scholarly journals Optical properties of sea ice doped with black carbon – an experimental and radiative-transfer modelling comparison

2017 ◽  
Vol 11 (6) ◽  
pp. 2867-2881 ◽  
Author(s):  
Amelia A. Marks ◽  
Maxim L. Lamare ◽  
Martin D. King

Abstract. Radiative-transfer calculations of the light reflectivity and extinction coefficient in laboratory-generated sea ice doped with and without black carbon demonstrate that the radiative-transfer model TUV-snow can be used to predict the light reflectance and extinction coefficient as a function of wavelength. The sea ice is representative of first-year sea ice containing typical amounts of black carbon and other light-absorbing impurities. The experiments give confidence in the application of the model to predict albedo of other sea ice fabrics. Sea ices,  ∼  30 cm thick, were generated in the Royal Holloway Sea Ice Simulator ( ∼  2000 L tanks) with scattering cross sections measured between 0.012 and 0.032 m2 kg−1 for four ices. Sea ices were generated with and without  ∼  5 cm upper layers containing particulate black carbon. Nadir reflectances between 0.60 and 0.78 were measured along with extinction coefficients of 0.1 to 0.03 cm−1 (e-folding depths of 10–30 cm) at a wavelength of 500 nm. Values were measured between light wavelengths of 350 and 650 nm. The sea ices generated in the Royal Holloway Sea Ice Simulator were found to be representative of natural sea ices. Particulate black carbon at mass ratios of  ∼  75,  ∼  150 and  ∼  300 ng g−1 in a 5 cm ice layer lowers the albedo to 97, 90 and 79 % of the reflectivity of an undoped clean sea ice (at a wavelength of 500 nm).

2013 ◽  
Vol 7 (4) ◽  
pp. 1193-1204 ◽  
Author(s):  
A. A. Marks ◽  
M. D. King

Abstract. The response of the albedo of bare sea ice and snow-covered sea ice to the addition of black carbon is calculated. Visible light absorption and light-scattering cross-sections are derived for a typical first-year and multi-year sea ice with both "dry" and "wet" snow types. The cross-sections are derived using data from a 1970s field study that recorded both reflectivity and light penetration in Arctic sea ice and snow overlying sea ice. The variation of absorption cross-section over the visible wavelengths suggests black carbon is the dominating light-absorbing impurity. The response of first-year and multi-year sea ice albedo to increasing black carbon, from 1 to 1024 ng g−1, in a top 5 cm layer of a 155 cm-thick sea ice was calculated using a radiative-transfer model. The albedo of the first-year sea ice is more sensitive to additional loadings of black carbon than the multi-year sea ice. An addition of 8 ng g−1 of black carbon causes a decrease to 98.7% of the original albedo for first-year sea ice compared to a decrease to 99.7% for the albedo of multi-year sea ice, at a wavelength of 500 nm. The albedo of sea ice is surprisingly unresponsive to additional black carbon up to 100 ng g−1 . Snow layers on sea ice may mitigate the effects of black carbon in sea ice. Wet and dry snow layers of 0.5, 1, 2, 5 and 10 cm depth were added onto the sea ice surface. The albedo of the snow surface was calculated whilst the black carbon in the underlying sea ice was increased. A layer of snow 0.5 cm thick greatly diminishes the effect of black carbon in sea ice on the surface albedo. The albedo of a 2–5 cm snow layer (less than the e-folding depth of snow) is still influenced by the underlying sea ice, but the effect of additional black carbon in the sea ice is masked.


