scholarly journals Relative drifts and biases between six ozone limb satellite measurements from the last decade

2015 ◽  
Vol 8 (4) ◽  
pp. 3697-3728 ◽  
Author(s):  
N. Rahpoe ◽  
M. Weber ◽  
A. V. Rozanov ◽  
K. Weigel ◽  
H. Bovensmann ◽  
...  
Keyword(s):  
Relative Difference ◽  
Third Party ◽  
Satellite Measurements ◽  
Data Set ◽  
Middle Latitudes ◽  
Ozone Profile ◽  
Combining Data ◽  
High Vertical Resolution ◽  
Long Term Trend

Abstract. As part of ESA's climate change initiative high vertical resolution ozone profiles from three instruments all aboard ESA's Envisat (GOMOS, MIPAS, SCIAMACHY) in combination with ESA's third party missions (OSIRIS, SMR, ACE-FTS) are to be combined in order to create an essential climate variable data record for the last decade. A prerequisite before combining data is the examination of differences and drifts between the datasets. In this paper, we present a detailed analysis of ozone profile differences based on pairwise collocated measuerements, including the evolution of the differences with time. Such a diagnosis is helpful to identify strengths and weaknesses of each data set that may vary in time and introduce uncertainties in long-term trend estimates. Main results of this paper indicate that the 6 instruments perform well in the stratosphere particularly between 20 and 40 km with a mean relative difference of ±5% (middle latitudes) to ±10% (tropics). Larger differences and variability in the differences are found in the upper troposphere lower stratosphere region and in the mesosphere. The analysis reveals that the relative drift between the sensors is not statistically significant for most pairs of instruments.

scholarly journals Relative drifts and biases between six ozone limb satellite measurements from the last decade

2015 ◽  
Vol 8 (10) ◽  
pp. 4369-4381 ◽  
Author(s):  
N. Rahpoe ◽  
M. Weber ◽  
A. V. Rozanov ◽  
K. Weigel ◽  
H. Bovensmann ◽  
...  
Keyword(s):  
Third Party ◽  
Data Sets ◽  
Satellite Measurements ◽  
Data Set ◽  
Ozone Profile ◽  
Combining Data ◽  
High Vertical Resolution ◽  
Added Uncertainty ◽  
Long Term Trend

Abstract. As part of European Space Agency's (ESA) climate change initiative, high vertical resolution ozone profiles from three instruments all aboard ESA's Envisat (GOMOS, MIPAS, SCIAMACHY) and ESA's third party missions (OSIRIS, SMR, ACE-FTS) are to be combined in order to create an essential climate variable data record for the last decade. A prerequisite before combining data is the examination of differences and drifts between the data sets. In this paper, we present a detailed analysis of ozone profile differences based on pairwise collocated measurements, including the evolution of the differences with time. Such a diagnosis is helpful to identify strengths and weaknesses of each data set that may vary in time and introduce uncertainties in long-term trend estimates. The analysis reveals that the relative drift between the sensors is not statistically significant for most pairs of instruments. The relative drift values can be used to estimate the added uncertainty in physical trends. The added drift uncertainty is estimated at about 3 % decade−1 (1σ). Larger differences and variability in the differences are found in the lowermost stratosphere (below 20 km) and in the mesosphere.

Long-term variations of the oxygen red 630 nm line nightglow intensity

2007 ◽  
Vol 85 (2) ◽  
pp. 189-198 ◽  
Author(s):  
N B Gudadze ◽  
G G Didebulidze ◽  
G Sh. Javakhishvili ◽  
M G Shepherd ◽  
M V Vardosanidze
Keyword(s):  
Line Intensity ◽  
Peak Height ◽  
Mean Value ◽  
Lower Atmosphere ◽  
Data Set ◽  
Term Trend ◽  
Long Term Trend ◽  
Long Term Variations ◽  
Red Line

