Reaction-induced strain localisation in garnet pyroxenites during mantle corner flow: an example from the Ulten Zone (Eastern Alps, N Italy)

Author(s):  
Stefano Zanchetta ◽  
Luca Menegon ◽  
Luca Pellegrino ◽  
Simone Tumiati ◽  
Nadia Malaspina

<p>In the Ulten Zone (Tonale nappe, Eastern Alps, N Italy), numerous peridotite bodies occur within high-grade crustal rocks. Peridotites show a transition from coarse protogranular spinel-lherzolites to fine-grained mylonitic garnet-amphibole peridotites (Obata and Morten, 1987). Pyroxenites veins and dikes, transposed along the peridotite foliation, show a similar evolution from coarse garnet-free websterites to fine-grained garnet + amphibole clinopyroxenites (Morten and Obata, 1983). This evolution has been interpreted to reflect cooling and pressure increase of pyroxenites and host peridotites from spinel- (1200 °C, 1.3-1.6 GPa) to garnet-facies conditions (850 °C and 2.8 GPa) within the mantle corner flow (Nimis and Morten, 2000).</p><p>The newly formed garnet occurs as exsolution within porphyroclastic, high-T pyroxenes, and crystallises along the pyroxenite and peridotite foliation.</p><p>Textural evidence and crystallographic orientation data indicate that the transition from spinel- to garnet-facies conditions was assisted by intense shearing and deformation. Pyroxene porphyroclasts in garnet clinopyroxenites show well-developed crystallographic preferred orientation (CPO), high frequency of low-angle misorientations, and non-random distribution of the low-angle misorientation axes. These features indicates that pyroxene porphyroclasts primarily deform by dislocation creep on the (100) [010] slip system. Dislocation creep is accompanied by subgrain rotation recrystallisation, which promotes the formation of new, smaller and equant pyroxene grains around porphyroclasts. The grain size reduction promotes a switch in the deformation mechanism from grain-size insensitive creep (i.e. dislocation creep) in the porphyroclasts to grain-size sensitive (GSS) creep in the small recrystallised grains. The switch from dislocation to GSS creep is accompanied not only by grain size reduction of pyroxenes, but also by the formation of garnet exsolutions in pyroxenes and garnet crystallisation along foliation. We suggest that garnet crystallisation triggers the pinning of the recrystallised matrix, stabilising the fine-grained microtexture for GSS creep process, and finally contributes to the rheological weakening of pyroxenites.</p><p>Pyroxenites and peridotites of Ulten Zone thus offer a unique opportunity to investigate the effects of mantle deformation and weakening on the processes that control the material exchange between crust and mantle at subduction zones.</p><p> </p><p>Morten, L., & Obata, M. (1983). Bulletin de Minéralogie, 106(6), 775-780.</p><p>Nimis, P. & Morten, L. (2000). Journal of Geodynamics, 30(1-2), 93-115</p><p>Obata, M., & Morten, L. (1987). Journal of Petrology, 28(3), 599-623.</p>

2021 ◽  
Author(s):  
Luca Pellegrino ◽  
Luca Menegon ◽  
Stefano Zanchetta ◽  
Falko Langenhorst ◽  
Kilian Pollok ◽  
...  

