scholarly journals High-resolution mineral dust and sea ice proxy records from the Talos Dome ice core

2013 ◽  
Vol 9 (6) ◽  
pp. 2789-2807 ◽  
Author(s):  
S. Schüpbach ◽  
U. Federer ◽  
P. R. Kaufmann ◽  
S. Albani ◽  
C. Barbante ◽  
...  
Keyword(s):  
Southern Ocean ◽  
Sea Ice ◽  
Ross Sea ◽  
Transport Model ◽  
Mineral Dust ◽  
Ice Core ◽  
Ice Cores ◽  
Last Interglacial ◽  
The Holocene ◽  
Proxy Records

Abstract. In this study we report on new non-sea salt calcium (nssCa2+, mineral dust proxy) and sea salt sodium (ssNa+, sea ice proxy) records along the East Antarctic Talos Dome deep ice core in centennial resolution reaching back 150 thousand years (ka) before present. During glacial conditions nssCa2+ fluxes in Talos Dome are strongly related to temperature as has been observed before in other deep Antarctic ice core records, and has been associated with synchronous changes in the main source region (southern South America) during climate variations in the last glacial. However, during warmer climate conditions Talos Dome mineral dust input is clearly elevated compared to other records mainly due to the contribution of additional local dust sources in the Ross Sea area. Based on a simple transport model, we compare nssCa2+ fluxes of different East Antarctic ice cores. From this multi-site comparison we conclude that changes in transport efficiency or atmospheric lifetime of dust particles do have a minor effect compared to source strength changes on the large-scale concentration changes observed in Antarctic ice cores during climate variations of the past 150 ka. Our transport model applied on ice core data is further validated by climate model data. The availability of multiple East Antarctic nssCa2+ records also allows for a revision of a former estimate on the atmospheric CO2 sensitivity to reduced dust induced iron fertilisation in the Southern Ocean during the transition from the Last Glacial Maximum to the Holocene (T1). While a former estimate based on the EPICA Dome C (EDC) record only suggested 20 ppm, we find that reduced dust induced iron fertilisation in the Southern Ocean may be responsible for up to 40 ppm of the total atmospheric CO2 increase during T1. During the last interglacial, ssNa+ levels of EDC and EPICA Dronning Maud Land (EDML) are only half of the Holocene levels, in line with higher temperatures during that period, indicating much reduced sea ice extent in the Atlantic as well as the Indian Ocean sector of the Southern Ocean. In contrast, Holocene ssNa+ flux in Talos Dome is about the same as during the last interglacial, indicating that there was similar ice cover present in the Ross Sea area during MIS 5.5 as during the Holocene.

scholarly journals Sources and transport of dust to East Antarctica: new insights from high-resolution terrestrial and marine aerosol records from the Talos Dome ice core

2013 ◽  
Vol 9 (3) ◽  
pp. 3321-3370 ◽  
Author(s):  
S. Schüpbach ◽  
U. Federer ◽  
S. Albani ◽  
C. Barbante ◽  
T. F. Stocker ◽  
...  
Keyword(s):  
Ross Sea ◽  
Transport Model ◽  
Ice Core ◽  
Ice Cores ◽  
Sea Salt ◽  
Climate Variations ◽  
Last Interglacial ◽  
The Holocene ◽  
Sea Area ◽  
The Last Glacial

Abstract. In this study we report on new non-sea salt calcium (nssCa2+, mineral dust proxy) and sea salt sodium (ssNa+, sea ice proxy) records along the East Antarctic Talos Dome deep ice core in centennial resolution reaching back 150 thousand years before present. During glacial conditions nssCa2+ fluxes in Talos Dome are strongly related to temperature as has been observed before in other deep Antarctic ice core records, and has been associated with synchronous changes in the main source region (southern South America) during climate variations in the last glacial. However, during warmer climate conditions Talos Dome mineral dust input is clearly elevated compared to other records mainly due to the contribution of additional local dust sources in the Ross Sea area. Based on a simple transport model we compare nssCa2+ fluxes of different East Antarctic ice cores. From this multi-site comparison we conclude that changes in transport efficiency or atmospheric lifetime of dust particles do have a minor effect compared to source strength changes on the large scale concentration changes observed in Antarctic ice cores during climate variations of the past 150 thousand years. Our transport model applied on ice core data only so far is further validated by climate model data. The availability of multiple East Antarctic nssCa2+ records allows for a revision of a former estimate on the atmospheric CO2 sensitivity to reduced dust induced iron fertilisation in the Southern Ocean (SO) during the transition from the Last Glacial Maximum to the Holocene (T1). While the former estimate based on the EDC record only suggested 20 ppm, we find reduced dust induced iron fertilisation in the SO to be responsible for up to 40 ppm of the total atmospheric CO2 increase during T1. During the last interglacial, ssNa+ levels of EDC and EDML are only half of the Holocene levels, in line with higher temperatures during that period, indicating much reduced sea ice extent in the Atlantic as well as the Indian Ocean sector of the SO. In contrast, Holocene ssNa+ flux in Talos Dome is about the same as during the last interglacial, indicating that there was similar ice cover present in the Ross Sea area during MIS 5.5 as during the Holocene.

