scholarly journals Geochemical Classification and Determination of Maturity Source Weathering in Beach Sands of Eastern San’ in Coast, Tango Peninsula, and Wakasa Bay, Japan

2016 ◽  
Vol 5 (1) ◽  
pp. 44 ◽  
Author(s):  
Bah Mamadou Lamine Malick ◽  
Hiroaki Ishiga

<span style="font-size: 10.5pt; font-family: 'Times New Roman','serif'; mso-bidi-font-size: 10.0pt; mso-fareast-font-family: 宋体; mso-font-kerning: 1.0pt; mso-ansi-language: EN-US; mso-fareast-language: ZH-CN; mso-bidi-language: AR-SA;" lang="EN-US">Geochemistry of beach sand sediments collected from the Eastern San’in coast (n=17), Tango Peninsula (n=14) and Wakasa Bay (n=7) shorelines were investigated using XRF analyses for major and trace elements to characterize their composition, classification, maturity, provenance, tectonic setting and degree of weathering in source areas. Investigated sands from all sites were very similar showing depletion in all elements except SiO<sub>2</sub>, K<sub>2</sub>O and As relative to the UCCN and JUCN, suggesting a moderate geochemical maturation. Beach sand sediments from these locations can be classified as arkose, subarkose and litharenite that are chemically immature and formed under arid/semi-arid conditions with a tendency towards increasing chemical maturity suggesting that they are from multiple sources. The relatively low to moderate values of weathering indices of Chemical Index of Alteration (CIA), Plagioclase Index of Alteration (PIA) and Chemical Index of Weathering (CIW), the beach sands from all sites in the source area have undergone low to moderate degree of chemical weathering. A-CN-K and A-CNK-FM plots, which suggest a granitic source composition, also confirm that the sand samples from these sites have undergone low to moderate degree of chemical weathering in consistent with CIA, PIA and CIW values. A plot of the analyzed beach sands data on the provenance discriminating function F1/F2 showed that most of the investigated beach sand sediments in all locations fall within mafic to intermediate ocean island arc source; similar to the tectonic setting discrimination diagrams based on major elements suggesting a passive margin.</span>

2020 ◽  
Author(s):  
Hatice Nur Bayram ◽  
Asli Nur Uslu ◽  
Ali Erdem Bakkalbasi ◽  
Demet Kiran Yildirim ◽  
Zeynep Doner ◽  
...  

&lt;p&gt;&lt;strong&gt;Geochemical and mineralogical characteristics of beach sand sediments in southwestern Black Sea: An approach to heavy mineral placers &amp;#160;&lt;/strong&gt;&lt;/p&gt;&lt;p&gt;&lt;strong&gt;&amp;#160;&lt;/strong&gt;&lt;strong&gt;Hatice Nur Bayram (1*), Asl&amp;#305; Nur Uslu (1), Ali Erdem Bakkalba&amp;#351;&amp;#305; (1), Demet Kiran Yildirim (1), &lt;/strong&gt;&lt;strong&gt;Zeynep Doner (1), Ali Tugcan Unluer (1)&lt;/strong&gt;&lt;/p&gt;&lt;p&gt;&lt;strong&gt;&amp;#160;&lt;/strong&gt;(1) Istanbul Technical University, Faculty of Mines, Department of Geological Engineering, Istanbul, Turkey (*[email protected])&lt;/p&gt;&lt;p&gt;&lt;strong&gt;Abstract: &lt;/strong&gt;&lt;strong&gt;&amp;#160;&lt;/strong&gt;&lt;/p&gt;&lt;p&gt;Coastal or beach placer deposits are enrichments of heavy minerals with significant metal content that have been mechanically formed. This work studies the geochemical and mineralogical characteristics of beach sand sediments of southwestern Black Sea, Turkey which cover approximately 20 km&lt;sup&gt;2&lt;/sup&gt; area. The study area has 4 main geological units: Upper Cretaceous moderately-K kalkalkaline Istanbul volcanics, Oligocene Danismen Formation which is dominated by flood plain, marshy and lake environments, Upper Miocene-Pliocene Belgrad Formation which is dominated by terrestrial deposits, mostly gravel, sand and clay dominated and Quaternary formations which include sandy beaches, sand dunes and river alluvials.&lt;/p&gt;&lt;p&gt;A total of 8 beach sand samples were analyzed by X-ray Diffraction (XRD) and X-ray Fluorecance (XRF). Mineralogical compositions are mainly dominated by quartz, siderite, albite, calcite and minor amount of magnetite. Siderite-rich beach sands are observed in western part of the study area and mostly derived from Danismen Formation. Fe&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt; contents of this area are determined up to 40%. &amp;#160;On the other hand, in eastern part of the study area REE-Th-U content of beach sands are relatively higher than source rocks which is defined as a high-Al moderately-K kalkalkaline felsic rocks. The highest HFSE concentration were determined in -250+125&amp;#181;m fraction which consists of 16.5% of eastern beach sand. In this fraction LREE-Zr-U content rise drastically. It can be considered that REE-LREE contents is related with monazite minerals and U contents is related with zircon minerals, considering the monazite and zircon minerals are resistant to weathering and likely to occur in the orthomagmatic phase in the source volcanics.&lt;/p&gt;&lt;p&gt;&lt;strong&gt;Key words&lt;/strong&gt;: Beach sand sediments; REE-Th-U; heavy minerals; southwestern of Black Sea; Turkey&lt;/p&gt;


