The Airyx 2D SkySpec instrument: MAX-DOAS measurements of tropospheric NO2 and HCHO in Munich and the comparison to satellite observations

2020 ◽  
Author(s):  
Johannes Lampel ◽  
Ka Lok Chan ◽  
Denis Pöhler ◽  
Matthias Wiegner ◽  
Carlos Alberti ◽  
...  
Keyword(s):  
Pearson Correlation ◽  
Satellite Observations ◽  
Optical Absorption Spectroscopy ◽  
Aerosol Extinction ◽  
Aerosol Formation ◽  
Mixing Ratios ◽  
Monitor Data ◽  
Sun Light ◽  
Good Agreement

<p>We present the Airyx 2D SkySpec Instrument: A commercially available two-dimensionally scanning Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) setup for the observations of trace gases using spectral measurements of scattered sun light and optionally also direct sun light. The waterproof design of the scanner unit is designed for long-term outdoor deployment. Temperature stabilisation of the spectrometers and automatic calibration spectra measurement are used to ensure high-quality measurement data over months and years of observations.</p><p>We show 2.5 years of measurements in Munich. Vertical columns and vertical distribution profiles of aerosol extinction coefficient, NO<sub>2</sub> and HCHO are retrieved from the 2D MAX-DOAS observations. The measured surface aerosol extinction coefficients and NO<sub>2</sub> mixing ratios are compared to in-situ monitor data. The retrieved surface NO<sub>2</sub> mixing ratios show good agreement with in-situ monitor data with a Pearson correlation coefficient (R) of 0.91. Good agreement (R= 0.80) is also found for AOD when compared to sun-photometer measurements. Tropospheric vertical column densities (VCDs) of NO2 and HCHO derived from the MAX-DOAS measurements are also used to validate OMI and TROPOMI satellite observations. Monthly averaged data show good correlation, however, satellite observations are on average 30% lower than the MAX-DOAS measurements. Furthermore, the 2D MAX-DOAS observations are used to investigate the spatio-temporal characteristic of NO2 and HCHO in Munich. Analysis of the relations among aerosol, NO<sub>2</sub> and HCHO show higher aerosol to HCHO ratios in winter indicating a longer atmospheric lifetime of aerosol and HCHO. The analysis also suggests that secondary aerosol formation is the major source of aerosols in Munich.</p>

scholarly journals MAX-DOAS measurements of tropospheric NO<sub>2</sub> and HCHO in Munich and the comparison to OMI and TROPOMI satellite observations

2020 ◽  
Author(s):  
Ka Lok Chan ◽  
Matthias Wiegner ◽  
Carlos Alberti ◽  
Mark Wenig
Keyword(s):  
Pearson Correlation ◽  
Satellite Observations ◽  
Optical Absorption Spectroscopy ◽  
Aerosol Extinction ◽  
Aerosol Formation ◽  
Vertical Column ◽  
Mixing Ratios ◽  
Monitor Data ◽  
Good Agreement

Abstract. We present two dimensionally scanning Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations of nitrogen dioxide (NO2) and formaldehyde (HCHO) in Munich. Vertical columns and vertical distribution profiles of aerosol extinction coefficient, NO2 and HCHO are retrieved from the 2D MAX-DOAS observations. The measured surface aerosol extinction coefficients and NO2 mixing ratios derived from the retrieved profiles are compared to in-situ monitor data, and the surface NO2 mixing ratios show good agreement with in-situ monitor data with a Pearson correlation coefficient (R) of 0.91. The aerosols optical depths (AODs) show good agreement as well (R = 0.80) when compared to sun-photometer measurements. Tropospheric vertical column densities (VCDs) of NO2 and HCHO derived from the MAX-DOAS measurements are also used to validate OMI and TROPOMI satellite observations. Monthly averaged data show good correlation, however, satellite observations are on average 30 % lower than the MAX-DOAS measurements. Furthermore, the MAX-DOAS observations are used to investigate the spatio-temporal characteristic of NO2 and HCHO in Munich. Analysis of the relations among aerosol, NO2 and HCHO shows higher aerosol to HCHO ratios in winter indicating a longer atmospheric lifetime of aerosol and HCHO. The analysis also suggests that secondary aerosol formation is the major source of aerosols in Munich.