<p>Pyroxenites are common compositional heterogeneities in the upper mantle and represent key lithologies in mantle deformation processes, as the local presence of pyroxene-rich compositions can weaken the mantle strength. Pyroxenites occur ubiquitously as variably deformed layers in most of oceanic and orogenic peridotite massifs, and thus can be used as a proxy to investigate the rheological behavior of the mantle in different geodynamic settings, including subduction zones.  <br>In the Ulten Zone (Tonale nappe, Eastern Alps, N Italy), numerous peridotite bodies occur within high-grade crustal rocks. Peridotites show a transition from coarse protogranular spinel lherzolites to finer-grained amphibole + garnet peridotites (Obata and Morten, 1987). Pyroxenites veins and dikes, transposed along the peridotite foliation, show a similar evolution from coarse garnet-free websterites to finer-grained garnet clinopyroxenites (Morten and Obata, 1983). This evolution has been interpreted to reflect cooling and pressure increase of pyroxenites and host peridotites from spinel- (1200 °C, 1.3-1.6 GPa) to garnet-facies conditions (850 °C and 2.7 GPa) within the mantle corner flow (Nimis and Morten, 2000). This results in the consequent formation of garnet at the expense of spinel. In particular, garnet initially formed as coronas around spinel and as exsolution lamellae in high-T pyroxenes, and later as neoblasts along the foliation of pyroxenites and host peridotites. <br>Microstructures and crystallographic orientation data indicate that the transition from spinel- to garnet-facies conditions occurred in a deformation regime. Pyroxene porphyroclasts in garnet clinopyroxenites show well-developed crystallographic preferred orientation, high frequency of low-angle misorientations, and non-random distribution of the low-angle misorientation axes. These features indicate that pyroxene porphyroclasts primarily deformed by grain size insensitive (GSI) creep. Core-and-mantle microstructures in pyroxene porphyroclasts also suggest that GSI creep was aided by subgrain rotation (SGR) during recrystallization, leading the formation of smaller, neoblastic, and strain-free pyroxene grains around porphyroclasts. These recrystallized grains have been interpreted to deform by grain boundary sliding, i.e. a grain size sensitive (GSS) creep mechanism, as indicated by the occurrence of quadruple junctions between straight grain boundaries. Our rheological models also suggest that GSS creep of neoblastic pyroxenes occurred at differential stress of 40 MPa and strain rates of 10<sup>-18</sup>-10<sup>-15</sup> s<sup>-1</sup>. <br>The transition from GSI creep in the porphyroclasts to GSS creep in the neoblasts was accompanied not only by a reduction of the grain size of pyroxenes, but also by the crystallization of garnet along the pyroxenite foliation which facilitated pinning by second phase in the recrystallized matrix. This stabilized the fine-grained microtexture produced by the GSS creep process, and finally contributed to the rheological weakening of pyroxenites. <br>Pyroxenites of Ulten Zone thus offer a unique opportunity to investigate the effects of mantle weakening on the processes that control the material exchange between crust and mantle at subduction zones.</p><p>Morten, L., & Obata, M. (1983). Bulletin de Minéralogie, 106(6), 775-780.<br>Nimis, P. & Morten, L. (2000). Journal of Geodynamics, 30(1-2), 93-115<br>Obata, M., & Morten, L. (1987). Journal of Petrology, 28(3), 599-623.</p>


2018 ◽  
Author(s):  
Felix Hentschel ◽  
Claudia A. Trepmann ◽  
Emilie Janots

Abstract. Deformation microstructures of albitic plagioclase and K-feldspar were investigated in mylonitic pegmatites from the Austroalpine basement south of the western Tauern Window by polarized light microscopy, electron microscopy and electron backscatter diffraction to evaluate the rheologically dominant feldspar deformation mechanisms at greenschist facies conditions. The main mylonitic characteristics are alternating almost monophase quartz and albite layers, surrounding porphyroclasts of deformed feldspar and tourmaline. The dominant deformation microstructures of K-feldspar porphyroclasts are intragranular fractures parallel to the main shortening direction indicated by the foliation. The fractures are healed or sealed by polyphase aggregates of albite, K-feldspar, quartz and mica, which also occur along intragranular fractures of tourmaline and strain shadows around other porphyroclasts. Polyphase aggregates at sites of dilation indicate dissolution-precipitation creep. K-feldspar porphyroclasts are partly replaced by albite characterized by a sawtooth-shaped interface. This replacement is interpreted to be by interface-coupled dissolution-precipitation driven by a solubility difference between K-feldspar and albite and is not controlled by strain. In contrast, albite porphyroclasts are replaced at sites of shortening by fine-grained monophase albite aggregates of small strain-free new grains mixed with deformed fragments. Dislocation glide is indicated by bent, kinked and twinned albite. No indication of effective dislocation climb with dynamic recovery, for example by the presence of subgrains, a crystallographic preferred orientation or sutured grain boundaries was observed. We interpret the grain size reduction of albite at sites of shortening to be the result of coupled fracturing, dislocation glide and strain-induced grain boundary migration. This strain-induced replacement by nucleation and growth leads, together with granular flow, to the monophase albite layers. The associated quartz layers in contrast, show characteristics of dislocation creep by the presence of subgrains, undulatory extinction and sutured grain boundaries. We identified two endmember matrix microstructures that correlate with strain. Samples with lower strain are characterized by layers of a few hundreds of µm width, with coarse-grained quartz and layers with isometric, fine-grained feldspar. Higher strained samples are characterized by narrow alternating layers of some tens of µm width composed of fine-grained quartz and coarse albite grains elongated parallel to the stretching lineation, respectively. These observations indicate that grain size reduction by strain-induced replacement of albite, granular flow assisted by fracturing and dissolution-precipitation together with dislocation creep of quartz are rheologically dominant.


