scholarly journals Sea ice as a source of sea salt aerosol to Greenland ice cores: a model-based study

2017 ◽  
Vol 17 (15) ◽  
pp. 9417-9433 ◽  
Author(s):  
Rachael H. Rhodes ◽  
Xin Yang ◽  
Eric W. Wolff ◽  
Joseph R. McConnell ◽  
Markus M. Frey
Keyword(s):  
Sea Ice ◽  
Atmospheric Chemistry ◽  
Transport Model ◽  
Ice Core ◽  
Ice Cores ◽  
Open Ocean ◽  
Sea Salt ◽  
The Arctic ◽  
Sea Salt Aerosol ◽  
Annual Variability

Abstract. Growing evidence suggests that the sea ice surface is an important source of sea salt aerosol and this has significant implications for polar climate and atmospheric chemistry. It also suggests the potential to use ice core sea salt records as proxies for past sea ice extent. To explore this possibility in the Arctic region, we use a chemical transport model to track the emission, transport, and deposition of sea salt from both the open ocean and the sea ice, allowing us to assess the relative importance of each. Our results confirm the importance of sea ice sea salt (SISS) to the winter Arctic aerosol burden. For the first time, we explicitly simulate the sea salt concentrations of Greenland snow, achieving values within a factor of two of Greenland ice core records. Our simulations suggest that SISS contributes to the winter maxima in sea salt characteristic of ice cores across Greenland. However, a north–south gradient in the contribution of SISS relative to open-ocean sea salt (OOSS) exists across Greenland, with 50 % of winter sea salt being SISS at northern sites such as NEEM (77° N), while only 10 % of winter sea salt is SISS at southern locations such as ACT10C (66° N). Our model shows some skill at reproducing the inter-annual variability in sea salt concentrations for 1991–1999, particularly at Summit where up to 62 % of the variability is explained. Future work will involve constraining what is driving this inter-annual variability and operating the model under different palaeoclimatic conditions.

scholarly journals Sea ice as a source of sea salt aerosol to Greenland ice cores: a model-based study

2017 ◽  
Author(s):  
Rachael H. Rhodes ◽  
Xin Yang ◽  
Eric W. Wolff ◽  
Joseph R. McConnell ◽  
Markus M. Frey
Keyword(s):  
Sea Ice ◽  
Atmospheric Chemistry ◽  
Transport Model ◽  
Ice Core ◽  
Ice Cores ◽  
Open Ocean ◽  
Sea Salt ◽  
The Arctic ◽  
Sea Salt Aerosol ◽  
Annual Variability

Abstract. Growing evidence suggests that the sea ice surface is an important source of sea salt aerosol and this has significant implications for polar climate and atmospheric chemistry. It also offers the opportunity to use ice core sea salt records as proxies for past sea ice extent. To explore this possibility in the Arctic region, we use a chemical transport model to track the emission, transport and deposition of sea salt from both the open ocean and the sea ice, allowing us to assess the relative importance of each. Our results confirm the importance of sea ice sea salt (SISS) to the winter Arctic aerosol burden. For the first time, we explicitly simulate the sea salt concentrations of Greenland snow and find they match high resolution Greenland ice core records to within a factor of two. Our simulations suggest that SISS contributes to the winter maxima in sea salt characteristic of ice cores across Greenland. A north-south gradient in the contribution of SISS relative to open ocean sea salt (OOSS) exists across Greenland, with 50 % of sea salt being SISS at northern sites such as NEEM, while only 10 % of sea salt is SISS at southern locations such as ACT10C. Our model shows some skill at reproducing the inter-annual variability in sea salt concentrations for 1991–1999 AD, particularly at Summit where up to 62 % of the variability is explained. Future work will involve constraining what is driving this inter-annual variability and operating the model under different paleoclimatic conditions.