scholarly journals MAX-DOAS measurements of tropospheric NO<sub>2</sub> and HCHO in Munich and the comparison to OMI and TROPOMI satellite observations

2020 ◽  
Vol 13 (8) ◽  
pp. 4499-4520 ◽  
Author(s):  
Ka Lok Chan ◽  
Matthias Wiegner ◽  
Jos van Geffen ◽  
Isabelle De Smedt ◽  
Carlos Alberti ◽  
...  
Keyword(s):  
Satellite Observations ◽  
In Situ Monitoring ◽  
Monitoring Data ◽  
Aerosol Extinction ◽  
Aerosol Formation ◽  
Secondary Aerosol ◽  
Monitoring Instrument ◽  
Mixing Ratios ◽  
Good Agreement

Abstract. We present two-dimensional scanning Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations of nitrogen dioxide (NO2) and formaldehyde (HCHO) in Munich. Vertical columns and vertical distribution profiles of aerosol extinction coefficient, NO2 and HCHO are retrieved from the 2D MAX-DOAS observations. The measured surface aerosol extinction coefficients and NO2 mixing ratios derived from the retrieved profiles are compared to in situ monitoring data, and the surface NO2 mixing ratios show a good agreement with in situ monitoring data with a Pearson correlation coefficient (R) of 0.91. The aerosol optical depths (AODs) show good agreement as well (R = 0.80) when compared to sun photometer measurements. Tropospheric vertical column densities (VCDs) of NO2 and HCHO derived from the MAX-DOAS measurements are also used to validate Ozone Monitoring Instrument (OMI) and TROPOspheric Monitoring Instrument (TROPOMI) satellite observations. Monthly averaged data show a good correlation; however, satellite observations are on average 30 % lower than the MAX-DOAS measurements. Furthermore, the MAX-DOAS observations are used to investigate the spatiotemporal characteristic of NO2 and HCHO in Munich. Analysis of the relations between aerosol, NO2 and HCHO shows higher aerosol-to-HCHO ratios in winter, which reflects a longer atmospheric lifetime of secondary aerosol and HCHO during winter. The analysis also suggests that secondary aerosol formation is the major source of these aerosols in Munich.

scholarly journals MAX-DOAS observations of the total atmospheric water vapour column and comparison with independent observations

2013 ◽  
Vol 6 (1) ◽  
pp. 131-149 ◽  
Author(s):  
T. Wagner ◽  
M. O. Andreae ◽  
S. Beirle ◽  
S. Dörner ◽  
K. Mies ◽  
...  
Keyword(s):  
Radiative Transfer ◽  
Water Vapour ◽  
Satellite Observations ◽  
Shielding Effect ◽  
Optical Absorption Spectroscopy ◽  
Atmospheric Water ◽  
Near Surface ◽  
Atmospheric Water Vapour ◽  
Independent Observations ◽  
Good Agreement

Abstract. We developed an algorithm for the retrieval of the atmospheric water vapour column from Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations in the yellow and red spectral range. The retrieval is based on the so-called geometric approximation and does not depend on explicit a priori information for individual observations, extensive radiative transfer simulations, or the construction of large look-up tables. Disturbances of the radiative transfer due to aerosols and clouds are simply corrected using the simultaneously measured absorptions of the oxygen dimer, O4. We applied our algorithm to MAX-DOAS observations made at the Max Planck Institute for Chemistry in Mainz, Germany, from March to August 2011, and compared the results to independent observations. Good agreement with Aerosol Robotic Network (AERONET) and European Centre for Medium-Range Weather Forecasting (ECMWF) H2O vertical column densities (VCDs) is found, while the agreement with satellite observations is less good, most probably caused by the shielding effect of clouds for the satellite observations. Good agreement is also found with near-surface in situ observations, and it was possible to derive average daily H2O scale heights (between 1.5 km and 3 km). MAX-DOAS measurements use cheap and simple instrumentation and can be run automatically. One important advantage of our algorithm is that the H2O VCD can be retrieved even under cloudy conditions (except clouds with very high optical thickness).