2018 ◽  
Author(s):  
Alberto Ceccato ◽  
Luca Menegon ◽  
Giorgio Pennacchioni ◽  
Luiz Fernando Grafulha Morales

Abstract. At mid-crustal conditions, deformation of feldspar is mainly accomplished by a combination of fracturing, dissolution/precipitation and reaction-weakening mechanisms. In particular, K-feldspar is reaction-weakened by formation of strain-induced myrmekite – a fine-grained symplectite of plagioclase and quartz. Here we investigate with EBSD the microstructure of a granodiorite mylonite, developed at 420–460 °C during cooling of the Rieserferner pluton (Eastern Alps), to assess the microstructural processes and the role of weakening associated with myrmekite development. Our analysis shows that the crystallographic orientation of the plagioclase of pristine myrmekite was controlled by that of the replaced K-feldspar. Myrmekite nucleation resulted in both grain size reduction and ordered phase mixing by heterogeneous nucleation of quartz and plagioclase. The fine grain size of sheared myrmekite promoted grain size-sensitive creep mechanisms including fluid-assisted grain boundary sliding in plagioclase, coupled with heterogeneous nucleation of quartz within creep cavitation pores. Flow laws calculated for monomineralic quartz, feldspar, and quartz + plagioclase aggregates (sheared myrmekite), show that during mylonitization at 450 °C, grain-size-sensitive creep in sheared myrmekite accommodated strain rates several orders of magnitude higher than monomineralic quartz layers deforming by dislocation creep. Therefore, diffusion creep and grain size-sensitive processes contributed significantly to bulk rock weakening during mylonitization. Our results have implications for modelling the rheology of the mid-upper continental (felsic) crust.


Solid Earth ◽  
2018 ◽  
Vol 9 (6) ◽  
pp. 1399-1419 ◽  
Author(s):  
Alberto Ceccato ◽  
Luca Menegon ◽  
Giorgio Pennacchioni ◽  
Luiz Fernando Grafulha Morales

Abstract. At mid-crustal conditions, deformation of feldspar is mainly accommodated by a combination of fracturing, dissolution–precipitation, and reaction-weakening mechanisms. In particular, K-feldspar is reaction-weakened by the formation of strain-induced myrmekite – a fine-grained symplectite of plagioclase and quartz. Here we use electron backscattered diffraction to (i) investigate the microstructure of a granodiorite mylonite, developed at  ∼ 450 °C during cooling of the Rieserferner pluton (Eastern Alps); and (ii) assess the microstructural processes and the weakening associated with myrmekite development. Our analysis shows that the crystallographic orientation of plagioclase in pristine myrmekite was controlled by that of the replaced K-feldspar. Myrmekite nucleation resulted in both grain-size reduction and anti-clustered phase mixing by heterogeneous nucleation of quartz and plagioclase. The fine grain size of sheared myrmekite promoted grain-size-sensitive creep mechanisms including fluid-assisted grain boundary sliding in plagioclase, coupled with heterogeneous nucleation of quartz within creep cavitation pores. Flow laws, calculated for monomineralic quartz, feldspar, and quartz + plagioclase aggregates (sheared myrmekite) during deformation at 450 °C, show that grain-size-sensitive creep in sheared myrmekite accommodated strain rates several orders of magnitude higher than monomineralic quartz layers deforming by dislocation creep. Therefore, diffusion creep and grain-size-sensitive processes contributed significantly to bulk rock weakening during mylonitization. Our results have implications for modelling the rheology of the felsic middle crust.


