scholarly journals Natural organic matter removal by ion exchange at different positions in the drinking water treatment lane

2013 ◽  
Vol 6 (1) ◽  
pp. 1-10 ◽  
Author(s):  
A. Grefte ◽  
M. Dignum ◽  
E. R. Cornelissen ◽  
L. C. Rietveld

Abstract. To guarantee a good water quality at the customers tap, natural organic matter (NOM) should be (partly) removed during drinking water treatment. The objective of this research was to improve the biological stability of the produced water by incorporating anion exchange (IEX) for NOM removal. Different placement positions of IEX in the treatment lane (IEX positioned before coagulation, before ozonation or after slow sand filtration) and two IEX configurations (MIEX® and fluidized IEX (FIX)) were compared on water quality as well as costs. For this purpose the pre-treatment plant at Loenderveen and production plant Weesperkarspel of Waternet were used as a case study. Both, MIEX® and FIX were able to remove NOM (mainly the HS fraction) to a high extent. NOM removal can be done efficiently before ozonation and after slow sand filtration. The biological stability, in terms of assimilable organic carbon, biofilm formation rate and dissolved organic carbon, was improved by incorporating IEX for NOM removal. The operational costs were assumed to be directly dependent of the NOM removal rate and determined the difference between the IEX positions. The total costs for IEX for the three positions were approximately equal (0.0631 € m−3), however the savings on following treatment processes caused a cost reduction for the IEX positions before coagulation and before ozonation compared to IEX positioned after slow sand filtration. IEX positioned before ozonation was most cost effective and improved the biological stability of the treated water.

2012 ◽  
Vol 5 (1) ◽  
pp. 375-401
Author(s):  
A. Grefte ◽  
M. Dignum ◽  
E. R. Cornelissen ◽  
L. C. Rietveld

Abstract. To guarantee a good water quality at the customers tap, natural organic matter (NOM) should be (partly) removed during drinking water treatment. The objective of this research was to improve the drinking water quality, including biological stability, by incorporating anion exchange (IEX) for NOM removal. Different placement positions of IEX in the treatment lane (IEX positioned before coagulation, before ozonation or after slow sand filtration) are compared on water quality as well as costs. For this purpose the pre-treatment plant at Loenderveen and production plant Weesperkarspel of Waternet were used as a case study. NOM removal can be done efficiently before ozonation and after slow sand filtration; it was found that the position in the treatment lane did not influence the NOM removal capacity. The operational costs were assumed to be directly dependent of the NOM removal rate and determined the difference between the IEX positions. The operational costs for IEX positioned before coagulation were higher than for IEX positioned after slow sand filtration, however the savings on following treatment processes caused a cost reduction compared to IEX positioned after slow sand filtration. IEX positioned before coagulation or ozonation were most cost effective and produced the highest water quality.


Author(s):  
Huai-Ji Wang ◽  
Yan Wang ◽  
Xue Han ◽  
Jie Zhang ◽  
Jun-Ling Liu ◽  
...  

Dissolved organic matter (DOM) has detrimental effects on drinking water treatment, distribution water quality and human health. In this study, four methods (dissolved organic carbon (DOC), potassium permanganate index (CODMn),...


2020 ◽  
Vol 20 (6) ◽  
pp. 2106-2118
Author(s):  
Kassim Chabi ◽  
Jie Zeng ◽  
Lizheng Guo ◽  
Xi Li ◽  
Chengsong Ye ◽  
...  

