scholarly journals Aromatic acids in a Eurasian Arctic ice core: a 2600-year proxy record of biomass burning

2017 ◽  
Vol 13 (4) ◽  
pp. 395-410 ◽  
Author(s):  
Mackenzie M. Grieman ◽  
Murat Aydin ◽  
Diedrich Fritzsche ◽  
Joseph R. McConnell ◽  
Thomas Opel ◽  
...  
Keyword(s):  
Detection Limit ◽  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Large Scale ◽  
Ice Core ◽  
Ice Cores ◽  
Aromatic Acid ◽  
Aromatic Acids ◽  
The North

Abstract. Wildfires and their emissions have significant impacts on ecosystems, climate, atmospheric chemistry, and carbon cycling. Well-dated proxy records are needed to study the long-term climatic controls on biomass burning and the associated climate feedbacks. There is a particular lack of information about long-term biomass burning variations in Siberia, the largest forested area in the Northern Hemisphere. In this study we report analyses of aromatic acids (vanillic and para-hydroxybenzoic acids) over the past 2600 years in the Eurasian Arctic Akademii Nauk ice core. These compounds are aerosol-borne, semi-volatile organic compounds derived from lignin combustion. The analyses were made using ion chromatography with electrospray mass spectrometric detection. The levels of these aromatic acids ranged from below the detection limit (0.01 to 0.05 ppb; 1 ppb  =  1000 ng L−1) to about 1 ppb, with roughly 30 % of the samples above the detection limit. In the preindustrial late Holocene, highly elevated aromatic acid levels are observed during three distinct periods (650–300 BCE, 340–660 CE, and 1460–1660 CE). The timing of the two most recent periods coincides with the episodic pulsing of ice-rafted debris in the North Atlantic known as Bond events and a weakened Asian monsoon, suggesting a link between fires and large-scale climate variability on millennial timescales. Aromatic acid levels also are elevated during the onset of the industrial period from 1780 to 1860 CE, but with a different ratio of vanillic and para-hydroxybenzoic acid than is observed during the preindustrial period. This study provides the first millennial-scale record of aromatic acids. This study clearly demonstrates that coherent aromatic acid signals are recorded in polar ice cores that can be used as proxies for past trends in biomass burning.

scholarly journals Aromatic acids in a Eurasian Arctic ice core: a 3000-year proxy record of biomass burning

2016 ◽  
Author(s):  
Mackenzie M. Grieman ◽  
Murat Aydin ◽  
Diedrich Fritzsche ◽  
Joseph R. McConnell ◽  
Thomas Opel ◽  
...  
Keyword(s):  
Detection Limit ◽  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Ice Core ◽  
Ice Cores ◽  
Aromatic Acid ◽  
Aromatic Acids ◽  
The North ◽  
Lack Of Information

Abstract. Wildfires and their emissions have significant impacts on ecosystems, climate, atmospheric chemistry and carbon cycling. Well-dated proxy records are needed to study the long-term climatic controls on biomass burning and the associated climate feedbacks. There is a particular lack of information about long-term biomass burning variations in Siberia, the largest forested area in the Northern Hemisphere. In this study we report analyses of aromatic acids (vanillic and para-hydroxybenzoic acids) over the past 3145 years in the Eurasian Arctic Akademii Nauk ice core. These compounds are aerosol-borne, semi-volatile organic compounds derived from lignin combustion. The analyses were made using ion chromatography with electrospray mass spectrometric detection. The levels of these aromatic acids ranged from below the detection limit (.01 to .05 ppb) to about 1 ppb, with roughly 30 % of the samples above the detection limit. In the preindustrial late Holocene, highly elevated aromatic acid levels are observed during four distinct periods (1180–660 BCE, 180–220 CE, 380–660 CE, and 1460–1660 CE). The timing of these periods coincides with the episodic pulsing of ice-rafted debris in the North Atlantic known as Bond events. Aromatic acid levels also are elevated during the onset of the industrial period from 1780 to 1860 CE, but with a different ratio of vanillic and para-hydroxybenzoic acid than is observed during the preindustrial period. This study provides the first millennial scale record of aromatic acids. It clearly demonstrates that coherent aromatic acid signals are recorded in polar ice cores that can be used as proxies for past trends in biomass burning.

scholarly journals Precipitation record since AD 1600 from ice cores on the central Tibetan Plateau