The long-term data set of total nightglow intensity of the oxygen red 630.0~nm line observed at Abastumani (41.8°N, 42.8°E) between 1957–1993 is investigated. The long-term trend and characteristic variations in solar radiation during an 11 year cycle of the red-line intensity are different after astronomical twilight (premidnight) and at midnight. The amplitude of deviation of the red-line intensity from its mean value at solar maximum and (or) minimum phase is greatest after astronomical twilight and decreases toward midnight. The long-term trend of these variations changes from its value about 0.74 R/year premidnight to its minimum negative value of about –1.92 R/year at and after midnight. This behavior of the long-term trend is considered as a possible result of an increase in electron density below the peak height (hmF2) of the ionospheric F2 layer and lowering of the height hmF2 after midnight predicted by the TIME-GCM model on the assumption of an increase in density of greenhouse gases in the lower atmosphere. The third-order regression equation (with different solar activity indices) is considered to be convenient for describing long-term variations in the mean annual red-line intensity.PACS Nos.: 94.10.Rk, 94.20.Ji, 92.60.Vb

scholarly journals Re-analysis of ground-based microwave ClO measurements from Mauna Kea, 1992 to early 2012

2013 ◽  
Vol 13 (17) ◽  
pp. 8643-8650 ◽  
Author(s):  
B. J. Connor ◽  
T. Mooney ◽  
G. E. Nedoluha ◽  
J. W. Barrett ◽  
A. Parrish ◽  
...  
Keyword(s):  
Atmospheric Composition ◽  
Composition Change ◽  
Major Focus ◽  
Short Term ◽  
Data Set ◽  
Long Term Changes ◽  
The Difference ◽  
Long Term Trend ◽  
Linear Decline

Abstract. We present a re-analysis of upper stratospheric ClO measurements from the ground-based millimeter-wave instrument from January 1992 to February 2012. These measurements are made as part of the Network for the Detection of Atmospheric Composition Change (NDACC) from Mauna Kea, Hawaii, (19.8° N, 204.5° E). Here, we use daytime and nighttime measurements together to form a day–night spectrum, from which the difference in the day and night profiles is retrieved. These results are then compared to the day–night difference profiles from the Upper Atmosphere Research Satellite (UARS) and Aura Microwave Limb Sounder (MLS) instruments. We also compare them to our previous analyses of the same data, in which we retrieved the daytime ClO profile. The major focus will be on comparing the year-to-year and long-term changes in ClO derived by the two analysis methods, and comparing these results to the long-term changes reported by others. We conclude that the re-analyzed data set has less short-term variability and exhibits a more constant long-term trend that is more consistent with other observations. Data from 1995 to 2012 indicate a linear decline of mid-stratospheric ClO of 0.64 ± 0.15% yr−1 (2σ).

scholarly journals Long-term trend and variability of atmospheric PM<sub>10</sub> concentration in the Po Valley

2014 ◽  
Vol 14 (10) ◽  
pp. 4895-4907 ◽  
Author(s):  
A. Bigi ◽  
G. Ghermandi
Keyword(s):  
Weekend Effect ◽  
Wilcoxon Test ◽  
Particulate Emissions ◽  
Gaseous Emissions ◽  
Atmospheric Pollutant ◽  
Data Set ◽  
Term Trend ◽  
Po Valley ◽  
Long Term Trend