2021 ◽  
Vol 13 (1) ◽  
pp. 1187-1225
Author(s):  
Temitope Love Baiyegunhi ◽  
Kuiwu Liu ◽  
Oswald Gwavava ◽  
Christopher Baiyegunhi ◽  
Maropene Rapholo

Abstract An inorganic geochemical investigation of mudrocks and sandstone from the southern Bredasdorp Basin, off the south coast of South Africa was carried out to unravel the provenance, paleoweathering, and tectonic setting of the basin. Seventy-seven representative samples from exploration wells E-AH1, E-AJ1, E-BA1, E-BB1, and E-D3 underwent geochemical analysis involving major and trace elements. The major oxide compositions show that the sandstones could be classified as sub-arkose and sub-lithic arenite. The provenance discrimination diagrams based on major oxide geochemistry revealed that the sandstones are mainly of quartzose sedimentary provenance, while the mudrocks are of quartzose sedimentary and intermediate igneous provenances. The discrimination diagrams indicate that the Bredasdorp sediments were mostly derived from a cratonic interior or recycled orogen. The bivariate plots of TiO2 versus Ni, TiO2 against Zr, and La/Th versus Hf as well as the ternary diagrams of V–Ni–Th∗10 suggest that the mudrocks and sandstones were derived from felsic igneous rocks. The tectonic setting discrimination diagrams support passive-active continental margin setting of the provenance. Also, the closely similar compositions of the analysed samples and recent sedimentary rocks of the East African Rift System perhaps suggest a rifted basin tectonic setting for the Bredasdorp Basin. Chemical index of alteration (CIA) indices observed in the sandstones suggest that their source area underwent low to moderate degree of chemical weathering. However, the mudrocks have high CIA indices suggesting that the source area underwent more intense chemical weathering, possibly due to climatic and/or tectonic variations.


2020 ◽  
Vol 18 ◽  
pp. 97-118
Author(s):  
Nathaniel Odoma Atabo ◽  
Ojochogwu Idakwo Sunday