Exploring ice core sea ice proxies through process-based modelling

2020 ◽  
Author(s):  
Rachael Rhodes ◽  
Xin Yang ◽  
Eric Wolff
Keyword(s):  
Sea Ice ◽  
Atmospheric Chemistry ◽  
Ice Core ◽  
Ice Cores ◽  
Sea Salt ◽  
Atmospheric Composition ◽  
The Arctic ◽  
Sea Salt Aerosol ◽  
Aerosol Emission ◽  
The Impact

<p>It is important to understand the magnitude and rate of past sea ice changes, as well as their timing relative to abrupt shifts in other components of Earth’s climate system. Furthermore, records of past sea ice over the last few centuries are urgently needed to assess the scale of natural (internal) variability over decadal timescales. By continuously recording past atmospheric composition, polar ice cores have the potential to document changing sea ice conditions if atmospheric chemistry is altered.  Sea salt aerosol, specifically sodium (Na), and bromine enrichment (Br<sub>enr</sub>, Br/Na enriched relative to seawater ratio) are two ice core sea ice proxies suggested following this premise.</p><p>Here we aim to move beyond a conceptual understanding of the controls on Na and Br<sub>enr</sub> in ice cores by using process-based modelling to test hypotheses. We present results of experiments using a 3D global chemical transport model (p-TOMCAT) that represents marine aerosol emission, transport and deposition. Critically, the complex atmospheric chemistry of bromine is also included. Three fundamental issues will be examined: 1) the partitioning of Br between gas and aerosol phases, 2) sea salt aerosol production from first-year versus multi-year sea ice, and 3) the impact of increased acidity in the atmosphere due to human activity in the Arctic.</p>

Exploring ice core sea ice proxies through process-based modelling

2021 ◽  
Author(s):  
Rachael Rhodes ◽  
Xin Yang ◽  
Eric Wolff
Keyword(s):  
Sea Ice ◽  
Atmospheric Chemistry ◽  
Transport Model ◽  
Ice Core ◽  
Ice Cores ◽  
Internal Variability ◽  
Atmospheric Composition ◽  
Chemical Transport Model ◽  
Aerosol Emission ◽  
Abrupt Shifts

<p>It is important to understand the magnitude and rate of past sea ice changes, as well as their timing relative to abrupt shifts in other components of Earth’s climate system. Furthermore, records of past sea ice over the last few centuries are urgently needed to assess the scale of natural (internal) variability over decadal timescales. By continuously recording past atmospheric composition, polar ice cores have the potential to document changing sea ice conditions if atmospheric chemistry is altered.  Sea salt aerosol, specifically sodium (Na), and bromine enrichment (Br<sub>enr</sub>, Br/Na enriched relative to seawater ratio) are two ice core sea ice proxies suggested following this premise.</p><p>Here we aim to move beyond a conceptual understanding of the controls on Na and Br<sub>enr</sub> in ice cores by using process-based modelling to test hypotheses. We present results of experiments using a 3D global chemical transport model (p-TOMCAT) that represents marine aerosol emission, transport and deposition. Critically, the complex atmospheric chemistry of bromine is also included allowing us to explore the partitioning of Br between gas and aerosol phases.  </p>

scholarly journals First direct observation of sea salt aerosol production from blowing snow above sea ice

2020 ◽  
Vol 20 (4) ◽  
pp. 2549-2578 ◽  
Author(s):  
Markus M. Frey ◽  
Sarah J. Norris ◽  
Ian M. Brooks ◽  
Philip S. Anderson ◽  
Kouichi Nishimura ◽  
...  
Keyword(s):  
Sea Ice ◽  
Ice Cores ◽  
Open Ocean ◽  
Weddell Sea ◽  
Sea Salt ◽  
Local Source ◽  
Blowing Snow ◽  
Long Distance ◽  
First Order ◽  
Sea Salt Aerosol