Solid Earth ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 95-116 ◽  
Author(s):  
Felix Hentschel ◽  
Claudia A. Trepmann ◽  
Emilie Janots

Abstract. Deformation microstructures of albitic plagioclase and K-feldspar were investigated in mylonitic pegmatites from the Austroalpine basement south of the western Tauern Window by polarized light microscopy, electron microscopy and electron backscatter diffraction to evaluate feldspar deformation mechanisms at greenschist facies conditions. The main mylonitic characteristics are alternating almost monophase quartz and albite layers, surrounding porphyroclasts of deformed feldspar and tourmaline. The dominant deformation microstructures of K-feldspar porphyroclasts are intragranular fractures at a high angle to the stretching lineation. The fractures are healed or sealed by polyphase aggregates of albite, K-feldspar, quartz and mica, which also occur along intragranular fractures of tourmaline and strain shadows around other porphyroclasts. These polyphase aggregates indicate dissolution–precipitation creep. K-feldspar porphyroclasts are partly replaced by albite characterized by a cuspate interface. This replacement is interpreted to take place by interface-coupled dissolution–precipitation driven by a solubility difference between K-feldspar and albite. Albite porphyroclasts are replaced at boundaries parallel to the foliation by fine-grained monophase albite aggregates of small strain-free new grains mixed with deformed fragments. Dislocation glide is indicated by bent and twinned albite porphyroclasts with internal misorientation. An indication of effective dislocation climb with dynamic recovery, for example, by the presence of subgrains, is systematically missing. We interpret the grain size reduction of albite to be the result of coupled dislocation glide and fracturing (low-temperature plasticity). Subsequent growth is by a combination of strain-induced grain boundary migration and formation of growth rims, resulting in an aspect ratio of albite with the long axis within the foliation. This strain-induced replacement by nucleation (associated dislocation glide and microfracturing) and subsequent growth is suggested to result in the observed monophase albite layers, probably together with granular flow. The associated quartz layers show characteristics of dislocation creep by the presence of subgrains, undulatory extinction and sutured grain boundaries. We identified two endmember matrix microstructures: (i) alternating layers of a few hundred micrometres' width, with isometric, fine-grained feldspar (on average 15 µm in diameter) and coarse-grained quartz (a few hundred micrometres in diameter), representing lower strain compared to (ii) alternating thin layers of some tens of micrometres' width composed of fine-grained quartz (<20 µm in diameter) and coarse elongated albite grains (long axis of a few tens of micrometres) defining the foliation, respectively. Our observations indicate that grain size reduction by strain-induced replacement of albite (associated dislocation glide and microfracturing) followed by growth and granular flow simultaneous with dislocation creep of quartz are playing the dominating role in formation of the mylonitic microstructure.


2015 ◽  
Vol 7 (4) ◽  
pp. 2953-2998
Author(s):  
G. Viegas ◽  
L. Menegon ◽  
C. J. Archanjo