Two basins (Southern Bida and Northern Anambra Basins) were investigated to deduce weathering, paleooxygenation, provenance, depositional environment and tectonic setting, as well as to establish a relationship between the two basins. The obtained high values of calculated weathering indices such as Chemical index of alteration (CIA > 90), Chemical Index of Weathering (CIW > 90), Plagioclase Index of Alteration (PIA > 90) and the Al2O3-(CaO + Na2O)-K2O ternary relationship for the clay – shale sediments from both basins indicate intense weathering in the source area. Important geochemical ratios such as V/Cr, Cu/Zn, Ni/Co, (Cu+Mo)/Zn, revealed predominantly oxic conditions for the clay – shale sediments from both basins, although, a more reducing or an anoxic condition cannot be ruled out for the clay – shale sediments from the Southern Bida basin due to high ratios of U/Th (1.93-5.67) and Cu/Zn (0.19-5.00). In addition, the Sr/Ba ratios (0.16–3.50) for the clay-shales from the Southern Bida basin indicated an alternated marine and continental paleo-depositional settings and only continental setting (Sr/Ba ratios = 0.22 – 0.50) for the Northern Anambra basin. The Th/Sc, La/Sc, Th/Co and the LREE/HREE ratios showed a derivation of the shale and clay deposits from similar felsic-rich source rock while the log of (K2O/Na2O) vs SiO2, revealed a Passive Margin tectonic setting for the two Basins. There is insignificant differences between the geochemical classifications, weathering, source rock/provenance and tectonic settings of clay-shale sediments of both sedimentary basins, however, there exist slight disparity in their salinity conditions and redox settings. Keywords: Geochemistry, Clay-shale, Provenance, Tectonic Setting, Northern Anambra and Southern Bida Basins


Minerals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1376
Author(s):  
Xiaoneng Luo ◽  
Ziying Li ◽  
Yuqi Cai ◽  
Chao Yi ◽  
Zilong Zhang ◽  
...  

In adjustment to fulfill the requirements of the investigation regarding the lower Cretaceous sandstone uranium deposit in the Naogaodai area within the northwest of Ordos Basin, twenty-seven sandstone samples obtained from the Lower Cretaceous Huanhe Formation were analyzed for major, trace and rare earth elements (REE). The source of clastic and tectonic background was additionally analyzed. The results show that Huanhe sandstone is feldspar rich sandstone, and also the mineral composition is principally quartz, albite and plagioclase; the ratio of light to heavy rare earth elements (LREE/HREE) is 9.25–10.83, with an average value of 10.00; (La/Yb)CN is 10.20–12.53, with an average value of 11.24, demonstrating that LREE is enriched and fractionated compared with HREE. REE distribution patterns are similar, which additionally reveals that Huanhe sandstone has a homogenous source; the Index of Compositional Variability (ICV) value is 1.17–1.73, with an average value of 1.35, both greater than 1, showing an immature property, which may be first-order cycle deposition. The average value of the Chemical Index of Alteration (CIA) is 50.29, suggesting that the source rock has encountered weak chemical weathering; sandstones are near-source first-cycle provenance, which is not significantly influenced by sedimentary sorting and recycling. The geochemical qualities further indicate that Huanhe sandstone was deposited in a passive margin and experienced moderate weathering.


2018 ◽  
Vol 156 (07) ◽  
pp. 1157-1174 ◽  
Author(s):  
NAJMEH ETEMAD-SAEED ◽  
MAHDI NAJAFI

AbstractThe Soltanieh Formation in the Alborz Mountains of northern Iran is not only a key lithostratigraphic unit for reconstruction of the Iranian geological history, but also a globally outstanding succession to reveal variations in seawater composition across the Precambrian–Cambrian (PC–C) transition. Mineralogical and geochemical data from a continuous stratigraphic record of Lower and Upper Shale members of the Soltanieh Formation are used to define their provenance, tectonic setting as well as geochemical variations during the PC–C transition. The Soltanieh mudrocks are composed of quartz and plagioclase, with minor constituents of illite, chlorite and montmorillonite. The chemical index of alteration, A-CN-K (Al2O3 – CaO + Na2O – K2O) relations, index of compositional variability, and Th/Sc versus Zr/Sc ratios indicate low chemical weathering in source areas, compositionally immature and first-cycle sediments. Immobile trace-element ratios and discrimination diagrams, chondrite-normalized rare Earth element (REE) patterns and negative Eu anomaly, along with low total REE abundances and negligible Ce anomalies, demonstrate that the Soltanieh Formation was mainly derived from proximal felsic-intermediate Cadomian magmatic arc sources and deposited in a continental-arc-related basin on the proto-Tethyan active margin of Gondwana. The palaeoredox indicators exhibit a remarkable change in environmental condition from a suboxic to an oxic state across the PC–C transition from the Kahar Formation to the Upper Shale Member of the Soltanieh Formation. Moreover, a significant upwards increase of P, Ba, and Ca is likely associated with enhanced fluxes of nutrient elements during the PC–C transition, coeval with the building of collisional mountain belts during the amalgamation of Gondwana.