Abstract. Two consecutive cruises in the Weddell Sea, Antarctica, in winter 2013 provided the first direct observations of sea salt aerosol (SSA) production from blowing snow above sea ice, thereby validating a model hypothesis to account for winter time SSA maxima in the Antarctic. Blowing or drifting snow often leads to increases in SSA during and after storms. For the first time it is shown that snow on sea ice is depleted in sulfate relative to sodium with respect to seawater. Similar depletion in bulk aerosol sized ∼0.3–6 µm above sea ice provided the evidence that most sea salt originated from snow on sea ice and not the open ocean or leads, e.g. >90 % during the 8 June to 12 August 2013 period. A temporally very close association of snow and aerosol particle dynamics together with the long distance to the nearest open ocean further supports SSA originating from a local source. A mass budget estimate shows that snow on sea ice contains even at low salinity (<0.1 psu) more than enough sea salt to account for observed increases in atmospheric SSA during storms if released by sublimation. Furthermore, snow on sea ice and blowing snow showed no or small depletion of bromide relative to sodium with respect to seawater, whereas aerosol was enriched at 2 m and depleted at 29 m, suggesting that significant bromine loss takes place in the aerosol phase further aloft and that SSA from blowing snow is a source of atmospheric reactive bromine, an important ozone sink, even during winter darkness. The relative increase in aerosol concentrations with wind speed was much larger above sea ice than above the open ocean, highlighting the importance of a sea ice source in winter and early spring for the aerosol burden above sea ice. Comparison of absolute increases in aerosol concentrations during storms suggests that to a first order corresponding aerosol fluxes above sea ice can rival those above the open ocean depending on particle size. Evaluation of the current model for SSA production from blowing snow showed that the parameterizations used can generally be applied to snow on sea ice. Snow salinity, a sensitive model parameter, depends to a first order on snowpack depth and therefore was higher above first-year sea ice (FYI) than above multi-year sea ice (MYI). Shifts in the ratio of FYI and MYI over time are therefore expected to change the seasonal SSA source flux and contribute to the variability of SSA in ice cores, which represents both an opportunity and a challenge for the quantitative interpretation of sea salt in ice cores as a proxy for sea ice.

scholarly journals A reinterpretation of sea-salt records in Greenland and Antarctic ice cores?

2004 ◽  
Vol 39 ◽  
pp. 276-282 ◽  
Author(s):  
Andrew M. Rankin ◽  
Eric W. Wolff ◽  
Robert Mulvaney
Keyword(s):  
Sea Ice ◽  
Ice Core ◽  
Open Water ◽  
Weddell Sea ◽  
Sea Salt ◽  
Sea Salt Aerosol ◽  
Ice Surface ◽  
Frost Flowers ◽  
Ice Production ◽  
Ice Core Records

AbstractIt has recently been shown that much sea-salt aerosol around the coast of Antarctica is generated not from open water, but from the surface of newly formed sea ice. Previous interpretations of ice-core records have disregarded the sea-ice surface as a source of sea salt. The majority of sea-salt aerosol at Halley research station originates from frost flowers rather than open water, and the seasonal cycle of sea salt in aerosol at Halley appears to be controlled by ice production in the Weddell Sea, as well as variations in wind speed. Frost flowers are also an important source of aerosol at Siple Dome, suggesting that variations in sea-salt concentrations in the core, and other cores drilled in similar locations, may be reflecting changes in sea-ice production rather than changes in transportation patterns. For Greenland cores, and those from low-accumulation inland sites in Antarctica, it is not simple to calculate the proportion of sea salt originating from frost flowers rather than open water. However, modelling studies suggest that a sea-ice surface source contributed much of the flux of sea salt to these sites in glacial periods, suggesting that interpretations of ice-core records from these locations should also be revisited.

scholarly journals High-resolution mineral dust and sea ice proxy records from the Talos Dome ice core

2013 ◽  
Vol 9 (6) ◽  
pp. 2789-2807 ◽  
Author(s):  
S. Schüpbach ◽  
U. Federer ◽  
P. R. Kaufmann ◽  
S. Albani ◽  
C. Barbante ◽  
...  
Keyword(s):  
Southern Ocean ◽  
Sea Ice ◽  
Ross Sea ◽  
Transport Model ◽  
Mineral Dust ◽  
Ice Core ◽  
Ice Cores ◽  
Last Interglacial ◽  
The Holocene ◽  
Proxy Records