scholarly journals Vertical profiles of NO<sub>2</sub>, SO<sub>2</sub>, HONO, HCHO, CHOCHO, and aerosols derived from MAX-DOAS measurements at a rural site in the central-western North China Plain and their relation to emission sources and effects of regional transport

2018 ◽  
Author(s):  
Yang Wang ◽  
Steffen Dörner ◽  
Sebastian Donner ◽  
Sebastian Böhnke ◽  
Isabelle De Smedt ◽  
...  
Keyword(s):  
Trace Gases ◽  
Rural Site ◽  
Optical Absorption Spectroscopy ◽  
Vertical Profiles ◽  
Regional Transport ◽  
Near Surface ◽  
North West ◽  
Mixing Ratios ◽  
Chemistry Research

Abstract. A Multi Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) instrument was deployed in May and June 2016 at a monitoring station (37.18° N, 114.36° E) in the suburban area of Xingtai (one of the most polluted cities in China) during the Atmosphere-Aerosol-Boundary Layer-Cloud (A2BC) and Air chemistry Research In Asia (ARIAs) joint experiments to derive tropospheric vertical profiles of NO2, SO2, HONO, HCHO, CHOCHO and aerosols. Aerosol optical depths derived from MAX-DOAS were found to be consistent with collocated sun-photometer measurements. Also the derived near-surface aerosol extinction and HCHO mixing ratio agree well with coincident visibility meter and in situ HCHO measurements, with mean HCHO near-surface mixing ratios of ~ 3.5 ppb. Underestimates of MAX-DOAS results compared to in situ measurements of NO2 (~ 60 %), SO2 (~ 20 %) are found expectedly due to vertical and horizontal inhomogeneity of trace gases. Vertical profiles of aerosols and NO2, SO2 are reasonably consistent with those measured by a collocated Raman Lidar and aircraft spirals over the station. The deviations can be attributed to differences in sensitivity as a function of altitude and substantial horizontal gradients of pollutants. Aerosols, HCHO, and CHOCHO profiles typically extended to higher altitudes (with 75 % integrated column located below ~ 1.4 km) than did NO2, SO2, and HONO (with 75 % integrated column below ~ 0.5 km) under polluted condition. Lifted layers were systematically observed for all species, (except HONO), indicating accumulation, secondary formation, or long-range transport of the pollutants at higher altitudes. Maximum values routinely occurred in the morning for NO2, SO2, and HONO, but around noon for aerosols, HCHO, and CHOCHO, mainly dominated by photochemistry, characteristic upslope/downslope circulation and PBL dynamics. Significant day-to-day variations are found for all species due to the effect of regional transport and changes in synoptic pattern analysed with HYSPLIT trajectories. Low pollution was often observed for air masses from the north-west (behind cold fronts), and high pollution from the southern areas such as industrialized Wuan. The contribution of regional transport for the pollutants measured at the site during the observation period was estimated to be about 20 % to 30 % for trace gases, and about 50 % for aerosols. In addition, agricultural burning events impacted the day-to-day variations of HCHO, CHOCHO and aerosols.

scholarly journals Total column CO<sub>2</sub> measurements at Darwin, Australia – site description and calibration against in situ aircraft profiles

2010 ◽  
Vol 3 (2) ◽  
pp. 989-1021 ◽  
Author(s):  
N. M. Deutscher ◽  
D. W. T. Griffith ◽  
G. W. Bryant ◽  
P. O. Wennberg ◽  
G. C. Toon ◽  
...  
Keyword(s):  
Nir Spectroscopy ◽  
Solar Observatory ◽  
Total Carbon ◽  
Relative Precision ◽  
Mixing Ratios ◽  
Clear Sky ◽  
The World ◽  
Total Column ◽  
Good Agreement

