The Kaolinite Crystallinity and Influence Factors of Coal-Measure Kaolinite Rock from Datong Coalfield, China

In order to ascertain the kaolinite crystallinity of Carboniferous Permian coal-measure kaolinite rocks, seven groups of fresh samples were collected from below the ground in the Xiaoyu mine, Datong coalfield. Microscopy, X-ray diffraction (XRD), differential thermal analysis (DTA), infrared (IR) spectroscopy and X-ray fluorescence (XRF) spectrometry methods were applied to the samples. The petrographic analysis results show that the kaolinite rocks are characterized as compact, phaneritic, clastic, sand-bearing, sandy and silty types; the kaolinite content in the Shanxi formation and upper Taiyuan formations was more than 95%, while it was 60–90% in the middle and lower Taiyuan formations. Based on the Hinckley index and the features of XRD, DTA and IR of kaolinites, crystallinity was classified as having three grades: ordered, slightly disordered and disordered. The kaolinites’ SiO2 /Al2O3 molar ratio was about 1.9–5.7, with a chemical index of alteration (CIA) of about 95.4–99.5. This research suggests that the kaolinite crystallinity correlates positively to its clay mineral content, purity and particle size, which are also related to the SiO2/Al2O3 molar ratio and CIA. The original sedimentary environment and weathering have a direct influence on kaolinite crystallinity, and the existence of organic matter is conducive to the stable existence of kaolinite. The study results have significance for the extraction and utilization of coal-measure kaolinite and the development of kaolinite crystallography and mineralogy.

The Role of New-Emerging Lands on Sources of Aeolian Sand Deposits Driven by Shrinking of the Urmia Salt Lake

Urmia Lake, the largest saline lake in Iran and the Middle East, is located in the northwest of Iran, has shrunk over the past decades. The reduced water level has increased the area of dry land around the lake allowing new environmental hazard such as sand dunes encroachment, particularly on the western side of the lake. There are five terrain types that could contribute sediment to the dunes, and it is the main aim of this research to identify the contributions to the dunes of each terrain type. Fifteen surface samples were collected from the five most erodible terrain types and eight samples were collected from the dunes both in downwind and upwind directions from the lake, and major element components were measured using X-ray fluorescence (XRF). According to the Besler classification, all samples are in the saline class. Also, the chemical index of alteration (CIA) values in all samples were less than 50, indicating weak weathering. Based on multivariate statistical analysis, suitable tracers were selected and were imported to the sourcing equations. Quantification of uncertainty and the creation of two new fingerprinting models for aeolian sediments based on both Bayesian and GLUE procedures were used. The highest proportion comes from the salty and puffy lands (44.2%) followed by salty polygon land (23.5%), clay-salty areas, puffy-flaky lands (7.01%), the terminus of the fine sandy alluvial fan (13.2%), and clay-salty abandoned lands (12.1%). It is concluded that if land managers use these results, they can more efficiently decrease the hazards posed by dune reactivation and migration though implementation of soil conservation on the affected lands around the dried lake.

Geochemical Maturity and Paleo-Weathering Indices of Sedimentary Succession in JV Field Greater Ughelli Depo-Belt Niger Delta Basin

This study evaluates the geochemical maturity and paleo weathering indices of X well JV-Field, Greater UghelliDepo belt Niger Delta Basin, using reflected light microscope and geochemical proxies. The data obtained identified three lithofacies units as Sand, Shale, and Shaly sand facies .The application of source area weathering using Chemical index of alteration (CIA) and Chemical index of weathering (CIW) values for the sampled intervals ranges from (48.6-94.9%) and (60.6-96.7%), and have median values of (83.2 and 90.3) % respectively which is an indication of high weathering at the source. The values are variable and it may be as a result of multiple provenances of the sediments which have variable proportions of source area weathering and related processes or may be due to low concentrations of the alkalis and alkaline earth elements. However, all the samples excluding one with depth (12430ft) show CIA and CIW values greater than 70% indicating high (intensive) weathering either at the source or during transportation before deposition .From the high alteration indices value recorded from the sampled intervals, it can be inferred that the sediments are geochemically and texturally mature.

