Preparation of Ionic Conductivity Polymer Electrolyte Film Based on Epoxidized Deproteinized Natural Rubber

Ionic conductivity polymer electrolyte film based on epoxidized deproteinized natural rubber (EDPNR) and lithium salt lithium triflate (LiCF3SO3) were prepared by solution casting technique. The EDPNR was prepared from deproteinized natural rubber latex (DNR) epoxidized in the latex stage with fresh peracetic acid 33%, which was deproteinized by incubation of the latex with 0,1 wt% urea and 1 wt% surfactant. The ionic conductivity of EDPNR mixed with lithium salt was investigated through impedance analysis. The results show that the conductivity of EDPNR/ LiCF3SO3 mixture was dependent on LiCF3SO3 salt concentration and amount of epoxy group. The highest ionic conductivity at room temperature obtained is 1,71 x 10-5 S.cm-1 at 35 wt% LiCF3SO3 and 45 mol% epoxy groups. Fourier transform infrared spectroscopy (FTIR) spectra showed evidence of complexation between EDPNR and LiCF3SO3. Glass transition temperature, Tg displayed an increasing trend in which are the increase in salt concentration and the increase in epoxy group concentration.

Download Full-text

Ionic conductivity of highly deproteinized natural rubber having various amount of epoxy group mixed with lithium salt

Solid State Ionics ◽

10.1016/j.ssi.2006.08.006 ◽

2006 ◽

Vol 177 (37-38) ◽

pp. 3251-3257 ◽

Cited By ~ 19

Author(s):

W KLINKLAI ◽

S KAWAHARA ◽

E MARWANTA ◽

T MIZUMO ◽

Y ISONO ◽

...

Keyword(s):

Ionic Conductivity ◽

Natural Rubber ◽

Lithium Salt ◽

Epoxy Group ◽

Deproteinized Natural Rubber

Download Full-text

Temperature glass and conductivity behavior of epoxy deproteinized natural rubber in ternary blend of EDPNR/PMMA/LiCF3SO3

Progress in Rubber Plastics and Recycling Technology ◽

10.1177/14777606211042030 ◽

2021 ◽

pp. 147776062110420

Author(s):

Trịnh Thị Hang ◽

I Putu Mahendra ◽

Tran Manh Thang ◽

Seiichi Kawahara ◽

Phan Trung Nghia

Keyword(s):

Ionic Conductivity ◽

Natural Rubber ◽

Lithium Salt ◽

Ternary Blend ◽

Ternary Blends ◽

Binary Blends ◽

Lithium Trifluoromethanesulfonate ◽

The Right ◽

Deproteinized Natural Rubber ◽

Conductivity Behavior

The temperature glass behavior of epoxy deproteinized natural rubber/polymethylmethacrylate/lithium trifluoromethanesulfonate (EDPNR/PMMA/LiCF3SO3) and the conductivity behavior of EDPNR in the ternary blends were studied by DSC and multichannel potentiostat. The DSC result revealed the temperature glass of the EDPNR was shifted to the right with the increase of lithium salt amount in these binary blends composition. However, in the ternary blends of EDPNR/PMMA/LiCF3SO3 the temperature glass revealed the miscibility of these ternary blends. Two different temperature glass values were obtained when the ratio of EDPNR in EDPNR/PMMA was less than 80 wt.%. The ionic conductivity of EDPNR could be improved by increasing the amount of lithium salt up to 35 wt.%, after this amount the ionic conductivity of EDPNR was significantly decreased. While in the ternary blends, the highest ionic conductivity value was found at the ratio 80/20 of EDPNR/PMMA. Furthermore, the factors influencing the temperature glass and conductivity behavior of EDPNR were systematically studied in this work. The results demonstrated an intimate correlation between temperature glass and conductivity behavior of EDPNR.