Abstract. In this study we report on new non-sea salt calcium (nssCa2+, mineral dust proxy) and sea salt sodium (ssNa+, sea ice proxy) records along the East Antarctic Talos Dome deep ice core in centennial resolution reaching back 150 thousand years (ka) before present. During glacial conditions nssCa2+ fluxes in Talos Dome are strongly related to temperature as has been observed before in other deep Antarctic ice core records, and has been associated with synchronous changes in the main source region (southern South America) during climate variations in the last glacial. However, during warmer climate conditions Talos Dome mineral dust input is clearly elevated compared to other records mainly due to the contribution of additional local dust sources in the Ross Sea area. Based on a simple transport model, we compare nssCa2+ fluxes of different East Antarctic ice cores. From this multi-site comparison we conclude that changes in transport efficiency or atmospheric lifetime of dust particles do have a minor effect compared to source strength changes on the large-scale concentration changes observed in Antarctic ice cores during climate variations of the past 150 ka. Our transport model applied on ice core data is further validated by climate model data. The availability of multiple East Antarctic nssCa2+ records also allows for a revision of a former estimate on the atmospheric CO2 sensitivity to reduced dust induced iron fertilisation in the Southern Ocean during the transition from the Last Glacial Maximum to the Holocene (T1). While a former estimate based on the EPICA Dome C (EDC) record only suggested 20 ppm, we find that reduced dust induced iron fertilisation in the Southern Ocean may be responsible for up to 40 ppm of the total atmospheric CO2 increase during T1. During the last interglacial, ssNa+ levels of EDC and EPICA Dronning Maud Land (EDML) are only half of the Holocene levels, in line with higher temperatures during that period, indicating much reduced sea ice extent in the Atlantic as well as the Indian Ocean sector of the Southern Ocean. In contrast, Holocene ssNa+ flux in Talos Dome is about the same as during the last interglacial, indicating that there was similar ice cover present in the Ross Sea area during MIS 5.5 as during the Holocene.

Supplementary material to "Sea ice as a source of sea salt aerosol to Greenland ice cores: a model-based study"

2017 ◽  
Author(s):  
Rachael H. Rhodes ◽  
Xin Yang ◽  
Eric W. Wolff ◽  
Joseph R. McConnell ◽  
Markus M. Frey
Keyword(s):  
Sea Ice ◽  
Ice Cores ◽  
Sea Salt ◽  
Sea Salt Aerosol ◽  
Model Based ◽  
Supplementary Material

scholarly journals The effect of sea ice loss on sea salt aerosol concentrations and the radiative balance in the Arctic

2010 ◽  
Vol 10 (11) ◽  
pp. 28859-28908 ◽  
Author(s):  
H. Struthers ◽  
A. M. L. Ekman ◽  
P. Glantz ◽  
T. Iversen ◽  
A. Kirkevåg ◽  
...  
Keyword(s):  
Sea Ice ◽  
Sea Salt ◽  
The Arctic ◽  
Polar Cap ◽  
Sea Ice Extent ◽  
Arctic Clouds ◽  
Radiative Balance ◽  
Sea Salt Aerosol ◽  
Aerosol Emissions ◽  
Natural Aerosol

Abstract. Understanding Arctic climate change requires knowledge of both the external and the local drivers of Arctic climate as well as local feedbacks within the system. An Arctic feedback mechanism relating changes in sea ice extent to an alteration of the emission of sea salt aerosol and the consequent change in radiative balance is examined. A set of idealized climate model simulations were performed to quantify the radiative effects of changes in sea salt aerosol emissions induced by prescribed changes in sea ice extent. The model was forced using sea ice concentrations consistent with present day conditions and projections of sea ice extent for 2100. Sea salt aerosol emissions increase in response to a decrease in sea ice, the model results showing an annual average increase in number emission over the polar cap (70–90° N) of 86×106 m−2 s−1 (mass emission increase of 23 μg m−2 s−1). This in turn leads to an increase in the natural aerosol optical depth of approximately 23%. In response to changes in aerosol optical depth, the natural component of the aerosol direct forcing over the Arctic polar cap is estimated to be between −0.2 and −0.4 W m−2 for the summer months, which results in a negative feedback on the system. The model predicts that the change in first indirect aerosol effect (cloud albedo effect) is approximately a factor of ten greater than the change in direct aerosol forcing although this result is highly uncertain due to the crude representation of Arctic clouds and aerosol-cloud interactions in the model. This study shows that both the natural aerosol direct and first indirect effects are strongly dependent on the surface albedo, highlighting the strong coupling between sea ice, aerosols, Arctic clouds and their radiative effects.

scholarly journals First direct observation of sea salt aerosol production from blowing snow above sea ice

2019 ◽  
Author(s):  
Markus M. Frey ◽  
Sarah J. Norris ◽  
Ian M. Brooks ◽  
Philip S. Anderson ◽  
Kouichi Nishimura ◽  
...  
Keyword(s):  
Sea Ice ◽  
Sea Water ◽  
Open Ocean ◽  
Weddell Sea ◽  
Sea Salt ◽  
Polar Regions ◽  
Blowing Snow ◽  
Snow Layer ◽  
Sea Salt Aerosol ◽  
Drifting Snow