Geochemistry and mineralogy of the Truc Thon Clay, Hai Duong Province, North Vietnam: implication for paleoclimatic and provenance analysis

During the Miocene-Pleistocene, generally sub-tropical to tropical warm and humid paleoclimate prevailed in Southeast Asia with a gradual cooling trend. The Truc Thon clay (TTC) mine presents interesting outcrops for sedimentological and provenance analysis. The present study uses results of geological investigation in 16 outcrops and wells at the clay mine Truc Thon. The TTC has lens-shaped geometry, filled with two clay bodies, including grey-white clay and multicolor clay. Bulk mineralogy indicates the predominance of quartz and a relatively high amount of pyrophyllite. Clay mineralogy shows the presence of main kaolinite, followed by illite and mixed-layer illite-smectite. These may interpret a warm, humid paleoclimatic condition in the source areas. Illite may be inherited from basement rocks. The bulk rock geochemistry supports intense chemical weathering with the Chemical Index of Alteration (CIA) in the TTC ranged ca. 80.6-98 (average = 90.4). In combination with the geochemical proxies and the mineralogical composition of the TTC, the chemical weathering intensity indicated warm/hot, semi-humid/humid tropical paleoclimate in the source area. A combination of mineralogical and geochemical analyses with regional geological features show that the Hon Gai Triassic rocks are the main source for the TTC. Source materials are originally related to silicic rocks of granitic-granodioritic composition. Paleoclimatic conditions favored intense chemical weathering of the Hon Gai Triassic rocks and surrounding rocks, creating a ceramic mine of great industrial value.

Potassium-metasomatism in Anthracite: A Cluster of Geochemical Evidences

The present study focuses on the inorganic geochemical features of the bituminous coal samples from the Raniganj and the Jharia Basin, as well as the anthracite samples from the Himalayan fold-thrust belts of Sikkim, India. The SiO2 content (48.05 to 65.09 wt% in the ash yield of the bituminous coal samples and 35.92 to 50.11 wt% in the ash yield of the anthracite samples) and the ratio of Al2O3/TiO2 (6.97 to 17.03 in the bituminous coal samples and 10.34 to 20.07 in the anthracite samples) reveal the intermediate igneous source rock composition of the minerals. The ratio of the K2O/Al2O3 in the ash yield of the bituminous coal samples (0.03 to 0.09) may suggest the presence of kaolinite mixed with montmorillonite, while its range in the ash yield of the anthracite samples (0.16 to 0.27) may imply the presence of illite mixed with kaolinite. The chemical index of alteration values may suggest the moderate to strong chemical weathering of the source rock under sub-humid to humid climatic conditions. The plot of the bituminous coal samples in the A-CN-K diagram depicts the traditional weathering trend of parent rocks, but the anthracite samples plot near the illite field and are a bit offset from the weathering trend. This may imply the plausible influences of the potassium-metasomatism at post coalification stages. The Fourier transform infrared spectra further reveal the hydroxyl stretching intensity of the illite in the anthracite samples substantiating the effect of the epigenetic potassium-metasomatism. The decrease in total kaolinite intensity/compound intensity of quartz and feldspar may provide additional evidence towards this epigenetic event.

Geochemistry of Onshore Deposits From Rio-Del-Rey Sub-Basin of The Western Atlantic Margin of Cameroon (Coastal Basin, South West Cameroon): Provenance And Environments of Sedimentation