Abstract. The Pernambuco shear zone (northeastern Brazil) is a large-scale strike-slip fault that, in its eastern segment, deforms granitoids at mid-crustal conditions. Initially coarse (> 50 μm) grained feldspar porphyroclasts are intensively fractured and reduced to an ultrafine-grained mixture consisting of plagioclase and K-feldspar grains (~ < 15 μm in size) localized in C' shear bands. Detailed microstructural observations and EBSD analysis do not show evidence of intracrystalline plasticity in feldspar porphyroclasts and/or fluid-assisted replacement reactions. Quartz occurs either as thick (~ 1–2 mm) monomineralic bands or as thin ribbons dispersed in the feldspathic mixture. The microstructure and c axis crystallographic preferred orientation are similar in the thick monomineralic band and in the thin ribbons, and suggest dominant subgrain rotation recrystallization and activity of prism ⟨a⟩ and rhomb ⟨a⟩ slip systems. However, the grain size in monophase recrystallized domains decreases when moving from the transposed veins to the thin ribbons embedded in the feldspathic C' bands (14 μm vs. 5 μm, respectively). The fine-grained feldspar mixture has a weak crystallographic preferred orientation interpreted as the result of oriented growth during diffusion creep, as well as the same composition as the fractured porphyroclasts, suggesting that it generated by mechanical fragmentation of rigid porphyroclasts with a negligible role of chemical disequilibrium. Assuming that the C' shear bands deformed under constant stress conditions, the polyphase feldspathic aggregate would have deformed at a strain rate one order of magnitude faster than the monophase quartz ribbons. Overall, our dataset indicates that feldspar underwent a brittle-viscous transition while quartz was deforming via crystal plasticity. The resulting rock microstructure consists of a two-phase rheological mixture (fine-grained feldspars and recrystallized quartz) in which the polyphase feldspathic material localized much of the strain. Extensive grain-size reduction and weakening of feldspars is attained in the East Pernambuco mylonites mainly via fracturing under relatively fluid-absent conditions which would trigger a switch to diffusion creep and further strain localization without a prominent role of metamorphic reactions.


Solid Earth ◽  
2018 ◽  
Vol 9 (4) ◽  
pp. 985-1009 ◽  
Author(s):  
Sina Marti ◽  
Holger Stünitz ◽  
Renée Heilbronner ◽  
Oliver Plümper ◽  
Rüdiger Kilian

Abstract. It is widely observed that mafic rocks are able to accommodate high strains by viscous flow. Yet, a number of questions concerning the exact nature of the involved deformation mechanisms continue to be debated. In this contribution, rock deformation experiments on four different water-added plagioclase–pyroxene mixtures are presented: (i) plagioclase(An60–70)–clinopyroxene–orthopyroxene, (ii) plagioclase(An60)–diopside, (iii) plagioclase(An60)–enstatite, and (iv) plagioclase(An01)–enstatite. Samples were deformed in general shear at strain rates of 3×10−5 to 3×10−6 s−1, 800 °C, and confining pressure of 1.0 or 1.5 GPa. Results indicate that dissolution–precipitation creep (DPC) and grain boundary sliding (GBS) are the dominant deformation mechanisms and operate simultaneously. Coinciding with sample deformation, syn-kinematic mineral reactions yield abundant nucleation of new grains; the resulting intense grain size reduction is considered crucial for the activity of DPC and GBS. In high strain zones dominated by plagioclase, a weak, nonrandom, and geometrically consistent crystallographic preferred orientation (CPO) is observed. Usually, a CPO is considered a consequence of dislocation creep, but the experiments presented here demonstrate that a CPO can develop during DPC and GBS. This study provides new evidence for the importance of DPC and GBS in mid-crustal shear zones within mafic rocks, which has important implications for understanding and modeling mid-crustal rheology and flow.


