scholarly journals Comparison of three vertically resolved ozone data sets: climatology, trends and radiative forcings

2013 ◽  
Vol 13 (11) ◽  
pp. 5533-5550 ◽  
Author(s):  
B. Hassler ◽  
P. J. Young ◽  
R. W. Portmann ◽  
G. E. Bodeker ◽  
J. S. Daniel ◽  
...  

Abstract. Climate models that do not simulate changes in stratospheric ozone concentrations require the prescription of ozone fields to accurately calculate UV fluxes and stratospheric heating rates. In this study, three different global ozone time series that are available for this purpose are compared: the data set of Randel and Wu (2007) (RW07), Cionni et al. (2011) (SPARC), and Bodeker et al. (2013) (BDBP). All three data sets represent multiple-linear regression fits to vertically resolved ozone observations, resulting in a spatially and temporally continuous stratospheric ozone field covering at least the period from 1979 to 2005. The main differences among the data sets result from regression models, which use different observations and include different basis functions. The data sets are compared against ozonesonde and satellite observations to assess how the data sets represent concentrations, trends and interannual variability. In the Southern Hemisphere polar region, RW07 and SPARC underestimate the ozone depletion in spring ozonesonde measurements. A piecewise linear trend regression is performed to estimate the 1979–1996 ozone decrease globally, covering a period of extreme depletion in most regions. BDBP overestimates Arctic and tropical ozone depletion over this period relative to the available measurements, whereas the depletion is underestimated in RW07 and SPARC. While the three data sets yield ozone concentrations that are within a range of different observations, there is a large spread in their respective ozone trends. One consequence of this is differences of almost a factor of four in the calculated stratospheric ozone radiative forcing between the data sets (RW07: −0.038 Wm−2, SPARC: −0.033 Wm−2, BDBP: −0.119 Wm−2), important in assessing the contribution of stratospheric ozone depletion to the total anthropogenic radiative forcing.

2012 ◽  
Vol 12 (10) ◽  
pp. 26561-26605 ◽  
Author(s):  
B. Hassler ◽  
P. J. Young ◽  
R. W. Portmann ◽  
G. E. Bodeker ◽  
J. S. Daniel ◽  
...  

Abstract. Climate models that do not simulate changes in stratospheric ozone concentrations require ozone input fields to accurately calculate UV fluxes and stratospheric heating rates. In this study, three different global ozone time series that are available for this purpose are compared: the data set of Randel and Wu (2007) (RW07), Cionni et al. (2011) (SPARC), and Bodeker et al. (2012) (BDBP). The latter is a very recent data set, based on the comprehensive ozone measurement database described by Hassler et al. (2008). All three data sets represent multiple-linear regression fits to vertically resolved ozone observations, resulting in a patially and temporally continuous stratospheric ozone field covering at least the period from 1979 to 2005. The main difference between the data sets result from using different observations and including different basis functions for the regression model fits. These three regression-based data sets are compared against observations from ozonesondes and satellites to compare how the data sets represent concentrations, trends, and interannual variability. In the Southern Hemisphere polar region, RW07 and SPARC underestimate the ozone depletion in spring as seen in ozonesonde measurements. A piecewise linear trend regression is performed to estimate the 1979–1996 ozone decrease globally, covering a period of extreme depletion in most regions. BDBP seems to overestimate Arctic and tropical ozone loss over this period somewhat relative to the available measurements, whereas these appear to be underestimated in RW07 and SPARC. In most regions, the three data sets yield ozone values that are within the range of the different observations that serve as input to the regressions. However, the differences among the three suggest that there are large uncertainties in ozone trends. These result in differences of almost a factor of four in radiative forcing, which is important for the resulting climate changes.