2008 ◽  
Vol 4 (3) ◽  
pp. 175-180 ◽  
Author(s):  
T. Yao ◽  
K. Duan ◽  
B. Xu ◽  
N. Wang ◽  
X. Guo ◽  
...  
Keyword(s):  
Tibetan Plateau ◽  
Ice Core ◽  
Ice Cores ◽  
The North ◽  
Northern Tibetan Plateau ◽  
Central Tibetan Plateau ◽  
Precipitation Record ◽  
Ice Field ◽  
The 19Th Century

Abstract. Lack of reliable long-term precipitation record from the northern Tibetan Plateau has constrained our understanding of precipitation variations in this region. We drilled an ice core on the Puruogangri Ice Field in the central Tibetan Plateau in 2000 to reveal the precipitation variations. The well dated part of the core extends back to AD 1600, allowing us to construct a 400-year annual accumulation record. This record shows that the central Tibetan plateau experienced a drier period with an average annual precipitation of ~300 mm in the 19th century, compared to ~450 mm in the wetter periods during 1700–1780 and the 20th century. This pattern agrees with precipitation reconstructions from the Dunde and Guliya ice cores on the northern Plateau but differs from that found in the Dasuopu ice cores from the southern Plateau The north-south contrasts in precipitation reconstruction reveals difference in moisture origin between the south Tibetan Plateau dominated by the Asian monsoon and the north Tibetan Plateau dominated by the continental recycling and the westerlies.

scholarly journals An 800 year high-resolution black carbon ice-core record from Lomonosovfonna, Svalbard

2018 ◽  
Author(s):  
Dimitri Osmont ◽  
Isabel A. Wendl ◽  
Loïc Schmidely ◽  
Michael Sigl ◽  
Carmen P. Vega ◽  
...  
Keyword(s):  
High Resolution ◽  
Black Carbon ◽  
20Th Century ◽  
Biomass Burning ◽  
Ice Core ◽  
Ice Cores ◽  
The Arctic ◽  
Snow Albedo ◽  
Decadal Scale

Abstract. Produced by the incomplete combustion of fossil fuel and biomass, black carbon (BC) contributes to Arctic warming by reducing snow albedo and thus triggering a snow-albedo feedback leading to increased snow melting. Therefore, it is of high importance to assess past BC emissions to better understand and constrain their role. However, only few long-term BC records are available from the Arctic, mainly originating from Greenland ice cores. Here, we present the first long-term and high-resolution refractory black carbon (rBC) record from Svalbard, derived from the analysis of two ice cores drilled at the Lomonosovfonna ice field in 2009 (LF-09) and 2011 (LF-11) and covering 800 years of atmospheric emissions. Our results show that rBC concentrations strongly increased from 1860 on due to anthropogenic emissions and reached two maxima, at the end of the 19th century and in the middle of the 20th century. No increase in rBC concentrations during the last decades was observed, which is corroborated by atmospheric measurements elsewhere in the Arctic but contradicts a previous study from another ice core from Svalbard. While melting may affect BC concentrations during periods of high temperatures, rBC concentrations remain well-preserved prior to the 20th century due to lower temperatures inducing little melt. Therefore, the preindustrial rBC record (before 1800), along with ammonium (NH4+), formate (HCOO−) and specific organic markers (vanillic acid (VA) and p-hydroxybenzoic acid (p-HBA)), was used as a proxy for biomass burning. Despite numerous single events, no long-term trend was observed over the time period 1222–1800 for rBC and NH4+. In contrast, formate, VA and p-HBA experience multi-decadal peaks reflecting periods of enhanced biomass burning. Most of the background variations and single peak events are corroborated by other ice-core records from Greenland and Siberia. We suggest that the paleofire record from the LF ice core primarily reflects biomass burning episodes from Northern Eurasia, induced by decadal-scale climatic variations.

scholarly journals Large changes in biomass burning over the last millennium inferred from paleoatmospheric ethane in polar ice cores

2018 ◽  
Vol 115 (49) ◽  
pp. 12413-12418 ◽  
Author(s):  
Melinda R. Nicewonger ◽  
Murat Aydin ◽  
Michael J. Prather ◽  
Eric S. Saltzman
Keyword(s):  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Little Ice Age ◽  
Ice Core ◽  
Stable Carbon Isotope ◽  
Ice Cores ◽  
Ice Age ◽  
Climate Forcing ◽  
Medieval Period ◽  
Highly Sensitive