2013 ◽  
Vol 7 (2) ◽  
pp. 943-973
Author(s):  
A. A. Marks ◽  
M. D. King

Abstract. Black carbon in sea ice will decrease sea ice surface albedo through increased absorption of incident solar radiation, exacerbating sea ice melting. Previous literature has reported different albedo responses to additions of black carbon in sea ice and has not considered how a snow cover may mitigate the effect of black carbon in sea ice. Sea ice is predominately snow covered. Visible light absorption and light scattering coefficients are calculated for a typical first year and multi-year sea ice and "dry" and "wet" snow types that suggest black carbon is the dominating absorbing impurity. The albedo response of first year and multi-year sea ice to increasing black carbon, from 1–1024 ng g−1, in a top 5 cm layer of a 155 cm thick sea ice was calculated using the radiative transfer model: TUV-snow. Sea ice albedo is surprisingly unresponsive to black carbon additions up to 100 ng g−1 with a decrease in albedo to 98.7% of the original albedo value due to an addition of 8 ng g−1 of black carbon in first year sea ice compared to an albedo decrease to 99.6% for the same black carbon mass ratio increase in multi-year sea ice. The first year sea ice proved more responsive to black carbon additions than the multi-year ice. Comparison with previous modelling of black carbon in sea ice suggests a more scattering sea ice environment will be less responsive to black carbon additions. Snow layers on sea ice may mitigate the effects of black carbon in sea ice. "Wet" and "dry" snow layers of 0.5, 1, 2, 5 and 10 cm were added onto the sea ice surface and the snow surface albedo calculated with the same increase in black carbon in the underlying sea ice. Just a 0.5 cm layer of snow greatly diminishes the effect of black carbon on surface albedo, and a 2–5 cm layer (less than half the e-folding depth of snow) is enough to "mask" any change in surface albedo owing to additional black carbon in sea ice, but not thick enough to ignore the underlying sea ice.


2018 ◽  
Vol 12 (4) ◽  
pp. 1331-1345 ◽  
Author(s):  
Peng Lu ◽  
Matti Leppäranta ◽  
Bin Cheng ◽  
Zhijun Li ◽  
Larysa Istomina ◽  
...  

Abstract. Pond color, which creates the visual appearance of melt ponds on Arctic sea ice in summer, is quantitatively investigated using a two-stream radiative transfer model for ponded sea ice. The upwelling irradiance from the pond surface is determined and then its spectrum is transformed into RGB (red, green, blue) color space using a colorimetric method. The dependence of pond color on various factors such as water and ice properties and incident solar radiation is investigated. The results reveal that increasing underlying ice thickness Hi enhances both the green and blue intensities of pond color, whereas the red intensity is mostly sensitive to Hi for thin ice (Hi  <  1.5 m) and to pond depth Hp for thick ice (Hi  >  1.5 m), similar to the behavior of melt-pond albedo. The distribution of the incident solar spectrum F0 with wavelength affects the pond color rather than its intensity. The pond color changes from dark blue to brighter blue with increasing scattering in ice, and the influence of absorption in ice on pond color is limited. The pond color reproduced by the model agrees with field observations for Arctic sea ice in summer, which supports the validity of this study. More importantly, the pond color has been confirmed to contain information about meltwater and underlying ice, and therefore it can be used as an index to retrieve Hi and Hp. Retrievals of Hi for thin ice (Hi  <  1 m) agree better with field measurements than retrievals for thick ice, but those of Hp are not good. The analysis of pond color is a new potential method to obtain thin ice thickness in summer, although more validation data and improvements to the radiative transfer model will be needed in future.


Atmosphere ◽  
2020 ◽  
Vol 11 (10) ◽  
pp. 1077
Author(s):  
Nicholas D. Beres ◽  
Magín Lapuerta ◽  
Francisco Cereceda-Balic ◽  
Hans Moosmüller

The broadband surface albedo of snow can greatly be reduced by the deposition of light-absorbing impurities, such as black carbon on or near its surface. Such a reduction increases the absorption of solar radiation and may initiate or accelerate snowmelt and snow albedo feedback. Coincident measurements of both black carbon concentration and broadband snow albedo may be difficult to obtain in field studies; however, using the relationship developed in this simple model sensitivity study, black carbon mass densities deposited can be estimated from changes in measured broadband snow albedo, and vice versa. Here, the relationship between the areal mass density of black carbon found near the snow surface to the amount of albedo reduction was investigated using the popular snow radiative transfer model Snow, Ice, and Aerosol Radiation (SNICAR). We found this relationship to be linear for realistic amounts of black carbon mass concentrations, such as those found in snow at remote locations. We applied this relationship to measurements of broadband albedo in the Chilean Andes to estimate how vehicular emissions contributed to black carbon (BC) deposition that was previously unquantified.