2002 ◽  
Vol 2 (5) ◽  
pp. 363-374 ◽  
Author(s):  
D. T. Shindell ◽  
G. Faluvegi

Abstract. Using historical observations and model simulations, we investigate ozone trends prior to the mid-1970s onset of halogen-induced ozone depletion. Though measurements are quite limited, an analysis based on multiple, independent data sets (direct and indirect) provides better constraints than any individual set of observations. We find that three data sets support an apparent long-term stratospheric ozone trend of -7.2 ± 2.3 DU during 1957-1975, which modeling attributes primarily to water vapor increases. The results suggest that 20th century stratospheric ozone depletion may have been roughly 50% more than is generally supposed. Similarly, three data sets support tropospheric ozone increases over polluted Northern Hemisphere continental regions of 8.2 ± 2.1 DU during this period, which are mutually consistent with the stratospheric trends. As with paleoclimate data, which is also based on indirect proxies and/or limited spatial coverage, these results must be interpreted with caution. However, they provide the most thorough estimates presently available of ozone changes prior to the coincident onset of satellite data and halogen dominated ozone changes. If these apparent trends were real, the radiative forcing by stratospheric ozone since the 1950s would then have been -0.15 ± 0.05 W/m2, and -0.2 W/m2 since the preindustrial. For tropospheric ozone, it would have been 0.38 ± 0.10 W/m2 since the late 1950s. Combined with even a very conservative estimate of tropospheric ozone forcing prior to that time, this would be larger than current estimates since 1850 which are derived from models that are even less well constrained. These calculations demonstrate the importance of gaining a better understanding of historical ozone changes.


2020 ◽  
Author(s):  
Sabine Haase ◽  
Jaika Fricke ◽  
Tim Kruschke ◽  
Sebastian Wahl ◽  
Katja Matthes

Abstract. Southern hemisphere lower stratospheric ozone depletion has been shown to lead to a poleward shift of the tropospheric jet stream during austral summer, influencing surface atmosphere and ocean conditions, such as surface temperatures and sea ice extent. The characteristics of stratospheric and tropospheric responses to ozone depletion, however, differ largely among climate models depending on the representation of ozone in the models. The most accurate way to represent ozone in a model is to calculate it interactively. However, due to computational costs, in particular for long-term coupled ocean-atmosphere model integrations, the more common way is to prescribe ozone from observations or calculated model fields. Here, we investigate the difference between an interactive and a specified chemistry version of the same atmospheric model in a fully-coupled setup using a 9-member chemistry-climate model ensemble. In the specified chemistry version of the model the ozone fields are prescribed using the output from the interactive chemistry model version. In contrast to earlier studies, we use daily-resolved ozone fields in the specified chemistry simulations to achieve a better comparability between the ozone forcing with and without interactive chemistry. We find that although the short-wave heating rate trend in response to ozone depletion is the same in the different chemistry settings, the interactive chemistry ensemble shows a stronger trend in polar cap stratospheric temperatures (by about 0.7 K per decade) and circumpolar stratospheric zonal mean zonal winds (by about 1.6 m/s per decade) as compared to the specified chemistry ensemble. This difference between interactive and specified chemistry in the stratospheric response to ozone depletion also affects the tropospheric response, namely the poleward shift of the tropospheric jet stream. We attribute part of these differences to the missing representation of feedbacks between chemistry and dynamics in the specified chemistry ensemble, which affect the dynamical heating rates, and part of it to the lack of spatial asymmetries in the prescribed ozone fields. This effect is investigated using a sensitivity ensemble that was forced by a three-dimensional instead of a two–dimensional ozone field. This study emphasizes the value of interactive chemistry for the representation of the southern hemisphere tropospheric jet response to ozone depletion and infers that for periods with strong ozone variability (trends) the details of the ozone forcing can be crucial for representing southern hemispheric climate variability.