Abstract. An automated Fourier Transform Spectroscopic (FTS) solar observatory was established in Darwin, Australia in August 2005. The laboratory is part of the Total Carbon Column Observing Network, and measures atmospheric column abundances of CO2 and O2 and other gases. Measured CO2 columns were calibrated against integrated aircraft profiles obtained during the TWP-ICE campaign in January–February 2006, and show good agreement with calibrations for a similar instrument in Park Falls, Wisconsin. A clear-sky low airmass relative precision of 0.1% is demonstrated in the CO2 and O2 retrieved column-averaged volume mixing ratios. The 1% negative bias in the FTS XCO2 relative to the World Meteorological Organization (WMO) calibrated in situ scale is within the uncertainties of the NIR spectroscopy and analysis.

scholarly journals MAX-DOAS retrieval of aerosol extinction properties in Madrid, Spain

2016 ◽  
Author(s):  
Shanshan Wang ◽  
Carlos A. Cuevas ◽  
Udo Frieß ◽  
Alfonso Saiz-Lopez
Keyword(s):  
Saharan Dust ◽  
Optical Absorption Spectroscopy ◽  
Retrieval Algorithm ◽  
Back Trajectory ◽  
Aerosol Extinction ◽  
Inversion Algorithm ◽  
Back Trajectory Analysis ◽  
Particle Layer ◽  
Level Of Agreement

Abstract. Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements were performed in the urban environment of Madrid, Spain, from March to September in 2015. The O4 absorption in the UV was used to retrieve the aerosol extinction profile by an inversion algorithm. The results show a good agreement between the hourly retrieved aerosol optical depth (AOD) and the correlative Aerosol Robotic Network (AERONET) product, with a correlation coefficient of R = 0.87. Higher AODs are found in the summer season due to the more frequent occurrence of Saharan dust intrusions. The surface aerosol extinction coefficient as retrieved by the MAX-DOAS measurements was also compared to in situ PM2.5 concentrations. The level of agreement between both measurements indicates that the MAX-DOAS retrieval has the ability to characterize the extinction by particle near the surface. The retrieval algorithm was also used to study a case of severe dust intrusion on 12 May 2015. The capability of the MAX-DOAS retrieval to recognize the dust event including an elevated particle layer is investigated along with air mass back trajectory analysis.

scholarly journals On the performance of satellite-based observations of <i>CO</i><sub>2</sub> in capturing the NOAA Carbon Tracker model and ground-based flask observations over Africa land mass

2019 ◽  
Author(s):  
Anteneh Getachew Mengistu ◽  
Gizaw Mengistu Tsidu
Keyword(s):  
Model Simulation ◽  
Satellite Observation ◽  
Satellite Observations ◽  
Lower Altitude ◽  
Equatorial Africa ◽  
In Situ Observations ◽  
The Mean ◽  
Data Gap ◽  
Good Agreement

Abstract. Africa is one of the most data-scarce regions as satellite observation at the equator is limited by cloud cover and there are a very limited number of ground-based measurements. As a result, the use of simulations from models are mandatory to fill this data gap. A comparison of satellite observation with model and available in-situ observations will be useful to estimate the performance of satellites in the region. In this study, GOSAT XCO2 is compared with the NOAA CT2016 and six flask observations over Africa using five years of data covering the period from May 2009 to April 2014. Ditto for OCO-2 XCO2 against NOAA CT16NRT17 and eight flask observations over Africa using two years of data covering the period from January 2015 to December 2016. The analysis shows that the XCO2 from GOSAT is higher than XCO2 simulated by CT2016 by 0.28 ppm whereas OCO-2 XCO2 is lower than CT16NRT17 by 0.34 ppm on African landmass on average. The mean correlations of 0.83 and 0.60 and average RMSD of 2.30 and 2.57 ppm are found between the model and the respective datasets from GOSAT and OCO-2 implying the existence of a reasonably good agreement between CT and the two satellites over Africa's land region. However, significant variations were observed in some regions. For example, OCO-2 XCO2 are lower than that of CT16NRT17 by up to 3 ppm over some regions in North Africa (e.g., Egypt, Libya, and Mali) whereas it exceeds CT16NRT17 XCO2 by 2 ppm over Equatorial Africa (10° S–10° N). This regional difference is also noted in the comparison of model simulations and satellite observations with flask observations over the continent. For example, CT shows a better sensitivity in capturing flask observations over sites located in Northern Africa. In contrast, satellite observations have better sensitivity in capturing flask observations in lower altitude island sites. CT2016 shows a high spatial mean of seasonal mean RMSD of 1.91 ppm during DJF with respect to GOSAT while CT16NRT17 shows 1.75 ppm during MAM with respect to OCO-2. On the other hand, low RMSD of 1.00 and 1.07 ppm during SON in the model XCO2 with respect to GOSAT and OCO-2 are determined respectively indicating better agreement during autumn. The model simulation and satellite observations exhibit similar seasonal cycles of XCO2 with a small discrepancy over Southern Africa and during wet seasons over all regions.