Abstract. Two consecutive cruises in the Weddell Sea, Antarctica, in winter 2013 provided the first direct observations of sea salt aerosol (SSA) production from blowing snow above sea ice, thereby validating a model hypothesis to account for winter time SSA maxima in polar regions not explained otherwise. Blowing or drifting snow always lead to increases in SSA during and after storms. Observed aerosol gradients suggest that net production of SSA takes place near the top of the blowing or drifting snow layer. The observed relative increase of SSA concentrations with wind speed suggests that on average the corresponding aerosol mass flux during storms was equal or larger above sea ice than above the open ocean, demonstrating the importance of the blowing snow source for SSA in winter and early spring. For the first time it is shown that snow on sea ice is depleted in sulphate relative to sodium with respect to sea water. Similar depletion observed in the aerosol suggests that most sea salt originated from snow on sea ice and not the open ocean or leads, e.g. on average 93 % during the 8 June and 12 August 2013 period. A mass budget calculation shows that sublimation of snow even with low salinity (

scholarly journals Evaluating the impact of blowing-snow sea salt aerosol on springtime BrO and O<sub>3</sub> in the Arctic

2020 ◽  
Vol 20 (12) ◽  
pp. 7335-7358 ◽  
Author(s):  
Jiayue Huang ◽  
Lyatt Jaeglé ◽  
Qianjie Chen ◽  
Becky Alexander ◽  
Tomás Sherwen ◽  
...  
Keyword(s):  
Sea Ice ◽  
Sea Salt ◽  
The Arctic ◽  
Blowing Snow ◽  
Sea Salt Aerosol ◽  
Surface Sites ◽  
Surface Snow ◽  
Ozone Monitoring ◽  
Halogen Activation ◽  
Arctic Surface

Abstract. We use the GEOS-Chem chemical transport model to examine the influence of bromine release from blowing-snow sea salt aerosol (SSA) on springtime bromine activation and O3 depletion events (ODEs) in the Arctic lower troposphere. We evaluate our simulation against observations of tropospheric BrO vertical column densities (VCDtropo) from the GOME-2 (second Global Ozone Monitoring Experiment) and Ozone Monitoring Instrument (OMI) spaceborne instruments for 3 years (2007–2009), as well as against surface observations of O3. We conduct a simulation with blowing-snow SSA emissions from first-year sea ice (FYI; with a surface snow salinity of 0.1 psu) and multi-year sea ice (MYI; with a surface snow salinity of 0.05 psu), assuming a factor of 5 bromide enrichment of surface snow relative to seawater. This simulation captures the magnitude of observed March–April GOME-2 and OMI VCDtropo to within 17 %, as well as their spatiotemporal variability (r=0.76–0.85). Many of the large-scale bromine explosions are successfully reproduced, with the exception of events in May, which are absent or systematically underpredicted in the model. If we assume a lower salinity on MYI (0.01 psu), some of the bromine explosions events observed over MYI are not captured, suggesting that blowing snow over MYI is an important source of bromine activation. We find that the modeled atmospheric deposition onto snow-covered sea ice becomes highly enriched in bromide, increasing from enrichment factors of ∼5 in September–February to 10–60 in May, consistent with composition observations of freshly fallen snow. We propose that this progressive enrichment in deposition could enable blowing-snow-induced halogen activation to propagate into May and might explain our late-spring underestimate in VCDtropo. We estimate that the atmospheric deposition of SSA could increase snow salinity by up to 0.04 psu between February and April, which could be an important source of salinity for surface snow on MYI as well as FYI covered by deep snowpack. Inclusion of halogen release from blowing-snow SSA in our simulations decreases monthly mean Arctic surface O3 by 4–8 ppbv (15 %–30 %) in March and 8–14 ppbv (30 %–40 %) in April. We reproduce a transport event of depleted O3 Arctic air down to 40∘ N observed at many sub-Arctic surface sites in early April 2007. While our simulation captures 25 %–40 % of the ODEs observed at coastal Arctic surface sites, it underestimates the magnitude of many of these events and entirely misses 60 %–75 % of ODEs. This difficulty in reproducing observed surface ODEs could be related to the coarse horizontal resolution of the model, the known biases in simulating Arctic boundary layer exchange processes, the lack of detailed chlorine chemistry, and/or the fact that we did not include direct halogen activation by snowpack chemistry.

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