Abstract. The limits to atmospheric pollutant concentration set by the European Commission provide a challenging target for the municipalities in the Po Valley, because of the characteristic climatic conditions and high population density of this region. In order to assess climatology and trends in the concentration of atmospheric particles in the Po Valley, a data set of PM10 data from 41 sites across the Po Valley have been analysed, including both traffic and background sites (either urban, suburban or rural). Of these 41 sites, 18 with 10 yr or longer record have been analysed for long-term trend in deseasonalized monthly means, in annual quantiles and in monthly frequency distribution. A widespread significant decreasing trend has been observed at most sites, up to a few percent per year, by a generalized least squares and Theil–Sen method. All 41 sites have been tested for significant weekly periodicity by Kruskal–Wallis test for mean anomalies and by Wilcoxon test for weekend effect magnitude. A significant weekly periodicity has been observed for most PM10 series, particularly in summer and ascribed mainly to anthropic particulate emissions. A cluster analysis has been applied in order to highlight stations sharing similar pollution conditions over the reference period. Five clusters have been found, two encompassing the metropolitan areas of Turin and Milan and their respective nearby sites and the other three clusters gathering northeast, northwest and central Po Valley sites respectively. Finally, the observed trends in atmospheric PM10 have been compared to trends in provincial emissions of particulates and PM precursors, and analysed along with data on vehicular fleet age, composition and fuel sales. A significant basin-wide drop in emissions occurred for gaseous pollutants, contrarily to emissions of PM10 and PM2.5, whose drop was low and restricted to a few provinces. It is not clear whether the decrease for only gaseous emissions is sufficient to explain the observed drop in atmospheric PM10, or if the low drop in particulate emissions is indeed due to the uncertainty in the emission inventory data for this species.

scholarly journals Trends in erythemal doses at the Polish Polar Station, Hornsund, Svalbard based on the homogenized measurements (1996–2016) and reconstructed data (1983–1995)

2018 ◽  
Vol 18 (1) ◽  
pp. 1-11 ◽  
Author(s):  
Janusz W. Krzyścin ◽  
Piotr S. Sobolewski
Keyword(s):  
Historical Data ◽  
Sunshine Duration ◽  
Satellite Measurements ◽  
Data Set ◽  
Modification Factor ◽  
Daily Sunshine ◽  
Yearly Dose ◽  
Column Ozone ◽  
Dose Variability

Abstract. Erythemal daily doses measured at the Polish Polar Station, Hornsund (77°00′ N, 15°33′ E), for the periods 1996–2001 and 2005–2016 are homogenized using yearly calibration constants derived from the comparison of observed doses for cloudless conditions with the corresponding doses calculated by radiative transfer (RT) simulations. Modeled all-sky doses are calculated by the multiplication of cloudless RT doses by the empirical cloud modification factor dependent on the daily sunshine duration. An all-sky model is built using daily erythemal doses measured in the period 2005–2006–2007. The model is verified by comparisons with the 1996–1997–1998 and 2009–2010–2011 measured data. The daily doses since 1983 (beginning of the proxy data) are reconstructed using the all-sky model with the historical data of the column ozone from satellite measurements (SBUV merged ozone data set), the snow depth (for ground albedo estimation), and the observed daily sunshine duration at the site. Trend analyses of the monthly and yearly time series comprised of the reconstructed and observed doses do not reveal a statistically significant trend in the period 1983–2016. The trends based on the observed data only (1996–2001 and 2005–2016) show declining tendency (about −1 % per year) in the monthly mean of daily erythemal doses in May and June, and in the yearly sum of daily erythemal doses. An analysis of sources of the yearly dose variability since 1983 shows that cloud cover changes are a basic driver of the long-term UV changes at the site.

scholarly journals ML-TOMCAT: machine-learning-based satellite-corrected global stratospheric ozone profile data set from a chemical transport model

2021 ◽  
Vol 13 (12) ◽  
pp. 5711-5729
Author(s):  
Sandip S. Dhomse ◽  
Carlo Arosio ◽  
Wuhu Feng ◽  
Alexei Rozanov ◽  
Mark Weber ◽  
...  
Keyword(s):  
Transport Model ◽  
Stratospheric Ozone ◽  
Chemical Transport ◽  
Data Sets ◽  
Chemical Transport Model ◽  
Profile Data ◽  
Data Set ◽  
Ozone Profile ◽  
Satellite Instruments