Biomass burning drives changes in greenhouse gases, climate-forcing aerosols, and global atmospheric chemistry. There is controversy about the magnitude and timing of changes in biomass burning emissions on millennial time scales from preindustrial to present and about the relative importance of climate change and human activities as the underlying cause. Biomass burning is one of two notable sources of ethane in the preindustrial atmosphere. Here, we present ice core ethane measurements from Antarctica and Greenland that contain information about changes in biomass burning emissions since 1000 CE (Common Era). The biomass burning emissions of ethane during the Medieval Period (1000–1500 CE) were higher than present day and declined sharply to a minimum during the cooler Little Ice Age (1600–1800 CE). Assuming that preindustrial atmospheric reactivity and transport were the same as in the modern atmosphere, we estimate that biomass burning emissions decreased by 30 to 45% from the Medieval Period to the Little Ice Age. The timing and magnitude of this decline in biomass burning emissions is consistent with that inferred from ice core methane stable carbon isotope ratios but inconsistent with histories based on sedimentary charcoal and ice core carbon monoxide measurements. This study demonstrates that biomass burning emissions have exceeded modern levels in the past and may be highly sensitive to changes in climate.

scholarly journals Effects of the 2006 El Niño on tropospheric ozone and carbon monoxide: implications for dynamics and biomass burning

2009 ◽  
Vol 9 (13) ◽  
pp. 4239-4249 ◽  
Author(s):  
S. Chandra ◽  
J. R. Ziemke ◽  
B. N. Duncan ◽  
T. L. Diehl ◽  
N. J. Livesey ◽  
...  
Keyword(s):  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Forest Fires ◽  
El Niño ◽  
Tropospheric Ozone ◽  
Large Scale ◽  
El Nino ◽  
Global Burden ◽  
The North ◽  
Tropospheric O3

Abstract. We have studied the effects of the 2006 El Niño on tropospheric O3 and CO at tropical and sub-tropical latitudes measured from the OMI and MLS instruments on the Aura satellite. The 2006 El Niño-induced drought caused forest fires (largely set to clear land) to burn out of control during October and November in the Indonesian region. The effects of these fires are clearly seen in the enhancement of CO concentration measured from the MLS instrument. We have used a global model of atmospheric chemistry and transport (GMI CTM) to quantify the relative importance of biomass burning and large scale transport in producing observed changes in tropospheric O3 and CO. The model results show that during October and November biomass burning and meteorological changes contributed almost equally to the observed increase in tropospheric O3 in the Indonesian region. The biomass component was 4–6 DU but it was limited to the Indonesian region where the fires were most intense. The dynamical component was 4–8 DU but it covered a much larger area in the Indian Ocean extending from South East Asia in the north to western Australia in the south. By December 2006, the effect of biomass burning was reduced to zero and the observed changes in tropospheric O3 were mostly due to dynamical effects. The model results show an increase of 2–3% in the global burden of tropospheric ozone. In comparison, the global burden of CO increased by 8–12%.

scholarly journals Effects of the 2006 El Niño on tropospheric ozone and carbon monoxide: implications for dynamics and biomass burning

2009 ◽  
Vol 9 (1) ◽  
pp. 2735-2761
Author(s):  
S. Chandra ◽  
J. R. Ziemke ◽  
B. N. Duncan ◽  
T. L. Diehl ◽  
N. J. Livesey ◽  
...  
Keyword(s):  
Biomass Burning ◽  
Atmospheric Chemistry ◽  
Forest Fires ◽  
El Niño ◽  
Tropospheric Ozone ◽  
Large Scale ◽  
El Nino ◽  
Global Burden ◽  
The North ◽  
Tropospheric O3

Abstract. We have studied the effects of the 2006 El Niño on tropospheric O3 and CO at tropical and sub-tropical latitudes measured from the OMI and MLS instruments on the Aura satellite. The 2006 El Niño-induced drought allowed forest fires set to clear land to burn out of control during October and November in the Indonesian region. The effects of these fires are clearly seen in the enhancement of CO concentration measured from the MLS instrument. We have used a global model of atmospheric chemistry and transport (GMI CTM) to quantify the relative importance of biomass burning and large scale transport in producing observed changes in tropospheric O3 and CO. The model results show that during October and November both biomass burning and meteorological changes contributed almost equally to the observed increase in tropospheric O3 in the Indonesian region. The biomass component was 4–6 DU but it was limited to the Indonesian region where the fires were most intense. The dynamical component was 4–8 DU but it covered a much larger area in the Indian Ocean extending from South East Asia in the north to western Australia in the south. By December 2006, the effect of biomass burning was reduced to zero and the observed changes in tropospheric O3 were mostly due to dynamical effects. The model results show an increase of 2–3% in the global burden of tropospheric ozone. In comparison, the global burden of CO increased by 8–12%.