scholarly journals The preservation of methanesulphonic acid in frozen ice-core samples

2008 ◽  
Vol 54 (187) ◽  
pp. 680-684 ◽  
Author(s):  
Nerilie J. Abram ◽  
Mark A.J. Curran ◽  
Robert Mulvaney ◽  
Tessa Vance
Keyword(s):  
Sea Ice ◽  
Ice Core ◽  
Frozen Storage ◽  
Ice Cores ◽  
Ice Storage ◽  
Core Samples ◽  
Proxy Records ◽  
Subsequent Determination ◽  
Earth’S Climate

AbstractIce-core records of methanesulphonic acid (MSA) provide a potentially powerful tool for producing proxy records of sea ice, a critical but poorly understood component of the Earth’s climate system. However, MSA is able to diffuse through solid ice, and here we examine the effect of two different methods of frozen storage on the preservation of MSA in archived ice-core samples. Re-analysis of archived ice sticks confirms that MSA diffuses out of ice cores archived in this manner. Despite MSA losses of up to 39% after 7 years storage, the ice sticks studied here preserve much of the variability of the original MSA record, suggesting that useful proxy records can be obtained from archived ice sticks. Furthermore, re-analysis of ice-core samples that had been refrozen into discrete bottled samples for storage demonstrates that it is possible to archive ice samples in a way that prevents MSA loss. In this case, accurate records of MSA variability and concentration were preserved even over storage periods of 15 years. This has important implications for the storage of ice cores and subsequent determination of MSA, and demonstrates that ice storage history needs to be considered when interpreting MSA records.

scholarly journals The Ross Sea Dipole – temperature, snow accumulation and sea ice variability in the Ross Sea region, Antarctica, over the past 2700 years

2018 ◽  
Vol 14 (2) ◽  
pp. 193-214 ◽  
Author(s):  
Nancy A. N. Bertler ◽  
Howard Conway ◽  
Dorthe Dahl-Jensen ◽  
Daniel B. Emanuelsson ◽  
Mai Winstrup ◽  
...  
Keyword(s):  
Sea Ice ◽  
Ross Sea ◽  
Ice Core ◽  
Ice Cores ◽  
Snow Accumulation ◽  
Ice Age ◽  
West Antarctica ◽  
Isotopic Enrichment ◽  
The Past ◽  
Western Ross Sea

Abstract. High-resolution, well-dated climate archives provide an opportunity to investigate the dynamic interactions of climate patterns relevant for future projections. Here, we present data from a new, annually dated ice core record from the eastern Ross Sea, named the Roosevelt Island Climate Evolution (RICE) ice core. Comparison of this record with climate reanalysis data for the 1979–2012 interval shows that RICE reliably captures temperature and snow precipitation variability in the region. Trends over the past 2700 years in RICE are shown to be distinct from those in West Antarctica and the western Ross Sea captured by other ice cores. For most of this interval, the eastern Ross Sea was warming (or showing isotopic enrichment for other reasons), with increased snow accumulation and perhaps decreased sea ice concentration. However, West Antarctica cooled and the western Ross Sea showed no significant isotope temperature trend. This pattern here is referred to as the Ross Sea Dipole. Notably, during the Little Ice Age, West Antarctica and the western Ross Sea experienced colder than average temperatures, while the eastern Ross Sea underwent a period of warming or increased isotopic enrichment. From the 17th century onwards, this dipole relationship changed. All three regions show current warming, with snow accumulation declining in West Antarctica and the eastern Ross Sea but increasing in the western Ross Sea. We interpret this pattern as reflecting an increase in sea ice in the eastern Ross Sea with perhaps the establishment of a modern Roosevelt Island polynya as a local moisture source for RICE.

scholarly journals Sea ice as a source of sea salt aerosol to Greenland ice cores: a model-based study

