Photoneutron activation analysis and multivariate geostatistical approach to assess the spatial occurrence of trace heavy metals in Crisuri Basin

DIALOGO ◽  
2021 ◽  
Vol 8 (1) ◽  
pp. 77-82
Author(s):  
Cristiana Oprea ◽  
Diana Cupsa ◽  
Alexandru Ioan Oprea ◽  
Cosmin Tudor Ciocan ◽  
Marina V. Gustova ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Activation Analysis ◽  
Geochemical Data ◽  
Gamma Ray Spectrometry ◽  
Multivariate Statistical ◽  
Running Water ◽  
Trace Heavy Metals ◽  
Geostatistical Approach ◽  
Environmental Monitoring System ◽  
Spatially Distributed

The Crisuri Basin, with its total length of 1093 km (among which 670 km in Romania), is subjected to an effective environmental monitoring system consisting of 18 water stations network. Their integrated information is used for the water assessment problem to understand the biogeochemical processes leading to significant pollution levels in some running water sectors. The goal of this research is to predict the most important factors causing the change of the geochemical measured parameters of some components of the Crisuri water resources. In the present paper, we developed a multivariate statistical model to estimate the spatiotemporal distribution of heavy metals in the field and to identify the contamination sources of Basin River waters. Two methods were deployed as an overall approach to fulfill the proposed objectives, namely the photoneutron activation analysis followed by high-resolution gamma-ray spectrometry and the multivariate statistical analysis. The elements analyzed by different analytical techniques and introduced in databases were As, Cd, Ca, Cu, Fe, Mg, Hg, Na, Ni, Pb, Zn, N-NH4, N-NO2, N-NO3, P-PO4, fixed residues, S-SO4, Cl, phenols and, additional oil compounds. By combining the spatially distributed geochemical data on trace heavy metals with the spatially distributed geophysical data, we obtained the most significant fingerprint factors and their associated uncertainty information concerning the water quality.

scholarly journals Geochemical assessment of heavy metal impact on soil around Ewu-Elepe Dumpsite, Lagos State, Nigeria

2021 ◽  
Vol 22 (3) ◽  
pp. 119-138
Author(s):  
A.O. Olorunfemi ◽  
A.B. Alao-Daniel ◽  
T.A. Adesiyan ◽  
C.E. Onah
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Agricultural Soils ◽  
Control Sample ◽  
Shallow Groundwater ◽  
Contamination Factor ◽  
Heavy Metal Concentration ◽  
Geochemical Data ◽  
Multivariate Statistical ◽  
Accumulation Index

The concentrations of certain heavy metals in the top soils around the Ewu-Elepe dumpsite and its environs were determined with a view to  ascertaining the level of metal pollution in the soils of the dumpsite vicinity. Thirty-two (32) soil samples were randomly collected within the dumpsite vicinity and one control sample was collected from a distance of about 9.0 km from the dumpsite. The samples were prepared according  to standard procedures and analyzed for some heavy metals (Ni, Mn, Co, Cd, Cu, Pb, and Zn) using the Atomic Absorption Spectrophotometer at the Geochemistry Laboratory of the Department of Geology, Obafemi Awolowo University, Ile-Ife. The geochemical data was subjected to both  univariate and multivariate statistical treatments and comparisons were made with various world standards. The results obtained showed that the mean concentrations of Ni (12.00 ppm), Mn (525.60 ppm), Co (5.64 ppm), Cu (44.59 ppm), and Zn (105.28 ppm) were within the acceptable limits for agricultural soils while those of Cd (1.40 ppm) and Pb (33.74 ppm) exceeded the limits. Geo-accumulation index and contamination factor revealed that the soils around the dumpsite were moderately contaminated with Cd and slightly contaminated with Pb. The overall decreasing order of heavy metal concentration in the dumpsite soil is: Cd > Pb > Zn > Cu > Mn > Co > Ni. The study concluded that the soils around the Ewu-Elepe dumpsite was contaminated with Cd and Pb and as such should be discouraged in its usage for agricultural related purposes as these highly toxic trace elements can be absorbed by plants. A well-engineered landfill that takes into consideration the local geology and the topography of the area should be designed so as to prevent infiltration of leachates into the soil and shallow groundwater systems. Keywords - Heavy metals, Soil,Ewu-Elepe,Nigeria,Dumpsite,Contamination.

scholarly journals Source and Health Risk Assessment of Heavy Metals in Soil–Ginger System in the Jing River Basin of Shandong Province, North China

2021 ◽  
Vol 18 (13) ◽  
pp. 6749
Author(s):  
Songtao Wang ◽  
Zongjun Gao ◽  
Yuqi Zhang ◽  
Hairui Zhang ◽  
Zhen Wu ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
River Basin ◽  
Soil Profile ◽  
Pollution Index ◽  
Potential Ecological Risk ◽  
Average Concentration ◽  
Anthropogenic Factors ◽  
Multivariate Statistical ◽  
Cr Content