scholarly journals An 800-year high-resolution black carbon ice core record from Lomonosovfonna, Svalbard

2018 ◽  
Vol 18 (17) ◽  
pp. 12777-12795 ◽  
Author(s):  
Dimitri Osmont ◽  
Isabel A. Wendl ◽  
Loïc Schmidely ◽  
Michael Sigl ◽  
Carmen P. Vega ◽  
...  
Keyword(s):  
High Resolution ◽  
Black Carbon ◽  
20Th Century ◽  
Biomass Burning ◽  
Ice Core ◽  
Ice Cores ◽  
The Arctic ◽  
Snow Albedo ◽  
Decadal Scale

Abstract. Produced by the incomplete combustion of fossil fuel and biomass, black carbon (BC) contributes to Arctic warming by reducing snow albedo and thus triggering a snow-albedo feedback leading to increased snowmelt. Therefore, it is of high importance to assess past BC emissions to better understand and constrain their role. However, only a few long-term BC records are available from the Arctic, mainly originating from Greenland ice cores. Here, we present the first long-term and high-resolution refractory black carbon (rBC) record from Svalbard, derived from the analysis of two ice cores drilled at the Lomonosovfonna ice field in 2009 (LF-09) and 2011 (LF-11) and covering 800 years of atmospheric emissions. Our results show that rBC concentrations strongly increased from 1860 on due to anthropogenic emissions and reached two maxima, at the end of the 19th century and in the middle of the 20th century. No increase in rBC concentrations during the last decades was observed, which is corroborated by atmospheric measurements elsewhere in the Arctic but contradicts a previous study from another ice core from Svalbard. While melting may affect BC concentrations during periods of high temperatures, rBC concentrations remain well preserved prior to the 20th century due to lower temperatures inducing little melt. Therefore, the preindustrial rBC record (before 1800), along with ammonium (NH4+), formate (HCOO−) and specific organic markers (vanillic acid, VA, and p-hydroxybenzoic acid, p-HBA), was used as a proxy for biomass burning. Despite numerous single events, no long-term trend was observed over the time period 1222–1800 for rBC and NH4+. In contrast, formate, VA, and p-HBA experience multi-decadal peaks reflecting periods of enhanced biomass burning. Most of the background variations and single peak events are corroborated by other ice core records from Greenland and Siberia. We suggest that the paleofire record from the LF ice core primarily reflects biomass burning episodes from northern Eurasia, induced by decadal-scale climatic variations.

scholarly journals Aromatic acids in an Arctic ice core from Svalbard: a proxy record of biomass burning

2018 ◽  
Vol 14 (5) ◽  
pp. 637-651 ◽  
Author(s):  
Mackenzie M. Grieman ◽  
Murat Aydin ◽  
Elisabeth Isaksson ◽  
Margit Schwikowski ◽  
Eric S. Saltzman
Keyword(s):  
North Atlantic ◽  
Vanillic Acid ◽  
Ice Core ◽  
Ice Cores ◽  
Hydroxybenzoic Acid ◽  
Aromatic Acids ◽  
Back Trajectories ◽  
The North ◽  
Negative State ◽  
Arctic Ice

Abstract. This study presents vanillic acid and para-hydroxybenzoic acid levels in an Arctic ice core from Lomonosovfonna, Svalbard covering the past 800 years. These aromatic acids are likely derived from lignin combustion in wildfires and long-range aerosol transport. Vanillic and para-hydroxybenzoic acid are present throughout the ice core, confirming that these compounds are preserved on millennial timescales. Vanillic and para-hydroxybenzoic acid concentrations in the Lomonosovfonna ice core ranged from below the limits of detection to 0.2 and 0.07 ppb, respectively (1 ppb  =  1000 ng L−1). Vanillic acid levels are high (maximum of 0.1 ppb) from 1200 to 1400 CE, then gradually decline into the twentieth century. The largest peak in the vanillic acid in the record occurs from 2000 to 2008 CE. In the para-hydrobenzoic acid record, there are three centennial-scale peaks around 1300, 1550, and 1650 CE superimposed on a long-term decline in the baseline levels throughout the record. Ten-day air mass back trajectories for a decade of fire seasons (March–November, 2006–2015) indicate that Siberia and Europe are the principle modern source regions for wildfire emissions reaching the Lomonosovfonna site. The Lomonosovfonna data are similar to those from the Eurasian Arctic Akademii Nauk ice core during the early part of the record (1220–1400 CE), but the two ice cores diverge markedly after 1400 CE. This coincides with a shift in North Atlantic climate marked by a change of the North Atlantic Oscillation from a positive to a more negative state.