2020 ◽  
Vol 20 (22) ◽  
pp. 14043-14061
Author(s):  
Sabine Haase ◽  
Jaika Fricke ◽  
Tim Kruschke ◽  
Sebastian Wahl ◽  
Katja Matthes

Abstract. Southern Hemisphere lower-stratospheric ozone depletion has been shown to lead to a poleward shift of the tropospheric jet stream during austral summer, influencing surface atmosphere and ocean conditions, such as surface temperatures and sea ice extent. The characteristics of stratospheric and tropospheric responses to ozone depletion, however, differ among climate models depending on the representation of ozone in the models. The most appropriate way to represent ozone in a model is to calculate it interactively. However, due to computational costs, in particular for long-term coupled ocean–atmosphere model integrations, the more common way is to prescribe ozone from observations or calculated model fields. Here, we investigate the difference between an interactive and a specified chemistry version of the same atmospheric model in a fully coupled setup using a nine-member chemistry–climate model ensemble. In the specified chemistry version of the model the ozone fields are prescribed using the output from the interactive chemistry model version. We use daily resolved ozone fields in the specified chemistry simulations to achieve a very good comparability between the ozone forcing with and without interactive chemistry. We find that although the shortwave heating rate trend in response to ozone depletion is the same in the different chemistry settings, the interactive chemistry ensemble shows a stronger trend in polar cap stratospheric temperatures (by about 0.7 K decade−1) and circumpolar stratospheric zonal mean zonal winds (by about 1.6 m s−1 decade−1 as compared to the specified chemistry ensemble. This difference between interactive and specified chemistry in the stratospheric response to ozone depletion also affects the tropospheric response. However, an impact on the poleward shift of the tropospheric jet stream is not detected. We attribute part of the differences found in the experiments to the missing representation of feedbacks between chemistry and dynamics in the specified chemistry ensemble, which affect the dynamical heating rates, and part of it to the lack of spatial asymmetries in the prescribed ozone fields. This effect is investigated using a sensitivity ensemble that was forced by a three-dimensional instead of a two-dimensional ozone field. This study emphasizes the value of interactive chemistry for the representation of the Southern Hemisphere stratospheric-jet response to ozone depletion and infers that for periods with strong ozone variability (trends) the details of the ozone forcing could also have an influence on the representation of southern-hemispheric climate variability.


2002 ◽  
Vol 2 (5) ◽  
pp. 1371-1401
Author(s):  
D. T. Shindell ◽  
G. Faluvegi

Abstract. Using historical observations and model simulations, we investigate ozone trends prior to the mid-1970s onset of halogen-induced ozone depletion. Though measurements are quite limited, an analysis based on multiple, independent data sets (direct and indirect) provides better constraints than any individual set of observations. We find that three data sets support an apparent long-term stratospheric ozone trend of -7.2 ± 2.3 DU during 1957-1975, which modeling attributes primarily to water vapor increases. The results suggest that stratospheric ozone depletion may have been roughly 50% more than is generally supposed. Similarly, three data sets support tropospheric ozone increases over polluted Northern Hemisphere continental regions of 8.2 ± 2.1 DU during this period, which are mutually consistent with the stratospheric trends. As with paleoclimate data, which is also based on indirect proxies and/or limited spatial coverage, these results must be interpreted with caution. However, they provide the most thorough estimates presently available of ozone changes prior to the coincident onset of satellite data and halogen dominated ozone changes. If these apparent trends were real, the radiative forcing by stratospheric ozone since the 1950s would then have been -0.15 ± 0.05 W/m2, and -0.2 W/m2 since the preindustrial. For tropospheric ozone, it would have been 0.38 ±  0.10 W/m2 since the 1950s, larger than current estimates since 1850 which are derived from models that are even less well constrained. Going back to the preindustrial, the radiative forcing would have been +0.7 W/m2, roughly double what is generally assumed, although even more uncertain than the late twentieth century trends. These calculations demonstrate the importance of gaining a better understanding of historical ozone changes.


2011 ◽  
Vol 11 (4) ◽  
pp. 10875-10933 ◽  
Author(s):  
I. Cionni ◽  
V. Eyring ◽  
J. F. Lamarque ◽  
W. J. Randel ◽  
D. S. Stevenson ◽  
...  