Solid Earth ◽  
2016 ◽  
Vol 7 (2) ◽  
pp. 375-396 ◽  
Author(s):  
Gustavo Viegas ◽  
Luca Menegon ◽  
Carlos Archanjo

Abstract. The Pernambuco shear zone (northeastern Brazil) is a large-scale strike-slip fault that, in its eastern segment, deforms granitoids at mid-crustal conditions. Initially coarse-grained (> 50 µm) feldspar porphyroclasts are intensively fractured and reduced to an ultrafine-grained mixture consisting of plagioclase and K-feldspar grains (< 15 µm) localized in C' shear bands. Detailed microstructural observations and electron backscatter diffraction (EBSD) analysis do not show evidence of intracrystalline plasticity in feldspar porphyroclasts and/or fluid-assisted replacement reactions. Quartz occurs either as thick (∼ 1–2 mm) monomineralic veins transposed along the shear zone foliation or as thin ribbons ( ≤ 25 µm width) dispersed in the feldspathic mixture. The microstructure and c axis crystallographic-preferred orientation are similar in the thick monomineralic veins and in the thin ribbons, and they suggest dominant subgrain rotation recrystallization and activity of prism < a > and rhomb < a > slip systems. However, the grain size in monophase recrystallized domains decreases when moving from the quartz monomineralic veins to the thin ribbons embedded in the feldspathic C' bands (14 µm vs. 5 µm respectively). The fine-grained feldspar mixture has a weak crystallographic-preferred orientation interpreted as the result of shear zone parallel-oriented growth during diffusion creep, as well as the same composition as the fractured porphyroclasts, suggesting that it generated by mechanical fragmentation of rigid porphyroclasts with a negligible role of chemical disequilibrium. Once C' shear bands were generated and underwent viscous deformation at constant stress conditions, the polyphase feldspathic aggregate would have deformed at a strain rate 1 order of magnitude faster than the monophase quartz monomineralic veins, as evidenced by applying experimentally and theoretically calibrated flow laws for dislocation creep in quartz and diffusion creep in feldspar. Overall, our data set indicates that feldspar underwent a brittle-viscous transition while quartz was deforming via crystal plasticity. The resulting rock microstructure consists of a two-phase rheological mixture (fine-grained feldspars and recrystallized quartz) in which the polyphase feldspathic material localized much of the strain. Extensive grain-size reduction and weakening of feldspars is attained in the East Pernambuco mylonites mainly via fracturing which would trigger a switch to diffusion creep and strain localization without a prominent role of metamorphic reactions.


2021 ◽  
Author(s):  
Meghana Ranganathan ◽  
Brent Minchew ◽  
Colin Meyer ◽  
Matej Pec

&lt;p&gt;The initiation and propagation of fractures in floating regions of Antarctica has the potential to destabilize large regions of the ice sheet, leading to significant sea-level rise. While observations have shown rapid, localized deformation and damage in the margins of fast-flowing glaciers, there remain gaps in our understanding of how rapid deformation affects the creep and toughness of ice. Here we derive a model for dynamic recrystallization in ice and other rocks that includes a novel representation of migration recrystallization, which is absent from existing models but is likely to be dominant in warm areas undergoing rapid deformation within the ice sheet. We show that, in regions of elevated strain rate, grain sizes in ice may be larger than expected (~15 mm) due to migration recrystallization, a significant deviation from solid earth studies which find fine-grained rock in shear zones. This may imply that ice in shear margins deforms primarily by dislocation creep, suggesting a flow-law exponent of n=4 in these regions. Further, we find from existing models that this increase in grain size results in a decrease in tensile strength of ice by ~75% in the margins of glaciers. Thus, we expect that this increase in grain size makes the margins of fast-flowing glaciers less viscous and more vulnerable to fracture than we may suppose from standard model parameters.&lt;/p&gt;


1994 ◽  
Vol 9 (6) ◽  
pp. 1392-1396 ◽  
Author(s):  
Eric M. Taleff ◽  
Oleg D. Sherby

A Mg-6.5 wt. % Li alloy containing 80% hep alpha phase and 20% bcc beta phase was processed to achieve an average grain size of 5.9 μm. Strain-rate-change tests were performed in the temperature range from 398 K to 573 K. Two types of creep behavior were observed. A stress exponent of five, obtained at low temperatures and high stresses, is attributed to a diffusion-controlled dislocation creep process in the alpha matrix. A stress exponent of three, obtained at high temperatures and low stresses, is attributed to a solute-drag controlled dislocation creep process in the alpha matrix.


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