scholarly journals A Synoptic Scale Perspective on Greenland Ice Core δ18O Variability and Related Teleconnection Patterns

Atmosphere ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 294
Author(s):  
Norel Rimbu ◽  
Monica Ionita ◽  
Gerrit Lohmann
Keyword(s):  
Ice Core ◽  
Ice Cores ◽  
Synoptic Scale ◽  
Local Climate ◽  
Rossby Wave Breaking ◽  
Weather Patterns ◽  
Teleconnection Patterns ◽  
Climate Anomalies ◽  
The North ◽  
Oxygen Isotope Ratios

The variability of stable oxygen isotope ratios (δ18O) from Greenland ice cores is commonly linked to changes in local climate and associated teleconnection patterns. In this respect, in this study we investigate ice core δ18O variability from a synoptic scale perspective to assess the potential of such records as proxies for extreme climate variability and associated weather patterns. We show that positive (negative) δ18O anomalies in three southern and central Greenland ice cores are associated with relatively high (low) Rossby Wave Breaking (RWB) activity in the North Atlantic region. Both cyclonic and anticyclonic RWB patterns associated with high δ18O show filaments of strong moisture transport from the Atlantic Ocean towards Greenland. During such events, warm and wet conditions are recorded over southern, western and central part of Greenland. In the same time the cyclonic and anticyclonic RWB patterns show enhanced southward advection of cold polar air masses on their eastern side, leading to extreme cold conditions over Europe. The association between high δ18O winters in Greenland ice cores and extremely cold winters over Europe is partly explained by the modulation of the RWB frequency by the tropical Atlantic sea surface temperature forcing, as shown in recent modeling studies. We argue that δ18O from Greenland ice cores can be used as a proxy for RWB activity in the Atlantic European region and associated extreme weather and climate anomalies.

scholarly journals Impact of precipitation intermittency on NAO-temperature signals in proxy records

2013 ◽  
Vol 9 (2) ◽  
pp. 871-886 ◽  
Author(s):  
M. Casado ◽  
P. Ortega ◽  
V. Masson-Delmotte ◽  
C. Risi ◽  
D. Swingedouw ◽  
...  
Keyword(s):  
General Circulation ◽  
Ice Core ◽  
Circulation Model ◽  
Ice Cores ◽  
Stable Isotope Ratio ◽  
Global Network ◽  
Temporal Correlations ◽  
The North ◽  
The North Atlantic Oscillation ◽  
The Impact

Abstract. In mid and high latitudes, the stable isotope ratio in precipitation is driven by changes in temperature, which control atmospheric distillation. This relationship forms the basis for many continental paleoclimatic reconstructions using direct (e.g. ice cores) or indirect (e.g. tree ring cellulose, speleothem calcite) archives of past precipitation. However, the archiving process is inherently biased by intermittency of precipitation. Here, we use two sets of atmospheric reanalyses (NCEP (National Centers for Environmental Prediction) and ERA-interim) to quantify this precipitation intermittency bias, by comparing seasonal (winter and summer) temperatures estimated with and without precipitation weighting. We show that this bias reaches up to 10 °C and has large interannual variability. We then assess the impact of precipitation intermittency on the strength and stability of temporal correlations between seasonal temperatures and the North Atlantic Oscillation (NAO). Precipitation weighting reduces the correlation between winter NAO and temperature in some areas (e.g. Québec, South-East USA, East Greenland, East Siberia, Mediterranean sector) but does not alter the main patterns of correlation. The correlations between NAO, δ18O in precipitation, temperature and precipitation weighted temperature are investigated using outputs of an atmospheric general circulation model enabled with stable isotopes and nudged using reanalyses (LMDZiso (Laboratoire de Météorologie Dynamique Zoom)). In winter, LMDZiso shows similar correlation values between the NAO and both the precipitation weighted temperature and δ18O in precipitation, thus suggesting limited impacts of moisture origin. Correlations of comparable magnitude are obtained for the available observational evidence (GNIP (Global Network of Isotopes in Precipitation) and Greenland ice core data). Our findings support the use of archives of past δ18O for NAO reconstructions.

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