scholarly journals Nitric acid in the stratosphere based on Odin observations from 2001 to 2007 – Part 2: High-altitude polar enhancements

2008 ◽  
Vol 8 (3) ◽  
pp. 9591-9605 ◽  
Author(s):  
Y. J. Orsolini ◽  
J. Urban ◽  
D. P. Murtagh

Abstract. The wintertime abundance of nitric acid (HNO3) in the polar upper stratosphere displays a strong inter-annual variability, and is known to be strongly influenced by energetic particle precipitation, primarily during solar proton events, but also by precipitating electrons in the auroral zone. While wintertime HNO3 enhancements in the polar upper stratosphere had been occasionally observed before, from the ground or from satellite, we present here measurements by the Sub-Millimeter Radiometer instrument aboard the Odin satellite through 6 full annual cycles (2001 to 2007). Major solar proton events, e.g. during November 2001 or the Halloween solar storms of autumn 2003, lead to a two-stage HNO3 enhancement, likely involving different chemical reactions: a fast (about 1 week) in-situ enhancement from the mid to the upper stratosphere is followed by a slower, longer-lasting one, whereby anomalies originating in the upper stratosphere can descend within the polar vortex into the lower stratosphere. We highlight the fact that the actual chemical coupling between the upper and lower atmosphere involves a complex interplay of chemistry, dynamics and energetic particle precipitation.

2009 ◽  
Vol 9 (5) ◽  
pp. 22459-22504
Author(s):  
A. Robichaud ◽  
R. Ménard ◽  
S. Chabrillat ◽  
J. de Grandpré ◽  
Y. J. Rochon ◽  
...  

Abstract. In 2003, strong geomagnetic events occurred which produced massive amounts of energetic particles penetrating the top of the atmospheric polar region, significantly perturbing its chemical state down to the middle stratosphere. These events and their effects are generally left unaccounted for in current models of stratospheric chemistry and large differences between observations and models are then noted. In this study, we use a coupled 3-D stratospheric dynamical-chemical model and assimilation system to ingest MIPAS temperature and chemical observations. The goal is to gain further understanding and to evaluate the impacts of EPP (energetic particle precipitation) on stratospheric polar chemistry. Moreover, we investigate the feasibility of assimilating valid "outlier" observations associated with such events. We focus our analysis on OmF (Observation minus Forecast) residuals as they filter out phenomena well reproduced by the model (such as gas phase chemistry, transport, diurnal and seasonal cycles) thus revealing a clear trace of the EPP. Inspection of OmF statistics in both the passive (without chemical assimilation) and active (with chemical assimilation) cases altogether provides a powerful diagnostic tool to assess the model and assimilation system. We also show that passive OmF can permit a satisfactory evaluation of the ozone partial column loss due to EPP effects. Results suggest a small but significant loss of 5–6 DU (Dobson Units) during an EPP-IE (EPP indirect effects) event in the Antarctic winter of 2003, and about only 1 DU for the SPE (solar proton event) of October/November 2003. Despite large differences between the model and MIPAS chemical observations (NO2, HNO3, CH4 and O3), we demonstrate that a careful assimilation of these constituents with only gas phase chemistry included in the model (i.e. no provision for EPP impacts) and with relaxed quality control nearly eliminated the short-term bias and significantly reduced the standard deviation error below 1 hPa.


2020 ◽  
Vol 20 (11) ◽  
pp. 6259-6271
Author(s):  
Emily M. Gordon ◽  
Annika Seppälä ◽  
Johanna Tamminen

Abstract. Observations from the Ozone Monitoring Instrument (OMI) on the Aura satellite are used to study the effect of energetic particle precipitation (EPP, as proxied by the geomagnetic activity index, Ap) on the Antarctic stratospheric NO2 column in late winter–spring (August–December) during the period from 2005 to 2017. We show that the polar (60–90∘ S) stratospheric NO2 column is significantly correlated with EPP throughout the Antarctic spring, until the breakdown of the polar vortex in November. The strongest correlation takes place during years with the easterly phase of the quasi-biennial oscillation (QBO). The QBO modulation may be a combination of different effects: the QBO is known to influence the amount of the primary NOx source (N2O) via transport from the Equator to the polar region; and the QBO phase also affects polar temperatures, which may provide a link to the amount of denitrification occurring in the polar vortex. We find some support for the latter in an analysis of temperature and HNO3 observations from the Microwave Limb Sounder (MLS, on Aura). Our results suggest that once the background effect of the QBO is accounted for, the NOx produced by EPP significantly contributes to the stratospheric NO2 column at the time and altitudes when the ozone hole is present in the Antarctic stratosphere. Based on our findings, and the known role of NOx as a catalyst for ozone loss, we propose that as chlorine activation continues to decrease in the Antarctic stratosphere, the total EPP-NOx needs be accounted for in predictions of Antarctic ozone recovery.