Author(s):  
Nura Abdulmumini Yelwa ◽  
Khairul Azlan Mustapha ◽  
Mimonitu Opuwari ◽  
Azharuddin Abd Aziz

AbstractAptian to Campanian sediments from the Western offshore to Central Orange Basin were studied by integrating molecular geochemistry, inorganic and isotopic studies to recognize their geochemical characteristics via the reconstruction of the Orange basin’s paleoweathering, paleosalinity, paleovegetation, paleoclimate, and tectonic records. Molecular analyses of both aliphatic and aromatic compounds reveal an input dominantly from a marine source. The source rocks accumulated in a reduced, anoxic, saline water column. Based on various biomarker proxies and vitrinite reflectance data, some samples are thermally mature to produce petroleum, while others are not. According to the V/Ni ratio, samples from the Orange Basin in South Africa are mainly anoxic, with only a few samples ranging from suboxic to anoxic. This is congruent with biomarker and isotope analyses that further indicate the presence of marine-derived source rocks with some terrestrial remains generating hydrocarbons. The investigated sediments are made up of intermediate igneous rocks that have undergone moderate chemical weathering. Geochemical figures on tectonic setting discriminant function diagrams revealed a continental rift of passive margin settings. As a result, the extrapolated crustal processes are directly analogous to the genesis and evolution of the Orange Basin, demonstrating Gondwana’s breaking up and the opening of the Atlantic Ocean Margin.


2017 ◽  
Vol 64 (1) ◽  
pp. 35-52 ◽  
Author(s):  
Emmanuel E. Adiotomre ◽  
Innocent O. Ejeh ◽  
Edwin O. Adaikpoh

Abstract Geochemical analysis of fluvial sediments on the banks of River Ero using inductively coupled plasma mass spectrometry illustrates their maturity, provenance and tectonic setting. The analysed sediment samples show low SiO2/Al2O3 ratios of 2.92-2.99 (units FL_A, FL_B and FL_E) and high SiO2/Al2O3 ratios of 4.064-4.852 (units FL_C, FL_D, FL_F and FL_G). Sediments were geochemically classified as shales (units FL_A, FL_B and FL_E) and greywackes (units FL_C, FL_D, FL_F and FL_G). Variability in sediment maturity (FL_F > FL_G >FL_C >FL_D >FL_A > FL_B > FL_E) parallels a decreasing order in the ratios of SiO2/Al2O3 and K2O/Al2O3, as well as the proportion of quartz grains and matrix components. Evidence from Al2O3/TiO2, K2O, Rb, La/Co, Th/Co, Cr/ Th, Th/Cr, La/Th-Hf, Th-Hf-Co and rare earth element contents of sediment samples suggest felsic protoliths of upper continental crust in a passive margin tectonic setting. An insignificant contribution of mafic components from the source is, however, inferred based on the Ni and Cr contents of the sediment samples. Combined Eu anomalies <0.85 and (Gd/Yb)n ratios <2.0 (1.53- 1.82, average 1.65) suggest post-Archean protoliths.


