Chromium Distribution, Leachability and Speciation in a Chrome Plating Site

Hexavalent chromium (Cr(VI)) waste produced by chrome plating activities pollutes the surrounding environment and harms human health. However, information about the chromium (Cr) pollution characteristics of actual electroplating sites is still lacking. In this study, the concentration, leachability and speciation of Cr in soils from a typical chrome plating site were analyzed. Our results showed that this site was severely contaminated by Cr (7.2 to 7735.2 mg/kg) and Cr(VI) reached the mean concentration of 138.7 mg/kg. The spatial distribution of Cr(VI) was related to the plating processes. Chrome plating and sewage treatment areas could be considered as the hot spots of contaminated sites. The vertical distribution of Cr(VI) was mainly affected by soil properties, where the loam layer retained and reduced a large amount of Cr(VI) due to its high content of iron minerals and finer particle fractions. Additionally, the chemical extraction results showed that Cr was mainly in non-residual fractions and the existence of Cr(VI) led to a high leaching toxicity based on the toxicity characteristic leaching procedure (TCLP) results. Moreover, X-ray photoelectron spectroscopy (XPS) results revealed the speciation of Cr in the long-term contaminated soils. A large amount of Cr(VI) was reduced into Cr(III) and mainly existed as Cr(OH)3 and Cr2O3. Furthermore, Cr(VI) tended to precipitate as CaCrO4 and persisted in soils. Therefore, it is necessary to find appropriate strategies to remediate these contaminated soils. Overall, these findings strengthen our understanding of Cr(VI) behaviors and lay a foundation for the future pollution investigation, ecological remediation and risk assessment of sites contaminated by electroplating.

Population attributes of Littoraria angulifera (Gastropoda: Littorinidae) in mangroves in Bahia State, northeastern Brazil

Littoraria angulifera (Lamarck, 1822) is an estuarine gastropod of tropical occurrence, which lives mainly on trunks of mangrove tree species. This study aimed to evaluate the population attributes of this species, such as abundance, space-time distribution, sex ratio and recruitment in mangroves in Bahia State, northeastern Brazil. The specimens were collected monthly throughout 2018, on trunks of the red mangrove Rhizophora mangle L. at two heights and on two horizontal levels. Specimens that were on the marine grass Spartina alterniflora Loisel were also collected. After counting, biometrics and sexing, the specimens were returned alive to the environment. The average size and weight of L. angulifera was higher (p<0.05) in places with taller and less sparse trees and the vertical distribution on the trunks showed a preference for strata close to the soil. Both results are related to shading and protection against desiccation. Females were more abundant than males, at an approximate sex ratio F: M of 1.4: 1. Recruits were observed throughout the period, showing continuous reproduction of the species with a recruitment peak in spring (September to November). The study revealed the importance of keep the mangroves intact to allow the maintenance of the natural stocks of the species.

Association Between Early-Stage Juveniles of Sailfin Catfish (Pterygoplichthys, Loricariidae) and Floating Hydrophytes: Behaviour Supports Species Dispersal?

The vertical distribution of early-stage juvenile sailfin catfish (Pterygoplichthys, Loricariidae), an invasive species, were investigated in littoral habitats and the center of channel with floating hydrophytes from the Red River system in Vietnam. Sailfin catfish were sampled from the upper water column with associated floating hydrophytes of the invasive water hyacinth (Eichhornia crassipes) and native water spinach (Ipomoea aquatic) and the bottom using hand nets (2-mm mesh sizes). Significantly higher numbers of early-stage juveniles were associated with floating hydrophytes compared to bottom sampling. The association between early stages of sailfin catfishes and floating hydrophytes, especially the free-floating invasive water hyacinth, supports the potential mechanism in the dispersal of an invasive fish.

Seasonal variation in the vertical distribution of zone over Oakshin Gangotri, Antarctica

Ozone soundings made from Dakshin Gangotri, Antarctica during 1987 are presented. The vertical distribution of ozone over Antarctica is characterised by a double peak profile, one around 200-150 hPa and the other around 50 hPa. During late winter-early spring the upper peak is considerably depleted. Tropospheric ozoe remains low and nearly constant throughout the year.

UAVC: A New Method for Correcting Lidar Overlap Factors Based on Unmanned Aerial Vehicle Vertical Detection

A method to calibrate the overlap factor of Lidar is proposed, named unmanned aerial vehicle correction (UAVC), which uses unmanned aerial vehicles (UAVs) to detect the vertical distribution of particle concentrations. The conversion relationship between the particulate matter concentration and the aerosol extinction coefficient is inverted by the high-altitude coincidence of the vertical detection profiles of the UAV and Lidar. Using this conversion relationship, the Lidar signal without the influence of the overlap factor can be inverted. Then, the overlap factor profile is obtained by comparing the signal with the original Lidar signal. A 355 nm Raman-Mie Lidar and UAV were used to measure overlap factors under different weather conditions. After comparison with the Raman method, it is found that the overlap factors calculated by the two methods are in good agreement. The changing trend of the extinction coefficient at each height is relatively consistent, after comparing the inversion result of the corrected Lidar signal with the ground data. The results show that after the continuously measured Lidar signal is corrected by the overlap factor measured by this method, low-altitude aerosol information can be effectively obtained.

Vertical differentiation of pedogenic iron forms – a key of hydromorphic soil profile development

This paper focuses on the vertical distribution and characterisation of pedogenic iron forms in a Gleysol- Histosol transect developed in a marshy area in the Danube-Tisza Interfluve, Hungary. Four soil profiles were investigated along a series of increasing waterlogging and spatial and temporal patterns of hydromorphic pedofeatures (characteristics of pedogenic iron forms) were recorded. Frequent and wide-range redox potential (Eh) changes caused the emergence of many types of redoximorphic iron features, including mottles, plaques and nodules. The forms of these features depended on the micro-environments determined by the vertical position in the soil profile and the presence of plant roots. The greatest iron enrichment occurred in the zone of most intensive and widest-range redox fluctuations. Increasing water saturation resulted the extension of gleyic pattern due to the existence of permanent reduction. Most of the features also showed annual variations during the varying periods of water saturation and aeration.