2017 ◽  
Vol 17 (15) ◽  
pp. 9417-9433 ◽  
Author(s):  
Rachael H. Rhodes ◽  
Xin Yang ◽  
Eric W. Wolff ◽  
Joseph R. McConnell ◽  
Markus M. Frey
Keyword(s):  
Sea Ice ◽  
Atmospheric Chemistry ◽  
Transport Model ◽  
Ice Core ◽  
Ice Cores ◽  
Open Ocean ◽  
Sea Salt ◽  
The Arctic ◽  
Sea Salt Aerosol ◽  
Annual Variability

Abstract. Growing evidence suggests that the sea ice surface is an important source of sea salt aerosol and this has significant implications for polar climate and atmospheric chemistry. It also suggests the potential to use ice core sea salt records as proxies for past sea ice extent. To explore this possibility in the Arctic region, we use a chemical transport model to track the emission, transport, and deposition of sea salt from both the open ocean and the sea ice, allowing us to assess the relative importance of each. Our results confirm the importance of sea ice sea salt (SISS) to the winter Arctic aerosol burden. For the first time, we explicitly simulate the sea salt concentrations of Greenland snow, achieving values within a factor of two of Greenland ice core records. Our simulations suggest that SISS contributes to the winter maxima in sea salt characteristic of ice cores across Greenland. However, a north–south gradient in the contribution of SISS relative to open-ocean sea salt (OOSS) exists across Greenland, with 50 % of winter sea salt being SISS at northern sites such as NEEM (77° N), while only 10 % of winter sea salt is SISS at southern locations such as ACT10C (66° N). Our model shows some skill at reproducing the inter-annual variability in sea salt concentrations for 1991–1999, particularly at Summit where up to 62 % of the variability is explained. Future work will involve constraining what is driving this inter-annual variability and operating the model under different palaeoclimatic conditions.

scholarly journals A 200 year sulfate record from 16 Antarctic ice cores and associations with Southern Ocean sea-ice extent

2005 ◽  
Vol 41 ◽  
pp. 155-166 ◽  
Author(s):  
Daniel Dixon ◽  
Paul A. Mayewski ◽  
Susan Kaspari ◽  
Karl Kreutz ◽  
Gordon Hamilton ◽  
...  
Keyword(s):  
Sea Ice ◽  
Ross Sea ◽  
Ice Core ◽  
Ice Cores ◽  
South Pole ◽  
West Antarctica ◽  
The South ◽  
Sea Ice Extent ◽  
West Antarctic ◽  
Low Latitudes

AbstractChemistry data from 16, 50–115m deep, sub-annually dated ice cores are used to investigate spatial and temporal concentration variability of sea-salt (ss) SO42– and excess (xs) SO42– over West Antarctica and the South Pole for the last 200 years. Low-elevation ice-core sites in western West Antarctica contain higher concentrations of SO42– as a result of cyclogenesis over the Ross Ice Shelf and proximity to the Ross Sea Polynya. Linear correlation analysis of 15 West Antarctic ice-core SO42– time series demonstrates that at several sites concentrations of ssSO42– are higher when sea-ice extent (SIE) is greater, and the inverse for xsSO42–. Concentrations of xsSO42– from the South Pole site (East Antarctica) are associated with SIE from the Weddell region, and West Antarctic xsSO42– concentrations are associated with SIE from the Bellingshausen–Amundsen–Ross region. The only notable rise of the last 200 years in xsSO42–, around 1940, is not related to SIE fluctuations and is most likely a result of increased xsSO42– production in the mid–low latitudes and/or an increase in transport efficiency from the mid–low latitudes to central West Antarctica. These high-resolution records show that the source types and source areas of ssSO42– and xsSO42– delivered to eastern and western West Antarctica and the South Pole differ from site to site but can best be resolved using records from spatial ice-core arrays such as the International Trans-Antarctic Scientific Expedition (ITASE).

scholarly journals Sea ice as a source of sea salt aerosol to Greenland ice cores: a model-based study

2017 ◽  
Author(s):  
Rachael H. Rhodes ◽  
Xin Yang ◽  
Eric W. Wolff ◽  
Joseph R. McConnell ◽  
Markus M. Frey
Keyword(s):  
Sea Ice ◽  
Atmospheric Chemistry ◽  
Transport Model ◽  
Ice Core ◽  
Ice Cores ◽  
Open Ocean ◽  
Sea Salt ◽  
The Arctic ◽  
Sea Salt Aerosol ◽  
Annual Variability