2009 ◽  
Vol 9 (18) ◽  
pp. 7045-7052 ◽  
Author(s):  
Y. J. Orsolini ◽  
J. Urban ◽  
D. P. Murtagh

Abstract. The wintertime abundance of nitric acid (HNO3) in the polar upper stratosphere displays a strong inter-annual variability, and is known to be strongly influenced by energetic particle precipitation (EPP), primarily by protons during solar proton events (SPEs), but also by precipitating auroral or relativistic electrons. We analyse a multi-year record (August 2001 to April 2009) of middle atmospheric HNO3 measurements by the Sub-Millimeter Radiometer instrument aboard the Odin satellite, with a focus on the polar upper stratosphere. SMR observations show clear evidence of two different types of polar high-altitude HNO3 enhancements linked to EPP. In the first type, referred to as direct enhancements by analogy with the EPP/NOx direct effect, enhanced HNO3 mixing ratios are observed for a short period (1 week) after a SPE, upwards of a level typically in the mid-stratosphere. In a second type, referred to as indirect enhancements by analogy with the EPP/NOx indirect effect, the descent of mesospheric air triggers a stronger and longer-lasting enhancement. Each of the three major SPEs that occurred during the Northern Hemisphere autumn or winter, in November 2001, October–November 2003 and January 2005, are observed to lead to both direct and indirect HNO3 enhancements. On the other hand, indirect enhancements occur recurrently in winter, are stronger in the Southern Hemisphere, and are influenced by EPP at higher altitudes.


2016 ◽  
Vol 121 (17) ◽  
pp. 10,328-10,341 ◽  
Author(s):  
M. E. Andersson ◽  
P. T. Verronen ◽  
D. R. Marsh ◽  
S.-M. Päivärinta ◽  
J. M. C. Plane

2010 ◽  
Vol 10 (4) ◽  
pp. 1739-1757 ◽  
Author(s):  
A. Robichaud ◽  
R. Ménard ◽  
S. Chabrillat ◽  
J. de Grandpré ◽  
Y. J. Rochon ◽  
...  

Abstract. In 2003, strong energetic particle precipitation (EPP) events occurred producing massive amounts of ionization which affected the polar region significantly perturbing its chemical state down to the middle stratosphere. These events and their effects are generally left unaccounted for in current models of stratospheric chemistry and large differences between observations and models are then noted. In this study, we use a coupled 3-D stratospheric dynamical-chemical model and assimilation system to ingest MIPAS temperature and chemical observations. The goal is to gain further understanding of assimilation and monitoring processes during EPP events and their impacts on the stratospheric polar chemistry. Moreover, we investigate the feasibility of assimilating valid "outlier" observations associated with such events. We use OmF (Observation minus Forecast) residuals as they filter out phenomena well reproduced by the model (such as gas phase chemistry, transport, diurnal and seasonal cycles) thus revealing a clear trace of the EPP. Inspection of OmF statistics in both passive (without chemical assimilation) and active (with chemical assimilation) cases altogether provides a powerful diagnostic tool to assess the model and assimilation system. We also show that passive OmF can permit a satisfactory evaluation of the ozone partial column loss due to EPP effects. Results suggest a small but significant loss of 5–6 DU (Dobson Units) during an EPP-IE (EPP Indirect Effects) event in the Antarctic winter of 2003, and about only 1 DU for the SPE (Solar Proton Event) of October/November 2003. Despite large differences between the model and MIPAS chemical observations (NO2, HNO3, CH4 and O3), we demonstrate that a careful assimilation with only gas phase chemistry included in the model (i.e. no provision for EPP) and with relaxed quality control nearly eliminated the short-term bias and significantly reduced the standard deviation error of the constituents below 1 hPa.