2021 ◽  
pp. M55-2018-40
Author(s):  
Malcolm J. Hole

AbstractScattered occurrences of Miocene–Recent volcanic rocks of the alkaline intraplate association represent one of the last expressions of magmatism along the Antarctic Peninsula. The volcanic rocks were erupted after the cessation of subduction which stopped following a series of northward-younging ridge crest–trench collisions. Volcanism has been linked to the development of a growing slab window beneath the extinct convergent margin. Geochemically, lavas range from olivine tholeiite through to basanite and tephrite. Previous studies have emphasized the slab-window tectonic setting as key to allowing melting of peridotite in the asthenospheric void caused by the passage of the slab beneath the locus of volcanism. This hypothesis is revisited in the light of more recent petrological research, and an origin from melting of subducted slab-hosted pyroxenite is considered here to be a more viable alternative for their petrogenesis. Because of the simple geometry of ridge subduction, and the well-established chronology of ridge crest–trench collisions, the Antarctic Peninsula remains a key region for understanding the transition from active to passive margin resulting from cessation of subduction. However, there are still some key issues relating to their tectonomagmatic association, and, principally, the poor geochronological control on the volcanic rocks requires urgent attention.


1992 ◽  
Vol 6 ◽  
pp. 155-155
Author(s):  
Kotaro Kamada

Before opening of the Japan Sea, the Japanese islands were attached to the eastern margin of the Asian continent. The Southern Kitakami Belt is regarded as a micro-continent in an accretional complex of the islands, that accreted before the Early Cretaceous. But its tectonic setting and location between the belt and the Asian continent is still an unresolved argument.Permo-Triassic sequences in the Southern Kitakami Belt are composed of shallow to off-shore deposits. These deposits are composed of clastics, carbonates with volcaniclastics. But there was no volcanic activity in the belt in the Middle to Late Permian. From the viewpoint of the sedimentary character and history, the Middle Permian to Middle Triassic sequences differ from their previous and their following successions in the belt. And the sedimentary basin of Middle Permian to Middle Triassic was bounded by transform faults. Magmatic arc was replaced by passive margin as hinterland of the Southern Kitakami Belt during the Middle Permian to Middle Triassic. It means that the sedimentary basin moved from the margin of Yangtze Platform to Sino-Korean Platform at that time.


2019 ◽  
Vol 7 (2) ◽  
pp. T525-T545
Author(s):  
Yaxiong Sun ◽  
Wenlong Ding ◽  
Yang Gu ◽  
Gang Zhao ◽  
Siyu Shi ◽  
...  

Redbeds with a large thickness in the lower Cretaceous record abundant geologic information in the Minle Basin. We have conducted the paleoweathering conditions, provenance, and tectonic settings based on mineralogy and geochemistry. Our results indicate that mudstone samples are characterized by abundant illite with negligible amounts of K-feldspars and analcime. The lower part of the lower Cretaceous is rich in quartz, whereas the upper part is dominated by dolomite and analcime. We suggest that this is caused by the decreasing input of the clastic influx during the middle-late early Cretaceous. High index of compositional variation values (average 1.33) indicate first-cycle sediment supply, suggesting an overall compositional immaturity and short-distance transportation. These characteristics are consistent with an active regional extension tectonic setting. The [Formula: see text] system ([Formula: see text];[Formula: see text];[Formula: see text]) and Th/U versus Th consistently reveal that the lower Cretaceous experienced a positive gradient in chemical weathering from young to old formations. Although the patterns of trace elements in three formations of the lower Cretaceous are different, those of the rare earth elements (REEs) tend to be consistent. The significant enrichment of light REEs, heavy REEs fractionation, and distinctive negative Eu anomalies suggest derivation from an old, upper continental crust composed of predominantly felsic sediments. This interpretation is supported by several discrimination diagrams such as titanium dioxide-nickel ([Formula: see text]), which shows the characteristics of immature recycled sediments. A few sensitive elements, ratios, and normalized REE patterns indicate a provenance of an active continental margin and a continental island arc (CIA). The La-Th-Sc, Th-Co-Zr/10, and Th-Sc-Zr/10 discrimination plots further confirm the CIA signature. Thus, we conclude that the early Cretaceous redbeds in the Minle Basin, Hexi Corridor, were deposited in a dustpan-shaped half-graben basin in a CIA setting when northwest China was influenced by intense regional extension.


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