitors for Carbon Tetrachloride—Water Vapor Atmospheres

CORROSION ◽  
1959 ◽  
Vol 15 (9) ◽  
pp. 15-17 ◽  
Author(s):  
K. W. CALKINS ◽  
R. W. HAWLEY

Abstract The use of various inhibitors for the prevention of mild steel corrosion in a system of carbon tetrachloride and water vapor was investigated. An attempt also was made to establish a corrosion mechanism. Of the 48 inhibitors tested, 2-aminoethanol appeared to be the most effective. It was found that 0.4 percent by weight of 2-aminoethanol in carbon tetrachloride decreased the corrosion rate of mild steel in a carbon tetrachloride-water vapor atmosphere by 99 percent. The next most effective inhibitor decreased the rate by about 95 percent.

2012 ◽  
Vol 538-541 ◽  
pp. 2329-2333 ◽  
Author(s):  
Hui Xia Feng ◽  
Jian Li ◽  
Xiao Hong Gao

The corrosion inhibition behaviour of four selected Mannich bases compounds,namely 3-((N-methyl,N-phenyl)-methyl)2,4-Acetylacetone(MPMAA),3-((N-phenyl)-methyl) 2,4-Acetylacetone (PMAA),3-((N, N-diethyl)-methyl) 2, 4-Acetylacetone(DMAA) and 3-((N, N-methyl)-methyl) 2, 4-Acetylacetone (MMAA) as corrosion inhibitors for mild steel in 1M HCl solutions. Tafel polarization methods were performed to determine the corrosion parameters and inhibition efficiencies. Experimental results showed that PMAA is an excellent inhibitor for mild steel corrosion in 1M HCl solutions; showing a maximum efficiency 92.3% at concentration of 40mg/L. Polarization studies showed that the Mannich bases compounds can be regarded as mixed-type inhibitors and the inhibition efficiency of the four inhibitors followed the order PMAA > MPMAA > DMAA > MMAA. Then scanning electron microscope (SEM)techniques were also employed to examine the mechanism of corrosion inhibition property.


RSC Advances ◽  
2016 ◽  
Vol 6 (19) ◽  
pp. 15639-15654 ◽  
Author(s):  
Chandrabhan Verma ◽  
L. O. Olasunkanmi ◽  
I. B. Obot ◽  
Eno E. Ebenso ◽  
M. A. Quraishi

The inhibition of mild steel corrosion in 1 M HCl by four 5-arylpyrimido-[4,5-b]-quinoline-diones has been investigated using weight loss, electrochemical, surface, and quantum chemical calculations and molecular dynamics simulation methods.


2007 ◽  
Vol 49 (7) ◽  
pp. 2800-2814 ◽  
Author(s):  
Canan Küstü ◽  
Kaan C. Emregül ◽  
Orhan Atakol

CORROSION ◽  
1961 ◽  
Vol 17 (4) ◽  
pp. 188t-190t ◽  
Author(s):  
M. H. PETERSON ◽  
L J. WALDRON

Abstract The basic corrosion rate at San Diego has been determined by exposure of an extensive series of mild steel panels for 6, 12, and 18 months. The corrosion rate as determined by weight loss, and the degree of pitting determined by pit depth measurements was measured for unprotected panels, and for three different levels of cathodic protection. The basic corrosion rate for unprotected panels over the one-year exposure was 25.8 mdd and the greatest pit depth found exceeded 60 thousandths of an inch. The fully protected panels suffered virtually no corrosion while the partially protected panels had a corrosion rate of 8.3 mdd. However, the greatest pit depth found on the partially protected panels was only 9 mils. 6.2.3, 2.2.2, 3.2.2, 5.2.1


2014 ◽  
Vol 10 (3) ◽  
pp. 2388-2402 ◽  
Author(s):  
M.P. Chakravarthy ◽  
Dr. K. N. Mohana ◽  
C.B. Pradeep Kumar

Dapsone derivatives Viz., 4, 4’-sulfonylbis(N-((1H-pyrrol-2-yl)methylene)aniline) (SBPMA) and 2-dimethylamino-5-[(4-{4-[(4-dimethylamino-benzylidene)-amino]-benzenesulfonyl}-phenylimino)-methyl]-benzene (DBBPB), a new class of corrosion inhibitors have been synthesized and their corrosion inhibition efficiency on mild steel in 0.5 M H2SO4 was investigated by mass loss,  Tafel polarization and AC impedance measurements. Potentiodynamic polarization studies showed that, these compounds behave as mixed type of corrosion inhibitors. The adsorption process was found to obey Langmuir isotherm model. Electrochemical impedance spectroscopy (EIS) studies revealed that polarization resistance (RP) increases and double layer capacitance (Cdl) decreases as the concentration of the inhibitors increases. Various thermodynamic parameters for the adsorption of inhibitors on mild steel were computed and discussed. FTIR, EDX and SEM analyses were performed to study the film persistency of the inhibitors.


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