Abstract. A continuous tropospheric and stratospheric vertically resolved ozone time series, from 1850 to 2099, has been generated to be used as forcing in global climate models that do not include interactive chemistry. A multiple linear regression analysis of SAGE I+II satellite observations and polar ozonesonde measurements is used for the stratospheric zonal mean dataset during the well-observed period from 1979 to 2009. In addition to terms describing the mean annual cycle, the regression includes terms representing equivalent effective stratospheric chlorine (EESC) and the 11-yr solar cycle variability. The EESC regression fit coefficients, together with pre-1979 EESC values, are used to extrapolate the stratospheric ozone time series backward to 1850. While a similar procedure could be used to extrapolate into the future, coupled chemistry climate model (CCM) simulations indicate that future stratospheric ozone abundances are likely to be significantly affected by climate change, and capturing such effects through a regression model approach is not feasible. Therefore, the stratospheric ozone dataset is extended into the future (merged in 2009) with multi-model mean projections from 13 CCMs that performed a simulation until 2099 under the SRES (Special Report on Emission Scenarios) A1B greenhouse gas scenario and the A1 adjusted halogen scenario in the second round of the Chemistry-Climate Model Validation (CCMVal-2) Activity. The stratospheric zonal mean ozone time series is merged with a three-dimensional tropospheric data set extracted from simulations of the past by two CCMs (CAM3.5 and PUCCINI) and of the future by one CCM (CAM3.5). The future tropospheric ozone time series continues the historical CAM3.5 simulation until 2099 following the four different Representative Concentration Pathways (RCPs). Generally good agreement is found between the historical segment of the ozone database and satellite observations, although it should be noted that total column ozone is overestimated in the southern polar latitudes during spring and tropospheric column ozone is slightly underestimated. Vertical profiles of tropospheric ozone are broadly consistent with ozonesondes and in-situ measurements, with some deviations in regions of biomass burning. The tropospheric ozone radiative forcing (RF) from the 1850s to the 2000s is 0.23 W m−2, lower than previous results. The lower value is mainly due to (i) a smaller increase in biomass burning emissions; (ii) a larger influence of stratospheric ozone depletion on upper tropospheric ozone at high southern latitudes; and possibly (iii) a larger influence of clouds (which act to reduce the net forcing) compared to previous radiative forcing calculations. Over the same period, decreases in stratospheric ozone, mainly at high latitudes, produce a RF of −0.08 W m−2, which is more negative than the central Intergovernmental Panel on Climate Change (IPCC) Fourth Assessment Report (AR4) value of −0.05 W m−2, but which is within the stated range of −0.15 to +0.05 W m−2. The more negative value is explained by the fact that the regression model simulates significant ozone depletion prior to 1979, in line with the increase in EESC and as confirmed by CCMs, while the AR4 assumed no change in stratospheric RF prior to 1979. A negative RF of similar magnitude persists into the future, although its location shifts from high latitudes to the tropics. This shift is due to increases in polar stratospheric ozone, but decreases in tropical lower stratospheric ozone, related to a strengthening of the Brewer-Dobson circulation, particularly through the latter half of the 21st century. Differences in trends in tropospheric ozone among the four RCPs are mainly driven by different methane concentrations, resulting in a range of tropospheric ozone RFs between 0.4 and 0.1 W m−2 by 2100. The ozone dataset described here has been released for the Coupled Model Intercomparison Project (CMIP5) model simulations in netCDF Climate and Forecast (CF) Metadata Convention at the PCMDI website (http://cmip-pcmdi.llnl.gov/).


2012 ◽  
Vol 12 (5) ◽  
pp. 12357-12389
Author(s):  
F. Hendrick ◽  
E. Mahieu ◽  
G. E. Bodeker ◽  
K. F. Boersma ◽  
M. P. Chipperfield ◽  
...  