Abstract. High-quality stratospheric ozone profile data sets are a key requirement for accurate quantification and attribution of long-term ozone changes. Satellite instruments provide stratospheric ozone profile measurements over typical mission durations of 5–15 years. Various methodologies have then been applied to merge and homogenise the different satellite data in order to create long-term observation-based ozone profile data sets with minimal data gaps. However, individual satellite instruments use different measurement methods, sampling patterns and retrieval algorithms which complicate the merging of these different data sets. In contrast, atmospheric chemical models can produce chemically consistent long-term ozone simulations based on specified changes in external forcings, but they are subject to the deficiencies associated with incomplete understanding of complex atmospheric processes and uncertain photochemical parameters. Here, we use chemically self-consistent output from the TOMCAT 3-D chemical transport model (CTM) and a random-forest (RF) ensemble learning method to create a merged 42-year (1979–2020) stratospheric ozone profile data set (ML-TOMCAT V1.0). The underlying CTM simulation was forced by meteorological reanalyses, specified trends in long-lived source gases, solar flux and aerosol variations. The RF is trained using the Stratospheric Water and OzOne Satellite Homogenized (SWOOSH) data set over the time periods of the Microwave Limb Sounder (MLS) from the Upper Atmosphere Research Satellite (UARS) (1991–1998) and Aura (2005–2016) missions. We find that ML-TOMCAT shows excellent agreement with available independent satellite-based data sets which use pressure as a vertical coordinate (e.g. GOZCARDS, SWOOSH for non-MLS periods) but weaker agreement with the data sets which are altitude-based (e.g. SAGE-CCI-OMPS, SCIAMACHY-OMPS). We find that at almost all stratospheric levels ML-TOMCAT ozone concentrations are well within uncertainties of the observational data sets. The ML-TOMCAT (V1.0) data set is ideally suited for the evaluation of chemical model ozone profiles from the tropopause to 0.1 hPa and is freely available via https://doi.org/10.5281/zenodo.5651194 (Dhomse et al., 2021).

scholarly journals Homogenizing and Estimating the Uncertainty in NOAA’s Long Term Vertical Ozone Profile Records Measured with the Electrochemical Concentration Cell Ozonesonde

2017 ◽  
Author(s):  
Chance W. Sterling ◽  
Bryan J. Johnson ◽  
Samuel J. Oltmans ◽  
Herman G. J. Smit ◽  
Allen F. Jordan ◽  
...  
Keyword(s):  
Concentration Cell ◽  
Data Set ◽  
Total Column Ozone ◽  
Ozone Profile ◽  
Uncertainty Calculation ◽  
Cell Current ◽  
Column Ozone ◽  
The Vertical Distribution ◽  
Vertical Ozone

Abstract. NOAA’s program of long term monitoring of the vertical distribution of ozone with Electrochemical Concentration Cell (ECC) ozonesondes has undergone a number of changes over the 50 year record. In order to produce a homogenous data set, these changes must be documented and where necessary, appropriate corrections applied. This is the first comprehensive and consistent reprocessing of NOAA’s ozonesonde data records that corrects for these changes using the rawest form of the data (cell current and pump temperature) in native resolution as well as a point by point uncertainty calculation that is unique to each sounding. The reprocessing is carried out uniformly at all eight ozonesonde sites in NOAA’s network with differences in sensing solution and ozonesonde types accounted for in the same way at all sites. The corrections used to homogenize the NOAA ozonesonde data records greatly improve the ozonesonde measurements with an average one sigma uncertainty of ±4–6 % in the stratosphere and ±5–20 % in the troposphere. A comparison of the integrated column ozone from the ozonesonde profile with co-located Dobson spectrophotometers total column ozone measurements shows agreement within ±5 % for > 70 % of the profiles. Very good agreement is also found in the stratosphere between ozonesonde profiles and profiles retrieved from the Solar Backscatter Ultraviolet Instruments (SBUV).

scholarly journals GOMOS bright limb ozone data set

2015 ◽  
Vol 8 (8) ◽  
pp. 3107-3115 ◽  
Author(s):  
S. Tukiainen ◽  
E. Kyrölä ◽  
J. Tamminen ◽  
J. Kujanpää ◽  
L. Blanot
Keyword(s):  
Stray Light ◽  
Atmospheric Composition ◽  
Profile Data ◽  
Satellite Measurements ◽  
Data Set ◽  
Infrared Imager ◽  
Ozone Profile ◽  
Stellar Occultation ◽  
Ozone Monitoring ◽  
Better Than