2008 ◽  
Vol 8 (19) ◽  
pp. 5787-5800 ◽  
Author(s):  
B. Funke ◽  
M. López-Puertas ◽  
M. Garcia-Comas ◽  
G. P. Stiller ◽  
T. von Clarmann ◽  
...  

Abstract. N2O abundances ranging from 0.5 to 6 ppbv were observed in the polar upper stratosphere/lower mesosphere by the MIPAS instrument on the Envisat satellite during the Arctic and Antarctic winters in the period July 2002 to March 2004. A detailed study of the observed N2O-CH4 correlations shows that such enhancements cannot be explained by dynamics without invoking an upper atmospheric chemical source of N2O. The N2O enhancements observed at 58 km occurred in the presence of NOx intrusions from the upper atmosphere which were related to energetic particle precipitation. Further, the inter-annual variability of mesospheric N2O correlates well with observed precipitating electron fluxes. The analysis of possible chemical production mechanisms shows that the major part of the observed N2O enhancements is most likely generated under dark conditions by the reaction of NO2 with atomic nitrogen at altitudes around 70–75 km in the presence of energetic particle precipitation (EPP). A possible additional source of N2O in the middle and upper polar atmosphere is the reaction of N2(A3Σu+), generated by precipitating electrons, with O2, which would lead to N2O production peaking at altitudes around 90–100 km. N2O produced by the latter mechanism could then descend to the mesosphere and upper stratosphere during polar winter. The estimated fraction of EPP-generated N2O to the total stratospheric N2O inside the polar vortex above 20 km (30 km) never exceeds 1% (10%) during the 2002–2004 winters. Compared to the global amount of stratospheric N2O, the EPP-generated contribution is negligible.


2017 ◽  
Author(s):  
Miriam Sinnhuber ◽  
Uwe Berger ◽  
Bernd Funke ◽  
Holger Nieder ◽  
Thomas Reddmann ◽  
...  

Abstract. We analyze the impact of energetic particle precipitation on the stratospheric nitrogen budget, ozone abundances and net radiative heating using results from three global chemistry-climate models considering solar protons and geomagnetic forcing due to auroral or radiation belt electrons. Two of the models cover the atmosphere up to the lower thermosphere, the source region of auroral NO production. Geomagnetic forcing in these models is included by prescribed ionization rates. One model reaches up to about 80 km, and geomagnetic forcing is included by applying an upper boundary condition of auroral NO mixing ratios parameterized as a function of geomagnetic activity. Despite the differences in the implementation of the particle effect, the resulting modeled NOy in the upper mesosphere agrees well between all three models, demonstrating that geomagnetic forcing is represented in a consistent way either by prescribing ionization rates or by prescribing NOy at the model top. Compared with observations of stratospheric and mesospheric NOy from the MIPAS instrument for the years 2002–2010, the model simulations reproduce the spatial pattern and temporal evolution well. However, after strong sudden stratospheric warmings, particle induced NOy is underestimated by both high-top models, and after the solar proton event in October 2003, NOy is overestimated by all three models. Model results indicate that the large solar proton event in October 2003 contributed about 1–2 Gmol (109 mol) NOy per hemisphere to the stratospheric NOy budget, while downwelling of auroral NOx from the upper mesosphere and lower thermosphere contributes up to 4 Gmol NOy. Accumulation over time leads to a constant particle-induced background of about 0.5–1 Gmol per hemisphere during solar minimum, and up to 2 Gmol per hemisphere during solar maximum. Related negative anomalies of ozone are predicted by the models nearly in every polar winter, ranging from 10–50 % during solar maximum to 2–10 % during solar minimum. Ozone loss continues throughout polar summer after strong solar proton events in the Southern hemisphere and after large sudden stratospheric warmings in the Northern hemisphere. During mid-winter, the ozone loss causes a reduction of the infrared radiative cooling, i.e., a positive change of the net radiative heating (effective warming), in agreement with analyses of geomagnetic forcing in stratospheric temperatures which show a warming in the late winter upper stratosphere. In late winter and spring, the sign of the net radiative heating change turns to negative (effective cooling). This spring-time cooling lasts well into summer and continues until the following autumn after large solar proton events in the Southern hemisphere, after sudden stratospheric warmings in the Northern hemisphere.


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