Download Full-text

Ionic conductivity of highly deproteinized natural rubber having epoxy group mixed with alkali metal salts

Solid State Ionics ◽

10.1016/j.ssi.2003.12.024 ◽

2004 ◽

Vol 168 (1-2) ◽

pp. 131-136 ◽

Cited By ~ 13

Author(s):

W Klinklai

Keyword(s):

Ionic Conductivity ◽

Alkali Metal ◽

Natural Rubber ◽

Epoxy Group ◽

Metal Salts ◽

Alkali Metal Salts ◽

Deproteinized Natural Rubber

Download Full-text

Ionic conductivity of polymer electrolyte film deposited by vacuum evaporation of poly(ethylene oxide) and LiI

Solid State Ionics ◽

10.1016/0167-2738(87)90083-x ◽

1987 ◽

Vol 23 (1-2) ◽

pp. 69-75 ◽

Cited By ~ 4

Author(s):

Y ITO ◽

K KANEHORI ◽

K MIYAUCHI ◽

T KUDO

Keyword(s):

Ionic Conductivity ◽

Ethylene Oxide ◽

Polymer Electrolyte ◽

Vacuum Evaporation ◽

Electrolyte Film ◽

Poly Ethylene Oxide ◽

Polymer Electrolyte Film ◽

Poly Ethylene

Download Full-text

POLYMER ELECTROLYTE PREPARED FROM HIGHLY DEPROTEINIZED NATURAL RUBBER HAVING EPOXY GROUP

Solid State Ionics ◽

10.1142/9789812702586_0123 ◽

2004 ◽

pp. 1081-1088

Author(s):

W. KLINKLAI ◽

S. KAWAHARA ◽

Y. ISONO ◽

T. MIZUMO ◽

M. YOSHIZAWA ◽

...

Keyword(s):

Natural Rubber ◽

Polymer Electrolyte ◽

Epoxy Group ◽

Deproteinized Natural Rubber

Download Full-text

Morphology, optical and ionic conductivity studies of electron beam irradiated polymer electrolyte film

10.1063/1.5028986 ◽

2018 ◽

Author(s):

H. Devendrappa ◽

L. Yesappa ◽

M. Niranjana ◽

S. P. Ashokkumar ◽

H. Vijeth ◽

...

Keyword(s):

Electron Beam ◽

Ionic Conductivity ◽

Polymer Electrolyte ◽

Electrolyte Film ◽

Polymer Electrolyte Film

Download Full-text

Ionic Conductivity of Chitosan-based Polymer Electrolyte with Polyethylene Glycol (PEG) as Plasticizer and KCl as Alkaline Ion Transport Source

Omega Jurnal Fisika dan Pendidikan Fisika ◽

10.31758/omegajphysphyseduc.v4i1.13 ◽

2018 ◽

Vol 4 (1) ◽

pp. 13

Author(s):

Akhiruddin Maddu ◽

Muhamar Kadapi ◽

Irmansyah Sofian

Keyword(s):

Activation Energy ◽

Polyethylene Glycol ◽

Ionic Conductivity ◽

Ion Transport ◽

Polymer Electrolyte ◽

Composite Polymer Electrolyte ◽

Mixed Solution ◽

Composite Polymer ◽

Electrolyte Film ◽

Polymer Electrolyte Film

Polymer electrolyte films were fabricated utilizing chitosan biopolymer plasticized with polyethylene glycol (PEG) and KCl addition as ionic transport source. The precursor solution was prepared by mixing the chitosan in acetic acid solution and PEG that act as a plasticizer. Into the mixed solution was added KCl salt for as alkalin ion transport source in the polymer electrolyte. The polymer electrolyte films were fabricated by the casting method onto the petri glass. The influence of KCl content on ionic conductivity of the composite polymer electrolyte film was studied. The ionic conductivity of the composite polymer electrolyte film was characterized using LCR meter at a frequency of 1 kHz. The best ionic conductivity was found for the film containing 45 wt% of KCl salt. The activation energy was determined by using Arrhenius plot based on conductivity data at varied temperature. It has been found that the activation energy of the composite polymer electrolyte films varied to the KCL content in the composite polymer electrolyte films. The highest activation energy was found for the polymer electrolyte film with 45 wt% of KCl content.

Download Full-text