Abstract. The trend in stratospheric NO2 column at the NDACC (Network for the Detection of Atmospheric Composition Change) station of Jungfraujoch (46.5° N, 8.0° E) is assessed using ground-based FTIR and zenith-scattered visible sunlight SAOZ measurements over the period 1990 to 2009 as well as a composite satellite nadir data set constructed from ERS-2/GOME, ENVISAT/SCIAMACHY, and METOP-A/GOME-2 observations over the 1996–2009 period. To calculate the trends, a linear least squares regression model including explanatory variables for a linear trend, the mean annual cycle, the quasi-biennial oscillation (QBO), solar activity, and stratospheric aerosol loading is used. For the 1990–2009 period, statistically indistinguishable trends of −3.7 ± 1.1%/decade and −3.6 ± 0.9%/decade are derived for the SAOZ and FTIR NO2 column time series, respectively. SAOZ, FTIR, and satellite nadir data sets show a similar decrease over the 1996–2009 period, with trends of −2.4 ± 1.1%/decade, −4.3 ± 1.4%/decade, and −3.6 ± 2.2%/decade, respectively. The fact that these declines are opposite in sign to the globally observed +2.5%/decade trend in N2O, suggests that factors other than N2O are driving the evolution of stratospheric NO2 at northern mid-latitudes. Possible causes of the decrease in stratospheric NO2 columns have been investigated. The most likely cause is a change in the NO2/NO partitioning in favor of NO, due to a possible stratospheric cooling and a decrease in stratospheric chlorine content, the latter being further confirmed by the negative trend in the ClONO2 column derived from FTIR observations at Jungfraujoch. Decreasing ClO concentrations slows the NO + ClO → NO2 + Cl reaction and a stratospheric cooling slows the NO + O3 → NO2 + O2 reaction, leaving more NOx in the form of NO. The slightly positive trends in ozone estimated from ground- and satellite-based data sets are also consistent with the decrease of NO2 through the NO2 + O3 → NO3 + O2 reaction. Finally, we cannot rule out the possibility that a strengthening of the Dobson-Brewer circulation, which reduces the time available for N2O photolysis in the stratosphere, could also contribute to the observed decline in stratospheric NO2 above Jungfraujoch.


2021 ◽  
Author(s):  
Gabriel Chiodo ◽  
William T. Ball ◽  
Peer Nowack ◽  
Clara Orbe ◽  
James Keeble ◽  
...  

<p>Previous studies indicate a possible role of stratospheric ozone chemistry feedbacks in the climate response to 4xCO2, either via a reduction in equilibrium climate sensitivity (ECS) or via changes in the tropospheric circulation (Nowack et al., 2015; Chiodo and Polvani, 2017). However, these effects are subject to uncertainty. Part of the uncertainty may stem from the dependency of the feedback on the pattern of the ozone response, as the radiative efficiency of ozone largely depends on its vertical distribution (Lacis et al., 1990). Here, an analysis is presented of the ozone layer response to 4xCO2 in chemistry–climate models (CCMs) which participated to CMIP inter-comparisons. In a previous study using CMIP5 models, it has been shown that under 4xCO2, ozone decreases in the tropical lower stratosphere, and increases over the high latitudes and throughout the upper stratosphere (Chiodo et al., 2018). It was also found that a substantial portion of the spread in the tropical column ozone is tied to inter-model spread in tropical upwelling, which is in turn tied to ECS. Here, we revisit this connection using 4xCO2 data from CMIP6, thereby exploiting the larger number of CCMs available than in CMIP5. In addition, we explore the linearity of the ozone response, by complementing the analysis with simulations using lower CO2 forcing levels (2xCO2). We show that the pattern of the ozone response is similar to CMIP5. In some models (e.g. WACCM), we find larger ozone responses in CMIP6 than in CMIP5, partly because of the larger ECS and thus larger upwelling response in the tropical pipe. In this presentation, we will discuss the relationship between radiative forcing, transport and ozone, as well as further implications for CMIP6 models.</p>


2020 ◽  
Vol 20 (11) ◽  
pp. 6991-7019
Author(s):  
Markus Kunze ◽  
Tim Kruschke ◽  
Ulrike Langematz ◽  
Miriam Sinnhuber ◽  
Thomas Reddmann ◽  
...  