Radio Science ◽  
1998 ◽  
Vol 33 (2) ◽  
pp. 303-316 ◽  
Author(s):  
Rolf Fuhrhop ◽  
Thomas C. Grenfell ◽  
Georg Heygster ◽  
Klaus-Peter Johnsen ◽  
Peter Schlüssel ◽  
...  

2019 ◽  
Author(s):  
Gauthier Verin ◽  
Florent Dominé ◽  
Marcel Babin ◽  
Ghislain Picard ◽  
Laurent Arnaud

Abstract. The energy budget of Arctic sea ice is strongly affected by the snow cover. Intensive sampling of snow properties was conducted near Qikiqtarjuak in Baffin Bay on typical landfast sea ice during two melt seasons in 2015 and 2016. The sampling included stratigraphy, vertical profiles of snow specific surface area (SSA), density and surface spectral albedo. Both seasons feature four main phases: I) dry snow cover, II) surface melting, III) ripe snowpack and IV) melt pond formation. Each of them was characterized by distinctive physical and optical properties. Highest SSA of 49.3 m2 kg−1 was measured during phase I on surface windslab together with a high broadband albedo of 0.87. The next phase was marked by alternative episodes of surface melting which dramatically decreased the SSA below 3 m2 kg−1 and episodes of snowfall reestablishing the pre-melt conditions. Albedo was highly time variable especially in the near-infrared with minimum values around 0.45 at 1000 nm. At some point, the melt progressed leading to a fully ripe snowpack composed of clustered rounded grains in phase III. Albedo began to decrease in the visible as snow thickness decreased but remained steady at longer wavelengths. Moreover, its spatial variability clearly appeared for the first time following snow depth heterogeneity. The impacts on albedo of both snow SSA and thickness were quantitatively investigated using a radiative transfer model. Comparisons between albedo measurements and simulations show that our data on snow physical properties are relevant for radiative transfer modeling. They also point out to the importance of the properties of the very surface snow layer for albedo computation, especially during phase II when several distinctive layers of snow superimposed following snowfalls, melt or diurnal cycles.


Elem Sci Anth ◽  
2016 ◽  
Vol 4 ◽  
Author(s):  
Susann Müller ◽  
Anssi V. Vähätalo ◽  
Jari Uusikivi ◽  
Markus Majaneva ◽  
Sanna Majaneva ◽  
...  

Abstract Bio-optics is a powerful approach for estimating photosynthesis rates, but has seldom been applied to sea ice, where measuring photosynthesis is a challenge. We measured absorption coefficients of chromophoric dissolved organic matter (CDOM), algae, and non-algal particles along with solar radiation, albedo and transmittance at four sea-ice stations in the Gulf of Finland, Baltic Sea. This unique compilation of optical and biological data for Baltic Sea ice was used to build a radiative transfer model describing the light field and the light absorption by algae in 1-cm increments. The maximum quantum yields and photoadaptation of photosynthesis were determined from 14C-incorporation in photosynthetic-irradiance experiments using melted ice. The quantum yields were applied to the radiative transfer model estimating the rate of photosynthesis based on incident solar irradiance measured at 1-min intervals. The calculated depth-integrated mean primary production was 5 mg C m–2 d–1 for the surface layer (0–20 cm ice depth) at Station 3 (fast ice) and 0.5 mg C m–2 d–1 for the bottom layer (20–57 cm ice depth). Additional calculations were performed for typical sea ice in the area in March using all ice types and a typical light spectrum, resulting in depth-integrated mean primary production rates of 34 and 5.6 mg C m–2 d–1 in surface ice and bottom ice, respectively. These calculated rates were compared to rates determined from 14C incorporation experiments with melted ice incubated in situ. The rate of the calculated photosynthesis and the rates measured in situ at Station 3 were lower than those calculated by the bio-optical algorithm for typical conditions in March in the Gulf of Finland by the bio-optical algorithm. Nevertheless, our study shows the applicability of bio-optics for estimating the photosynthesis of sea-ice algae.