Abstract. Growing evidence suggests that the sea ice surface is an important source of sea salt aerosol and this has significant implications for polar climate and atmospheric chemistry. It also offers the opportunity to use ice core sea salt records as proxies for past sea ice extent. To explore this possibility in the Arctic region, we use a chemical transport model to track the emission, transport and deposition of sea salt from both the open ocean and the sea ice, allowing us to assess the relative importance of each. Our results confirm the importance of sea ice sea salt (SISS) to the winter Arctic aerosol burden. For the first time, we explicitly simulate the sea salt concentrations of Greenland snow and find they match high resolution Greenland ice core records to within a factor of two. Our simulations suggest that SISS contributes to the winter maxima in sea salt characteristic of ice cores across Greenland. A north-south gradient in the contribution of SISS relative to open ocean sea salt (OOSS) exists across Greenland, with 50 % of sea salt being SISS at northern sites such as NEEM, while only 10 % of sea salt is SISS at southern locations such as ACT10C. Our model shows some skill at reproducing the inter-annual variability in sea salt concentrations for 1991–1999 AD, particularly at Summit where up to 62 % of the variability is explained. Future work will involve constraining what is driving this inter-annual variability and operating the model under different paleoclimatic conditions.

scholarly journals Sea-ice feedbacks influence the isotopic signature of Greenland Ice Sheet elevation changes: Last Interglacial HadCM3 simulations

2020 ◽  
Author(s):  
Irene Malmierca-Vallet ◽  
Louise C. Sime ◽  
Paul J. Valdes ◽  
Julia C. Tindall
Keyword(s):  
Sea Ice ◽  
Ice Core ◽  
Ice Sheet ◽  
Greenland Ice Sheet ◽  
Ice Cores ◽  
Lapse Rate ◽  
Last Interglacial ◽  
Elevation Change ◽  
Elevation Gradients ◽  
Lapse Rates

Abstract. Changes in the Greenland ice sheet (GIS) affect global sea level. Greenland stable water isotope (δ18O) records from ice cores offer information on past changes in the surface of the GIS. Here, we use the isotope-enabled HadCM3 climate model to simulate a set of Last Interglacial (LIG) idealised GIS surface elevation change scenarios focusing on GIS ice core sites. We investigate how δ18O depends on the magnitude and sign of GIS elevation change and evaluate how the response is altered by sea ice changes. We find that modifying GIS elevation induces changes in Northern Hemisphere atmospheric circulation, sea ice and precipitation patterns. These climate feedbacks lead to ice core-averaged isotopic lapse rates of 0.49 ‰ per 100 m for the lowered GIS states and 0.29 ‰ per 100 m for the enlarged GIS states. This is lower than the spatially derived Greenland lapse rates of 0.62–0.72 ‰ per 100 m. These results thus suggest non-linearities in the isotope-elevation relationship, and have consequences for the interpretation of past elevation and climate changes across Greenland. In particular, our results suggest that winter sea ice changes may significantly influence isotopic-elevation gradients: winter sea ice effect can decrease (increase) modelled core-averaged isotopic lapse rate values by about -19 % (and +28 %) for the lowered (enlarged) GIS states respectively. The largest influence of sea ice on δ18O changes is found in coastal regions like the Camp Century site.

Exploring ice core sea ice proxies through process-based modelling

2021 ◽  
Author(s):  
Rachael Rhodes ◽  
Xin Yang ◽  
Eric Wolff
Keyword(s):  
Sea Ice ◽  
Atmospheric Chemistry ◽  
Transport Model ◽  
Ice Core ◽  
Ice Cores ◽  
Internal Variability ◽  
Atmospheric Composition ◽  
Chemical Transport Model ◽  
Aerosol Emission ◽  
Abrupt Shifts

<p>It is important to understand the magnitude and rate of past sea ice changes, as well as their timing relative to abrupt shifts in other components of Earth’s climate system. Furthermore, records of past sea ice over the last few centuries are urgently needed to assess the scale of natural (internal) variability over decadal timescales. By continuously recording past atmospheric composition, polar ice cores have the potential to document changing sea ice conditions if atmospheric chemistry is altered.  Sea salt aerosol, specifically sodium (Na), and bromine enrichment (Br<sub>enr</sub>, Br/Na enriched relative to seawater ratio) are two ice core sea ice proxies suggested following this premise.</p><p>Here we aim to move beyond a conceptual understanding of the controls on Na and Br<sub>enr</sub> in ice cores by using process-based modelling to test hypotheses. We present results of experiments using a 3D global chemical transport model (p-TOMCAT) that represents marine aerosol emission, transport and deposition. Critically, the complex atmospheric chemistry of bromine is also included allowing us to explore the partitioning of Br between gas and aerosol phases.  </p>