Abstract. Variations in the solar spectral irradiance (SSI) with the 11-year sunspot cycle have been shown to have a significant impact on temperatures and the mixing ratios of atmospheric constituents in the stratosphere and mesosphere. Uncertainties in modelling the effects of SSI variations arise from uncertainties in the empirical models reconstructing the prescribed SSI data set as well as from uncertainties in the chemistry–climate model (CCM) formulation. In this study CCM simulations with the ECHAM/MESSy Atmospheric Chemistry (EMAC) model and the Community Earth System Model 1 (CESM1)–Whole Atmosphere Chemistry Climate Model (WACCM) have been performed to quantify the uncertainties of the solar responses in chemistry and dynamics that are due to the usage of five different SSI data sets or the two CCMs. We apply a two-way analysis of variance (ANOVA) to separate the influence of the SSI data sets and the CCMs on the variability of the solar response in shortwave heating rates, temperature, and ozone. The solar response is derived from climatological differences of time slice simulations prescribing SSI for the solar maximum in 1989 and near the solar minimum in 1994. The SSI values for the solar maximum of each SSI data set are created by adding the SSI differences between November 1994 and November 1989 to a common SSI reference spectrum for near-solar-minimum conditions based on ATLAS-3 (Atmospheric Laboratory of Applications and Science-3). The ANOVA identifies the SSI data set with the strongest influence on the variability of the solar response in shortwave heating rates in the upper mesosphere and in the upper stratosphere–lower mesosphere. The strongest influence on the variability of the solar response in ozone and temperature is identified in the upper stratosphere–lower mesosphere. However, in the region of the largest ozone mixing ratio, in the stratosphere from 50 to 10 hPa, the SSI data sets do not contribute much to the variability of the solar response when the Spectral And Total Irradiance REconstructions-T (SATIRE-T) SSI data set is omitted. The largest influence of the CCMs on variability of the solar responses can be identified in the upper mesosphere. The solar response in the lower stratosphere also depends on the CCM used, especially in the tropics and northern hemispheric subtropics and mid-latitudes, where the model dynamics modulate the solar responses. Apart from the upper mesosphere, there are also regions where the largest fraction of the variability of the solar response is explained by randomness, especially for the solar response in temperature.


2015 ◽  
Vol 12 (7) ◽  
pp. 2195-2205 ◽  
Author(s):  
R. M. Bright ◽  
G. Myhre ◽  
R. Astrup ◽  
C. Antón-Fernández ◽  
A. H. Strømman

Abstract. In the presence of snow, the bias in the prediction of surface albedo by many climate models remains difficult to correct due to the difficulties of separating the albedo parameterizations from those describing snow and vegetation cover and structure. This can be overcome by extracting the albedo parameterizations in isolation, by executing them with observed meteorology and information on vegetation structure, and by comparing the resulting predictions to observations. Here, we employ an empirical data set of forest structure and daily meteorology for three snow cover seasons and for three case regions in boreal Norway to compute and evaluate predicted albedo to those based on daily MODIS retrievals. Forest and adjacent open area albedos are subsequently used to estimate bias in top-of-the-atmosphere (TOA) radiative forcings (RF) from albedo changes (Δα, Open–Forest) connected to land use and land cover changes (LULCC). As expected, given the diversity of approaches by which snow masking by tall-statured vegetation is parameterized, the magnitude and sign of the albedo biases varied considerably for forests. Large biases at the open sites were also detected, which was unexpected given that these sites were snow-covered throughout most of the analytical time period, therefore eliminating potential biases linked to snow-masking parameterizations. Biases at the open sites were mostly positive, exacerbating the strength of vegetation masking effects and hence the simulated LULCC Δα RF. Despite the large biases in both forest and open area albedos by some schemes in some months and years, the mean Δα RF bias over the 3-year period (November–May) was considerably small across models (−2.1 ± 1.04 Wm−2; 21 ± 11%); four of six models had normalized mean absolute errors less than 20%. Identifying systematic sources of the albedo prediction biases proved challenging, although for some schemes clear sources were identified.


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