2020 ◽  
Author(s):  
Robbie Mallett ◽  
Julienne Stroeve ◽  
Michel Tsamados ◽  
Glen Liston

&lt;p&gt;The depth of overlying snow on sea ice exerts a strong control on atmosphere-ocean heat and light flux and introduces major uncertainties in the remote sensing of sea ice thickness. Satellite-mounted microwave radiometers have enabled retrieval of snow depths over first year ice, but such retrievals are subject to a wide margin of error due to spatial variation in snow stratigraphy and roughness.&lt;/p&gt;&lt;p&gt;Here we model the microwave signature of snow on sea ice using a recently released sea ice variant of the snowpack evolution model, SNOWPACK (Wever et al., 2020). By advecting parcels of sea ice using ice motion vectors and exposing them to the relevant atmospheric forcing using ERA5 reanalysis, we model the accumulation of snow and the development of snowpack stratigraphy.&lt;/p&gt;&lt;p&gt;We then pass these modelled snowpacks to the Snow Microwave Radiative Transfer model (Picard et al., 2018) to estimate their microwave emission characteristics. By using relationships from the literature relating the ratios of the 37GHz and 19GHz channels, we calculate whether the traditional &amp;#8220;gradient ratio&amp;#8221; method (Markus and Cavalieri, 1998) over- or underestimates the depth of snow at a particular point based on our modelling. We then adjust the observed gradient ratio based on the model results in an attempt to better characterise snow depths.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;References&lt;/p&gt;&lt;p&gt;Wever, Nander, et al. &quot;Version 1 of a sea ice module for the physics-based, detailed, multi-layer SNOWPACK model.&quot; &lt;em&gt;Geoscientific Model Development&lt;/em&gt; 13.1 (2020): 99-119.&lt;/p&gt;&lt;p&gt;Picard, Ghislain, Melody Sandells, and Henning L&amp;#246;we. &quot;SMRT: An active&amp;#8211;passive microwave radiative transfer model for snow with multiple microstructure and scattering formulations (v1. 0).&quot; &lt;em&gt;Geoscientific Model Development &lt;/em&gt;11.7 (2018): 2763-2788.&lt;/p&gt;&lt;p&gt;Markus, Thorsten, and Donald J. Cavalieri. &quot;Snow depth distribution over sea ice in the Southern Ocean from satellite passive microwave data.&quot; &lt;em&gt;Antarctic sea ice: physical processes, interactions and variability &lt;/em&gt;74 (1998): 19-39.&lt;/p&gt;


2015 ◽  
Vol 9 (6) ◽  
pp. 2149-2161 ◽  
Author(s):  
M. C. Fuller ◽  
T. Geldsetzer ◽  
J. Yackel ◽  
J. P. S. Gill

Abstract. Within the context of developing data inversion and assimilation techniques for C-band backscatter over sea ice, snow physical models may be used to drive backscatter models for comparison and optimization with satellite observations. Such modeling has the potential to enhance understanding of snow on sea-ice properties required for unambiguous interpretation of active microwave imagery. An end-to-end modeling suite is introduced, incorporating regional reanalysis data (NARR), a snow model (SNTHERM89.rev4), and a multilayer snow and ice active microwave backscatter model (MSIB). This modeling suite is assessed against measured snow on sea-ice geophysical properties and against measured active microwave backscatter. NARR data were input to the SNTHERM snow thermodynamic model in order to drive the MSIB model for comparison to detailed geophysical measurements and surface-based observations of C-band backscatter of snow on first-year sea ice. The NARR variables were correlated to available in situ measurements with the exception of long-wave incoming radiation and relative humidity, which impacted SNTHERM simulations of snow temperature. SNTHERM snow grain size and density were comparable to observations. The first assessment of the forward assimilation technique developed in this work required the application of in situ salinity profiles to one SNTHERM snow profile, which resulted in simulated backscatter close to that driven by in situ snow properties. In other test cases, the simulated backscatter remained 4–6 dB below observed for higher incidence angles and when compared to an average simulated backscatter of in situ end-member snow covers. Development of C-band inversion and assimilation schemes employing SNTHERM89.rev4 should consider sensitivity of the model to bias in incoming long-wave radiation, the effects of brine, and the inability of SNTHERM89.Rev4 to simulate water accumulation and refreezing at the bottom and mid-layers of the snowpack. These impact thermodynamic response, brine wicking and volume processes, snow dielectrics, and thus microwave backscatter from snow on first-year sea ice.


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