Abstract. We have created a daytime ozone profile data set from the measurements of the Global Ozone Monitoring by Occultation of Stars (GOMOS) instrument on board the Envisat satellite. This so-called GOMOS bright limb (GBL) data set contains ∼ 358 000 stratospheric daytime ozone profiles measured by GOMOS in 2002–2012. The GBL data set complements the widely used GOMOS nighttime data based on stellar occultation measurements. The GBL data set is based on the GOMOS daytime occultations but instead of the transmitted star light we use limb-scattered solar light. The ozone profiles retrieved from these radiance spectra cover the 18–60 km altitude range and have approximately 2–3 km vertical resolution. We show that these profiles are generally in better than 10 % agreement with the NDACC (Network for the Detection of Atmospheric Composition Change) ozonesonde profiles and with the GOMOS nighttime, MLS (Microwave Limb Sounder), and OSIRIS (Optical Spectrograph and InfraRed Imager System) satellite measurements. However, there is a 10–13 % negative bias at 40 km altitude and a 10–50 % positive bias at 50 km for solar zenith angles > 75°. These biases are most likely caused by stray light which is difficult to characterize and to remove entirely from the measured spectra. Nevertheless, the GBL data set approximately doubles the amount of useful GOMOS ozone profiles and improves coverage of the summer pole.

The dynamically driven long-term trend in stratospheric ozone over northern middle latitudes

2002 ◽  
Vol 128 (583) ◽  
pp. 1393-1412 ◽  
Author(s):  
Panos Hadjinicolaou ◽  
Amna Jrrar ◽  
John A. Pyle ◽  
Lane Bishop
Keyword(s):  
Stratospheric Ozone ◽  
Term Trend ◽  
Middle Latitudes ◽  
Long Term Trend

scholarly journals Past changes in the vertical distribution of ozone – Part 1: Measurement techniques, uncertainties and availability

2014 ◽  
Vol 7 (5) ◽  
pp. 1395-1427 ◽  
Author(s):  
B. Hassler ◽  
I. Petropavlovskikh ◽  
J. Staehelin ◽  
T. August ◽  
P. K. Bhartia ◽  
...  
Keyword(s):  
Stratospheric Ozone ◽  
Measurement Techniques ◽  
United Nations Environment Programme ◽  
Critical Examination ◽  
Profile Measurement ◽  
Data Sets ◽  
Data Set ◽  
Ozone Profile ◽  
Measurement Uncertainties

Abstract. Peak stratospheric chlorofluorocarbon (CFC) and other ozone depleting substance (ODS) concentrations were reached in the mid- to late 1990s. Detection and attribution of the expected recovery of the stratospheric ozone layer in an atmosphere with reduced ODSs as well as efforts to understand the evolution of stratospheric ozone in the presence of increasing greenhouse gases are key current research topics. These require a critical examination of the ozone changes with an accurate knowledge of the spatial (geographical and vertical) and temporal ozone response. For such an examination, it is vital that the quality of the measurements used be as high as possible and measurement uncertainties well quantified. In preparation for the 2014 United Nations Environment Programme (UNEP)/World Meteorological Organization (WMO) Scientific Assessment of Ozone Depletion, the SPARC/IO3C/IGACO-O3/NDACC (SI2N) Initiative was designed to study and document changes in the global ozone profile distribution. This requires assessing long-term ozone profile data sets in regards to measurement stability and uncertainty characteristics. The ultimate goal is to establish suitability for estimating long-term ozone trends to contribute to ozone recovery studies. Some of the data sets have been improved as part of this initiative with updated versions now available. This summary presents an overview of stratospheric ozone profile measurement data sets (ground and satellite based) available for ozone recovery studies. Here we document measurement techniques, spatial and temporal coverage, vertical resolution, native units and measurement uncertainties. In addition, the latest data versions are briefly described (including data version updates as well as detailing multiple retrievals when available for a given satellite instrument). Archive location information for each data set is also given.

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