scholarly journals On the performance of satellite-based observations of <i>X</i>CO<sub>2</sub> in capturing the NOAA Carbon Tracker model and ground-based flask observations over Africa's land mass

2020 ◽  
Vol 13 (7) ◽  
pp. 4009-4033
Author(s):  
Anteneh Getachew Mengistu ◽  
Gizaw Mengistu Tsidu
Keyword(s):  
North Africa ◽  
Model Simulation ◽  
Satellite Observation ◽  
Satellite Observations ◽  
Lower Altitude ◽  
Equatorial Africa ◽  
Land Mass ◽  
Data Gap ◽  
Good Agreement

Abstract. Africa is one of the most data-scarce regions as satellite observation at the Equator is limited by cloud cover and there is a very limited number of ground-based measurements. As a result, the use of simulations from models is mandatory to fill this data gap. A comparison of satellite observation with model and available in situ observations will be useful to estimate the performance of satellites in the region. In this study, GOSAT column-averaged carbon dioxide dry-air mole fraction (XCO2) is compared with the NOAA CT2016 and six flask observations over Africa using 5 years of data covering the period from May 2009 to April 2014. Ditto for OCO-2 XCO2 against NOAA CT16NRT17 and eight flask observations over Africa using 2 years of data covering the period from January 2015 to December 2016. The analysis shows that the XCO2 from GOSAT is higher than XCO2 simulated by CT2016 by 0.28±1.05 ppm, whereas OCO-2 XCO2 is lower than CT16NRT17 by 0.34±0.9 ppm on the African land mass on average. The mean correlations of 0.83±1.12 and 0.60±1.41 and average root mean square deviation (RMSD) of 2.30±1.45 and 2.57±0.89 ppm are found between the model and the respective datasets from GOSAT and OCO-2, implying the existence of a reasonably good agreement between CT and the two satellites over Africa's land region. However, significant variations were observed in some regions. For example, OCO-2 XCO2 are lower than that of CT16NRT17 by up to 3 ppm over some regions in North Africa (e.g. Egypt, Libya, and Mali), whereas it exceeds CT16NRT17 XCO2 by 2 ppm over Equatorial Africa (10∘ S–10∘ N). This regional difference is also noted in the comparison of model simulations and satellite observations with flask observations over the continent. For example, CT shows a better sensitivity in capturing flask observations over sites located in North Africa. In contrast, satellite observations have better sensitivity in capturing flask observations in lower-altitude island sites. CT2016 shows a high spatial mean of seasonal mean RMSD of 1.91 ppm during DJF with respect to GOSAT, while CT16NRT17 shows 1.75 ppm during MAM with respect to OCO-2. On the other hand, low RMSDs of 1.00 and 1.07 ppm during SON in the model XCO2 with respect to GOSAT and OCO-2 are respectively determined, indicating better agreement during autumn. The model simulation and satellite observations exhibit similar seasonal cycles of XCO2 with a small discrepancy over Southern Africa (35–10∘ S) and during wet seasons over all regions.

scholarly journals In situ measurements of molecular iodine in the marine boundary layer: the link to macroalgae and the implications for O<sub>3</sub>, IO, OIO and NO<sub>x</sub>