The Rio del Rey Basin belongs to the coastal basins of Cameroon with Cretaceous to Cenozoic deposits. The Cretaceous (Cenomanian and Campanian-Maastrichtian) and Cenozoic (Paleocene) sediments were studied using major and trace elements geochemistry associated with mineralogical data. The studied samples are mainly made up of Fe-shale and shale with rare intercalations of Fe-sand in the Cenomanian deposits, Fe-shale and shale in the Campanian-Maastrichtian deposits and sub-litharenite, Fe-sand, shale and Fe-shale in the Paleocene deposits. These samples contain high LREE/HREE ratios (9.27 -24.23), no to slight positive Eu anomalies (Eu/Eu*= 1.02 – 1.44), moderate to high Al2O3/TiO2 (10.42 – 112.93) ratio and their position in the Ce vs. La/Yb, Zr vs. TiO2 and La/Sc vs. Th/Co diagrams indicate that they derivate from mainly felsic associated with subordinate intermediate igneous rocks. The CIA (Chemical Index of Alteration; 61.69 – 92.76), PIA (Plagioclase Index of Alteration; 62.16 – 99.47), K2O/Na2O ratios (0.08 – 22.125) and Zr/Sc vs. Th/Sc diagram suggest the source rocks have experienced low to high recycling and weathering (Paleocene deposits), high chemical weathering (Campanian-Maastrichtian) and moderate to high chemical watering (Cenomanian deposits). The SiO2 vs. Al2O3 + K2O + Na2O plot suggests a predominant semi-arid to arid climate with periodically semi-humid climate during the Paleocene, attested by the evolution of the clay minerals composition with association of illite-chlorite/vermiculite/kaolinite in the Cenomanian sediments and periodic appearance of siderite in the Campanian-Maastrichtian and Paleocene deposits. The Sr/Ba (0.41 – 2) and U/Th (0.16 – 0.28) ratios indicate brackish to shallow marine environment of deposition. The Arc-Rift-Collision of two sets of high and low silica rocks and SiO2 vs. K2O/Na2O diagrams indicate a Collisional or Active Continental Margin tectonic setting similar as the Cretaceous (Lower Mundeck and Logbadjeck Formation) and Paleocene (Nkapa Formation) deposits from the Douala sub-basin, which could reflect the Precambian basement history linked to the Neoproterozoic orogeny.

Geochemical Characteristics of the Campano-Maastrictian Sediments of the Anambra Basin, Southeastern Nigeria - Implication For Provenance, Paleodepositional Environment, Maturity and Tectonic Setting

The present study investigates the Anambra Basin shales to determine the provenance and maturity of the sediments using standard geochemical techniques. Twelve (12) representative samples recovered from shale sequences of The Mamu Formation and Nkporo Group of The Anambra Basin were studied to determine the sediment provenance, paleoenvironment, diagenetic conditions, maturity as well as the tectonic setting. To consider in detail and establish the inherent constituents of the Major minerals, Trace and Rare Earth elements, Inductively Coupled Plasma Mass Spectrometry (ICP-MS) analyses techniques was employed. The detrital minerals determined are Al2O3 (18.27% and 21.16%), TiO2 (1.73% and 1.63%) and Fe2O3 (2.78% \ and 2.85%), for Nkporo Group and Mamu Formation respectively. The enrichment of SiO2, Al2O3 and TiO2 (1.14, 1.94, 3.67 respectively) supported by Chemical Index of Alteration (CIA) of 93.54 & 39.55 and Rb/Sr ratio of 0.57 & 0.40, indicate that the Anambra Basin sediments are matured. TiO2/AL2O3 binary plots, Th/Co Vs La/Sc crossplots, Th-Sc-Zr triplots and Cr, Ni concentration suggest mixed provenance of felsic to mafic source rocks for these sediments. From the log (K2O/Na2O) Vs SiO2 crossplots, a passive margin tectonic setting was determined for these sediments.

Provenance of sediments from Barra del Tordo and Tesoro beaches, Tamaulipas State, northwestern Gulf of Mexico