This study investigated the characteristics and sources of heavy metals in a soil–ginger system and assessed their health risks. To this end, 321 topsoil samples and eight soil samples from a soil profile, and 18 ginger samples with root–soil were collected from a ginger-planting area in the Jing River Basin. The average concentration of heavy metals in the topsoil followed the order: Cr > Zn > Pb > Ni > Cu > As > Cd > Hg. In the soil profile, at depths greater than 80 cm, the contents of Cr, Ni, and Zn tended to increase with depth, which may be related to the parent materials, whereas As and Cu contents showed little change. In contrast, Pb content decreased sharply from top to bottom, which may be attributable to external environmental and anthropogenic factors. Multivariate statistical analysis showed that Cr, Ni, Cu, Zn, and Cd contents in soil are affected by natural sources, Pb and As contents are significantly affected by human activities, and Hg content is affected by farmland irrigation. Combined results of the single pollution index (Pi), geo-accumulation index (Igeo), and potential ecological risk assessment (Ei and RI) suggest that soil in the study area is generally not polluted by heavy metals. In ginger, Zn content was the highest (2.36 mg/kg) and Hg content was the lowest (0.0015 mg/kg). Based on the bioconcentration factor, Cd and Zn have high potential for enrichment in ginger. With reference to the limit of heavy metals in tubers, Cr content in ginger exceeds the standard in the study area. Although Cr does not accumulate in ginger, Cr enrichment in soil significantly increases the risk of excessive Cr content in ginger.

Trace heavy metals in various Yugoslav tobaccos

1978 ◽  
Vol 69 (3-4) ◽  
pp. 261-270 ◽  
Author(s):  
M. Dermelj ◽  
V. Ravnik ◽  
A. R. Byrne ◽  
A. Vakselj
Keyword(s):  
Heavy Metals ◽  
Trace Heavy Metals

Assessment of Heavy Metals Content in the Proximity of a Contaminated Site From Cluj-Napoca (Romania)

2020 ◽  
Vol 65 (2) ◽  
pp. 17-37
Author(s):  
Georgiana Grosu ◽  
◽  
Carmen Andreea Roba ◽  
Ramona Bălc ◽  
Maria Lucia Bizău-Cârstea ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Statistical Analysis ◽  
Multivariate Statistical Analysis ◽  
Sediment Contamination ◽  
Contaminated Site ◽  
Pollution Indices ◽  
Chemical Parameters ◽  
Multivariate Statistical ◽  
Water And Sediment ◽  
Physico Chemical

The present study was conducted in the proximity of a contaminated site from Cluj-Napoca city (Cluj County, Romania), where metal processing activities have been carried out for decades. Metal content and physico-chemical parameters were analyzed in soil, water and sediment samples, while organic matter (OM) and total organic carbon (TOC) was additionally analyzed for the soil samples. The sources of heavy metals were evaluated based on multivariate statistical analysis, while the soil and sediment contamination degree was assessed based on specific pollution indices. The calculated indices indicated a significant pollution with Cd and Pb, which may represent a risk if the area would become a residential area. Keywords: heavy metals, contaminated site, soil pollution indices, multivariate statistical analysis, Cluj-Napoca

scholarly journals Migration of heavy metals in system of coastal soil – bottom sediments – plants of the Khodtsa river during summer mean water in 2019

2020 ◽  
Vol 2020 (2) ◽  
pp. 67-74
Author(s):  
Zhanna Sergeevna Makakhaniuk ◽  
Valentina Mikhailovna Zubkova ◽  
Lyubov Anatolievna Rozumnaya
Keyword(s):  
Heavy Metals ◽  
Bottom Sediments ◽  
Aquatic Vegetation ◽  
River Mouth ◽  
Petroleum Products ◽  
Small River ◽  
Laboratory Research ◽  
Intermediate Point ◽  
Higher Aquatic Vegetation ◽  
Environmental Monitoring System

The article describes the purpose of the work, which is determining the distribution and relationships between the composition of pollutants in coastal soil, bottom sediments and higher aquatic vegetation in the small river Khodtsa. There have been presented the data of the laboratory research based on the results of the field work onselecting samples, on concentration of toxicants (cadmium, lead, iron, nitrogen, ammonium and petroleum products) in deposit media, as well as in Carex aquatilis plants of the small river Hodza. This plant species is limiting throughout the river due to the low intensity of biological absorption. The studies were carried out during the summer low water season in 2019 on the river section from the source (Elektrostal city) to the river mouth in the area of Pavlovsky Posad. In all the studied objects there have been found increased concentrations of iron. In the coastal ground and bottom sediments the pollution with heavy metals is manifested to a much greater extent: at the source and intermediate point. Petroleum products and ammonia nitrogen are distributed unevenly in space. A correlation analysis of the experimental data obtained in the components of the environment of the studied territory (the Khodtsa river) was performed. In general, the highest measurement results are observed in the upper reaches of the small river Khodtsa in the industrial city of Elektrostal. The obtained data on the heavy metals migration in the system “сoastal ground – bottom sediments – higher aquatic vegetation” of the small river Khodtsa can be successfully used as indicators an environmental monitoring system and serve as the basis for organizing further research, as well as for developing a strategy for environmental management and environmental protection in the Moscow Region.

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