Offsets among ice core derived CO2 reconstructions covering the Holocene and Last Interglacial

2020 ◽  
Author(s):  
Christoph Nehrbass-Ahles ◽  
Jochen Schmitt ◽  
Bernhard Bereiter ◽  
Sarah Eggleston ◽  
Lars Mächler ◽  
...  
Keyword(s):  
Atmospheric Carbon Dioxide ◽  
Ice Core ◽  
Ice Cores ◽  
Last Interglacial ◽  
High Accumulation ◽  
The Holocene ◽  
Drilling Site ◽  
Common Signal ◽  
Unambiguous Detection

<p>There is a general consensus in the scientific community that Greenlandic ice cores do not allow for reconstruction of past atmospheric carbon dioxide (CO<sub>2</sub>) concentrations due to artifacts likely caused by <em>in-situ</em> production of excess CO<sub>2</sub> from both organic and inorganic carbon compounds within the ice archive. In the case of Antarctic ice cores such processes are thought to be insignificant, making Antarctic ice cores the only direct archive of past atmospheric CO<sub>2</sub> concentrations beyond modern observations. However, with increasing numbers of high-precision CO<sub>2</sub> reconstructions from multiple Antarctic ice cores – mostly covering specific time intervals during the last 130 ka – it has become evident that offsets in CO<sub>2</sub> are not unique to Greenland ice cores. Over the last decade evidence is mounting that small systematic offsets of typically 2-10 ppm exist among different Antarctic CO<sub>2</sub> records covering the same time period. Because CO<sub>2</sub> is well-mixed within the atmosphere different ice cores should agree with each other within their measurement uncertainty, independent of the ice core drilling site. The unambiguous detection of such offsets between different ice cores is only possible in the absence of strong atmospheric trends, such as during interglacial periods. Here, we take a closer look at CO<sub>2</sub> offsets among records available for the Holocene and the Last Interglacial and investigate their long-term evolution. We present unpublished CO<sub>2</sub> data from multiple ice cores, including Talos Dome and EPICA Dome C, and discuss possible offset producing mechanisms. We speculate that Antarctic ice cores are also subject to slowly progressing <em>in-situ</em> production of CO<sub>2</sub> over many millennia, similar to Greenlandic ice cores, however to a much smaller extent and limited to about 10 ppm. We further note a tendency for higher offsets in the case of high accumulation sites. Despite all possible mechanisms that have the potential to alter CO<sub>2</sub> concentrations within the ice archive, we highlight that the overall integrity of the ice core-based CO<sub>2</sub> reconstruction is not in question, as all records generally share the same common signal. However, the absolute CO<sub>2</sub> levels should be interpreted with care and in light of such potential offsets.</p>

scholarly journals Deep ice as a geochemical reactor: insights from iron speciation and mineralogy of dust in the Talos Dome ice core (East Antarctica)

2021 ◽  
Author(s):  
Giovanni Baccolo ◽  
Barbara Delmonte ◽  
Elena Di Stefano ◽  
Giannantonio Cibin ◽  
Ilaria Crotti ◽  
...  
Keyword(s):  
Ross Sea ◽  
Mineral Dust ◽  
Ice Core ◽  
Ice Cores ◽  
East Antarctica ◽  
Main Process ◽  
Polar Ice ◽  
Atmospheric Species ◽  
Depositional Processes ◽  
Fe Mineralogy

Abstract. Thanks to its insolubility, mineral dust is considered a stable proxy in polar ice cores. With this study we show that below an ice-depth of 1000 m, the Talos Dome ice core (Ross Sea sector of East Antarctica) presents evident and progressive signs of post-depositional processes affecting the mineral dust records. We applied a suite of established and cutting edge techniques to investigate the properties of dust present in the Talos Dome ice core, ranging from concentration and grain-size to elemental-composition and Fe-mineralogy. Results show that through acidic/oxidative weathering, the conditions of deep ice at Talos Dome promote the dissolution of specific minerals and the englacial formation of others, deeply affecting dust primitive features. The expulsion of acidic atmospheric species from ice-grains and their concentration in localized environments is likely the main process responsible for englacial reactions and is related with ice re-crystallization. Deep ice can be seen as a "geochemical reactor" capable of fostering complex reactions which involve both soluble and insoluble impurities. Fe-bearing minerals can efficiently be used to explore such transformations.

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