The mineralogy, bulk sediment geochemical composition, and U–Pb ages of detrital zircons retrieved from the Barra del Tordo (Tordo) and Tesoro beach sediments in the northwestern Gulf of Mexico were analyzed to determine their provenance. The beach sediments are mainly composed of quartz, ilmenite, magnetite, titanite, zircon, and anorthite. The weathering proxies such as the Chemical Index of Alteration (CIA), Chemical Index of Weathering (CIW), and Plagioclase Index of Alteration (PIA), reveal a moderate-to-high intensity of weathering in the source area. The chondrite-normalized rare earth element (REE) patterns are similar to felsic igneous rocks, with large negative europium anomaly (Eu/Eu* = ~ 0.47–0.80 and ~ 0.57–0.67 in the Tordo and Tesoro beach sediments, respectively).Three major zircon U–Pb age groups are identified in the Tordo and Tesoro beach sediments, i.e., Proterozoic (~ 2039–595 Ma), Mesozoic (~ 244–70.3 Ma), and Cenozoic (~ 65.9–1.2 Ma). The differences of the zircon age spectrum between the Tordo and Tesoro beach sediments are not significant. The comparison of zircon U–Pb ages in this study with ages of potential source terranes suggests that the Mesozoic and Cenozoic zircons of the studied Tordo and Tesoro beach sediments were derived from the Eastern Alkaline Province (EAP) and Mesa Central Province (MCP). Similarly, the likely sources for the Proterozoic zircons were the Sierra Madre Oriental (SMOr) and Oaxaquia in the northwestern Gulf of Mexico. The results of this study further indicate that the sediments delivered to the beaches by rivers and redistributed by longshore currents were crucial in determining the sediment provenance.

Pedological trends and implications for forest productivity in a Holocene soil chronosequence, Calvert Island, British Columbia, Canada.

Chronosequence studies of soil formation and ecosystem development provide important insights into the pathways and rates of change occurring on centennial and millennial time scales. In cool or temperate humid environments, Podzols are the predominant soil type formed under coniferous forests in coarse-textured parent material and have been a major focus of chronosequence studies. This study examined the rate and mechanisms of Podzol development and related forest productivity in a sand dune chronosequence in a hypermaritime climate in coastal British Columbia (BC). The sequence spans 10,760 ± 864 years over eight sites and is the first documented chronosequence in coastal BC to span most of the Holocene Epoch. Soil samples from each genetic horizon were analyzed for bulk density, pH and concentrations of total carbon (C), pyrophosphate- and oxalate-extractable aluminum (Al) and iron (Fe), and total elements. Within ~3,500 years a mature Podzol had formed, with cemented horizons (ortstein and placic) present. Organo-metallic complexation appeared to be the dominant mechanism involved in podzolization . Despite a mild, moist climate conducive to chemical weathering, all soils had similarly low values for the Chemical Index of Alteration, suggesting that congruent dissolution of primary minerals may be occurring. Ecosystem retrogression is apparent in the latter stages of the chronosequence – a phenomenon not previously documented in coastal BC. Further research is needed to examine the interactions of nutrient limitation, soil physical barriers, and other possible drivers of ecosystem retrogression.

Geochemical and Petrographical Characteristics of the Madzaringwe Formation Coal, Mudrocks and Sandstones in the Vele Colliery, Limpopo Province, South Africa: Implications for Tectonic Setting, Provenance and Paleoweathering

The sedimentary rocks of the Madzaringwe Formation in the Tuli Basin have been investigated using geochemical and petrographic methods to reveal their source area composition, tectonic setting, provenance and paleoweathering conditions. The petrographic studies show that the rocks consist mostly of clay minerals and quartz. The major elements geochemistry indicates that the rocks of the Madzaringwe Formation have the same source area. Based on the discriminant function plots, it can be inferred that the rocks are of quartzose sedimentary provenance, suggesting that they were derived from a cratonic interior or recycled orogen. The binary plots of TiO2 versus Zr and La/Sr against Th/Co shows that the rocks were derived from silicic or felsic igneous rocks. The tectonic setting discrimination diagrams of SiO2 against Log (K2O/Na2O), Th–Sc–Zr/10, and TiO2 versus (Fe2O3 + MgO) support passive-active continental margin settings of the provenance. The A–CN–K (Al2O3–CaO + Na2O–K2O) ternary diagram and binary plot of the index of compositional variability (ICV) against chemical index of alteration (CIA) shows that the rocks have been subjected to moderate to intensive weathering. Geochemical and petrographic characteristics of the rocks point to uplifted basement source areas predominantly composed of sedimentary rocks and/or granite-gneiss rocks. These source areas might have been from adjacent areas near the Tuli coalfield which include the Limpopo Belt (igneous and sedimentary rocks), and basement uplifted rocks of the Beit-Bridge Complex, consisting of the granite, granite-gneisses and schists.