2010 ◽  
Vol 10 (1) ◽  
pp. 361-390
Author(s):  
R.-J. Huang ◽  
K. Seitz ◽  
J. Buxmann ◽  
D. Poehler ◽  
K. E. Hornsby ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Marine Boundary Layer ◽  
Single Point ◽  
Molecular Iodine ◽  
In Situ Measurements ◽  
Gas Chromatography Mass Spectrometry ◽  
Optical Absorption Spectroscopy ◽  
Mixing Ratios ◽  
Concentration Levels

Abstract. "Single-point" in situ measurements of molecular iodine (I2) were carried out in the coastal marine boundary layer (MBL) using diffusion denuders in combination with a gas chromatography-mass spectrometry (GC-MS) method. Comparison measurements were taken at Mace Head and Mweenish Bay, on the West Coast of Ireland. The observed mixing ratios of I2 at Mweenish Bay are much higher than that at Mace Head, indicating the emissions of I2 are correlated with the local algal biomass density and algae species. The concentration levels of I2 were found to correlate inversely with tidal height and correlate positively with the concentration levels of O3 in the surrounding air. However, the released I2 can also lead to O3 destruction via the reaction of O3 with iodine atoms that are formed by the photolysis of I2 during the day and via the reaction of I2 with NOx at night. IO and OIO were measured by long-path differential optical absorption spectroscopy (LP-DOAS). The results show that the concentrations of both daytime and nighttime IO are correlated with the mixing ratios of I2. OIO was observed not only during the day but also, for the first time at both Mace Head and Mweenish Bay, at night. In addition, I2 was measured simultaneously by the LP-DOAS technique and compared with the "single-point" in situ measurement. The results suggest that the local algae sources dominate the inorganic iodine chemistry at Mace Head and Mweenish Bay.

scholarly journals Tropospheric NO<sub>2</sub> column densities deduced from zenith-sky DOAS measurements in Shanghai, China, and their application to satellite validation

2008 ◽  
Vol 8 (4) ◽  
pp. 16713-16762 ◽  
Author(s):  
D. Chen ◽  
B. Zhou ◽  
S. Beirle ◽  
L. M. Chen ◽  
T. Wagner
Keyword(s):  
Solar Zenith Angle ◽  
Surface Concentration ◽  
Urban Site ◽  
Optical Absorption Spectroscopy ◽  
Vertical Column ◽  
Satellite Validation ◽  
Tropospheric No2 ◽  
Realistic Information ◽  
Good Agreement

Abstract. Zenith-sky scattered sunlight observations using differential optical absorption spectroscopy (DOAS) technique were carried out in Shanghai, China (31.3° N, 121.5° E) since December 2006. At this polluted urban site, the measurement provided NO2 total columns in the daytime. Here, we present a new method to extract time series of tropospheric vertical column densities (VCD) of NO2 from these observations. The derived tropospheric NO2 VCD is an important quantity for the estimation of emissions and for the validation of satellite observations. Our method makes use of assumptions on the relative NO2 height profiles and on the diurnal variation of the stratospheric NO2 VCD. The influence of these parameters on the retrieved tropospheric NO2 VCD is discussed; for a polluted site like Shanghai, the accuracy of our method is estimated to be <20% for solar zenith angle (SZA) lower than 85°. From simultaneously performed long-path DOAS measurement, the NO2 surface concentration at the same site was observed and the corresponding tropospheric NO2 VCD was estimated using the assumed seasonal NO2 profiles in the planetary boundary layer (PBL). By making a comparison between the tropospheric NO2 VCD from zenith-sky and long-path DOAS measurements, it was found that the former provided more realistic information about total tropospheric pollution than the latter, so it's more suitable for satellite data validation than the in situ measurement. A comparison between the tropospheric NO2 VCD from ground-based zenith-sky measurement and SCIAMACHY was also made. Satellite validation for a strongly polluted area is highly needed, but exhibits also a great challenge. Our comparison showed good agreement, considering in particular the different spatial resolutions between the two measurements.

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