Corrosion Behavior of High-Purity Fe-Cr-Ni Alloys in the Transpassive Condition

CORROSION ◽  
2000 ◽  
Vol 56 (1) ◽  
pp. 70-79 ◽  
Author(s):  
M. Mayuzumi ◽  
J. Ohta ◽  
K. Kako
Author(s):  
Hayette Faid

AbstractIn this work, Zn-Ni alloys have been deposited on steel from sulfate bath, by electrodeposition method. The effect of Zn content on deposits properties was studied by cyclic voltammetry (CV), chronoaperometry (CA), linear stripping voltammetry (ALSV) and diffraction (XRD) and scanning electronic microscopy (SEM). The corrosion behavior in 3.5 wt. NaCl solution was examined using anodic polarization test and electrochemical impedance spectroscopy. X-ray diffraction of show that Zn-Ni alloys structure is composed of δ phase and γ phase, which increase with the decrease of Zn content in deposits. Results show that deposits obtained from bath less Zn2+ concentration exhibited better corrosion resistance.


CORROSION ◽  
1960 ◽  
Vol 16 (2) ◽  
pp. 70t-72t ◽  
Author(s):  
DAVID SCHLAIN ◽  
CHARLES B. KENAHAN ◽  
WALTER L. ACHERMAN

Abstract Chemical and galvanic corrosion experiments at 35 C show that ductile vanadium is resistant to corrosion in substitute ocean water. It is also resistant in 60 percent sulfuric and 20 percent hydrochloric acids but corrodes rapidly in nitric acid solutions. Vanadium is less noble than stainless steel and copper and more noble than aluminum, magnesium and steel (SAE 4130) in substitute ocean water. 6.3.18


Author(s):  
Sang Kyu Woo ◽  
Byeong-Chan Suh ◽  
Nam Ryong Kim ◽  
Ha Sik Kim ◽  
Chang Dong Yim

1989 ◽  
Vol 38 (426) ◽  
pp. 300-306 ◽  
Author(s):  
Takashi KAWAKUBO ◽  
Hideo HIRAYAMA ◽  
Akira GOTO ◽  
Tadashi KANEKO

CORROSION ◽  
2001 ◽  
Vol 57 (10) ◽  
pp. 889-897 ◽  
Author(s):  
M. Mayuzumi ◽  
J. Ohta ◽  
K. Kako ◽  
E. Kawakami
Keyword(s):  

2013 ◽  
Vol 23 (1) ◽  
pp. 302-307 ◽  
Author(s):  
Yuttanant Boonyongmaneerat ◽  
Kanokwan Saengkiettiyut ◽  
Sawalee Saenapitak ◽  
Supin Sangsuk

Author(s):  
Ikuo Ioka ◽  
Jun Suzuki ◽  
Takafumi Motoka ◽  
Kiyoshi Kiuchi ◽  
Junpei Nakayama

An intergranular corrosion is observed in austenitic stainless steels exposed to high temperature, concentrated nitric acid (HNO3) solution with highly oxidizing ions. It is an important degradation mechanism of austenitic stainless steels for use in a nuclear fuel reprocessing plant. The intergranular corrosion is caused by the segregation of impurities to grain boundaries and the resultant formation of active sites. Extra High Purity (EHP™) austenitic stainless steel was developed with conducting the new multiple refined melting in order to suppress the total harmful impurities less than 100ppm. The intergranular corrosion behavior of EHP alloys with various impurities was examined in boiling HNO3 solution with highly oxidizing ions to find a correlation between the intergranular corrosion and the impurities of EHP alloys. A good correlation was confirmed between the degree of intergranular corrosion and the corrosion rate. The relationships between the corrosion rate and the impurities content of EHP alloys was determined using a multiple regression analysis. The influence on corrosion rate became small in order of B, P, Si, C, S and Mn. It was important to control B in intergranular corrosion behavior of EHP alloys.


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