Abstract People in remote areas are still drinking surface water that may contain certain pollutants including harmful microorganisms and chemical compounds directly without any pretreatment. In this study, we have designed and operated a pilot-scale drinking water treatment unit as part of our aim to find an economic and easily operable technology for providing drinking water to people in those areas. Our small-scale treatment unit contains filtration and disinfection (UV–C irradiation) stages to remove pollutants from source water. The water quality index was determined based on various parameters such as pH, temperature, dissolved oxygen, nitrate, nitrite, ammonium, phosphorus, dissolved organic carbon and bacteria. Water and media samples after DNA extraction were sequenced using Illumina MiSeq throughput sequencing for the determination of bacterial community composition. After the raw water treatment, the reduction of bacteria concentration ranged from 1 to 2 log10. The average removal of the turbidity, ammonium, nitrite, phosphorus and dissolved organic carbon reached up to 95.33%, 85.71%, 100%, 28.57%, and 45%, respectively. In conclusion, multiple biological stages in our designed unit showed an improvement of the drinking water quality. The designed drinking treatment unit produces potable water meeting standards at a lower cost of operation and it can be used in remote areas.


2005 ◽  
Vol 9 (1) ◽  
pp. 3-16 ◽  
Author(s):  
J. Z. Wang ◽  
R. S. Summers

Natural organic matter (NOM) in drinking water is a complex mixture of organic compounds. Some of the compounds are not biodegradable, while others are quickly biodegradable and a third group is more resistant to biodegradation. To have a better understanding of the biofiltration process in drinking water treatment, it is important to identify the elements of the quickly and slowly biodegradable NOM and to characterize the biodegradation rate of each element. In this study, an ozonated NOM solution was used as the substrate. The NOM was isolated from a groundwater in Germany using ion-exchange resins. The ozone dose was 0.35 mg O3/mg DOC (dissolved organic carbon). Previously bioacclimated sand was used as filter media and biomass source and was homogeneously distributed in the filter prior to each run. The substrate removal was evaluated by DOC, biodegradable DOC (BDOC), assimilable organic carbon (AOC), aldehyde and ketoacid analyses. When expressed in terms of the empty bed contact time (EBCT), the results showed that filter velocity in the range of 1.5 to 15 m/hr had no impact on substrate removal. This implies that substrate utilization, not external mass transfer, is the rate limiting step for substrate removal in drinking water biofilters. In this study, compounds or NOM fractions are termed quickly biodegradable if they are removed in the first three minutes of EBCT. 15% of the DOC was removed by the biofilter within three minutes of EBCT and was termed the quickly biodegradable fraction. The BDOC fraction of the ozonated solution was determined to be 40 to 45% of the DOC. In terms of BDOC, about one third of the total BDOC was quickly biodegradable. The AOC results show that about 90% of the total AOC was utilized by Spirillum sp. NOX (AOC-NOX). Most of the AOC was quickly biodegradable and was removed within one minute of EBCT. For aldehydes, glyoxal and methyl glyoxal were removed to below the detection limit after two minutes of EBCT. However, only 60% of formaldehyde removal was achieved in the first two minutes of EBCT, and no additional removal was achieved with increasing EBCT. Additionally, no significant removal of acetaldehyde was observed. The results of ketoacids show that their utilization rates were very high. More than 90% of glyoxylic acid and pyruvic acid were removed within one minute of EBCT.


2011 ◽  
Vol 11 (6) ◽  
pp. 668-674 ◽  
Author(s):  
B. Q. Zhao ◽  
C. P. Huang ◽  
S. Y. Chen ◽  
D. S. Wang ◽  
T. Li ◽  
...  

Natural organic matter (NOM) plays a significant role in the fouling of ultrafiltration membranes in drinking water treatment processes. For a better understanding of the interaction between fractional components of NOM and polysulfone (PS) ultrafiltration membranes used for drinking water treatment, fouling and especially the physically irreversible fouling of natural organic matter were investigated. Resin fractionation, fluorescence excitation–emission matrix (EEM) spectroscopy, fourier transform infrared spectroscopy (FTIR), contact angle and a scanning electron microscope (SEM) were employed to identify the potential foulants. The results showed that humic acid and fulvic acid of small size were likely to permeate the membrane, while the hydrophobic fraction of humic and fulvic acid and aromatic proteins tended to be rejected and retained. Organic compounds such as proteins, humic substances, and polysaccharide-like materials, were all detected in the fouling layer. The physically irreversible fouling of the PS membrane seemed to be mainly attributed to the hydrophobic fraction of humic substances.


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