Analysis of Soft Coating Corrosion Performance on Carbon Steel Using Electrochemical Impedance Spectroscopy

CORROSION ◽  
10.5006/1092 ◽  
2014 ◽  
Vol 70 (6) ◽  
pp. 615-626 ◽  
Author(s):  
X.M. Li ◽  
B. Faber ◽  
B. Minch ◽  
H. Castaneda
2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
J. Porcayo-Calderon ◽  
M. Casales-Diaz ◽  
L. M. Rivera-Grau ◽  
D. M. Ortega-Toledo ◽  
J. A. Ascencio-Gutierrez ◽  
...  

In order to determine the diesel contribution in the coadsorption process of the oil-soluble inhibitors, electrochemical impedance spectroscopy measurements have been carried out to study the performance of oil-soluble inhibitors in both presence and absence of diesel and CO2. The results showed that the presence of the oil phase provides some protection to the steel because the water-soluble fractions are capable of being adsorbed on the steel surface thereby reducing the corrosion rate. The oily phase does not contribute to the adsorption process of the inhibitor because the inhibitor is absorbed into the water-soluble fractions. The oil-soluble inhibitors are effective only when the solution is saturated with CO2. CO2saturation causes a decrease in the pH of the solution causing both an increase of the inhibitor solubility and a better dispersion of the inhibitor into the electrolyte.


2013 ◽  
Vol 652-654 ◽  
pp. 1432-1435
Author(s):  
Qian Hu ◽  
Jing Liu ◽  
Jie Zhang ◽  
Feng Huang ◽  
Xing Peng Guo

The crevice corrosion behaviors of X52 carbon steel in two typical Cl--containing solutions were investigated by electrochemical noise and electrochemical impedance spectroscopy. Results show that oxygen concentration difference leads to the coupled current in NaCl + NaHCO3 solution while HAc concentration difference causes the coupled current in NaCl solution saturated with CO2 in the presence of HAc. There exists an apparent incubation stage during the crevice corrosion process of X52 carbon steel in the former. However, no obvious incubation period of crevice corrosion can be observed in the latter. Micrography shows that the crevice corrosion occurs indeed and the corrosion inside the crevice is not uniform.


2018 ◽  
Vol 4 (1) ◽  
pp. 47-54 ◽  
Author(s):  
Nilesh S. Bagal ◽  
Vaibhav S. Kathavate ◽  
Pravin P. Deshpande

AbstractThe present study aims at deposition of zinc phosphate coatings on low carbon steel with incorporated nano- TiO2 particles by chemical phosphating method. The coated low carbon steel samples were assessed in corrosion studies using electrochemical impedance spectroscopy and potentiodynamic polarization techniques (Tafel) in 3.5% NaCl solution. Morphology and chemical composition of the coatings were analyzed by scanning electron microscopy and energy dispersive X-ray spectroscopy in order to observe growth of coating. Significant variations in the coating weight, porosity and corrosion resistance were observed with the addition of nano- TiO2 in the phosphating bath. Corrosion rate of nano-TiO2 chemical phosphate coated samples was found to be 3.5 milli inches per year which was 3 times less than the normal phosphate-coated sample (8 mpy). Electrochemical impedance spectroscopy studies reveal reduction of porosity of nano-TiO2 phosphate coated samples. It was found that nano-TiO2 particles in the phosphating solution yielded uniform phosphate coatings of higher coating weight, fewer defects and enhanced corrosion resistance than the normal zinc phosphate coatings (developed using normal phosphating bath).


2019 ◽  
Vol 43 (1) ◽  
pp. 71-77 ◽  
Author(s):  
Adriano H. Akita ◽  
Cecílio S. Fugivara ◽  
Idalina V. Aoki ◽  
Assis V. Benedetti

RSC Advances ◽  
2017 ◽  
Vol 7 (72) ◽  
pp. 45241-45251 ◽  
Author(s):  
M. A. Deyab ◽  
M. M. Osman ◽  
A. E. Elkholy ◽  
F. El-Taib Heakal

The anti-corrosion action of lemongrass (cymbopogon citratus) extract (LGE) was evaluated for carbon steel in produced oilfield water using weight loss method and electrochemical impedance spectroscopy (EIS).


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