Solid-state 119Sn NMR and M¨ossbauer Spectroscopic Studies of the Intermediate-valent Stannide CeRuSn

The ternary stannide CeRuSn is a static mixed-valent cerium compound with an ordering of trivalent and intermediate-valent cerium on two distinct crystallographic sites. 119Sn Mössbauer spectra showed two electronically almost identical tin atoms at 323 K, while at 298 K and below (77 and 4:2 K) two tin sites can clearly be distinguished. Solid-state 119Sn NMR experiments were performed to probe the local hyperfine fields at the two different Sn sites. Powder 119Sn NMR spectra are nicely fitted with two Sn sites with nearly the same magnetic anisotropy, but with different absolute shift values. Both Sn sites are strongly affected by crossover-like transitions between 100 and 280 K. This local-site study confirms the superstructure modulations found in previous investigations. Towards lower temperatures the powder NMR spectra are broadened giving strong precursor evidence for the antiferromagnetically ordered ground state.

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Spectroscopic Studies with N-Chloroarylsulphonamides: IR and 1H, 13C and 23Na Nmr Spectra of Sodium Salts of N-Chloro-Mono- and Di-Substituted-Benzenesulphonamides, 4-X-C6H4SO2NANCl (X = H; CH3; C2H5; F; Cl; Br; I or NO2) and i-X, j-YC6H3SO2NANCl (i-X, j-Y = 2,3-(CH3)2; 2,4-(CH3)2; 2,5-(CH3)2; 2-CH3, 4-Cl; 2-CH3, 5-Cl; 3-CH3, 4-Cl; 2,4-Cl2 or 3,4-Cl2)

Zeitschrift für Naturforschung A ◽

10.1515/zna-2003-0108 ◽

2003 ◽

Vol 58 (1) ◽

pp. 51-56 ◽

Cited By ~ 10

Author(s):

◽

J. D. D’Souza ◽

B. H. Arun Kumar

Keyword(s):

Solid State ◽

Chemical Shift ◽

Infrared Spectra ◽

Phenyl Ring ◽

Nmr Spectra ◽

Chemical Shifts ◽

Spectroscopic Studies ◽

Sodium Salts ◽

Experimental Chemical Shift ◽

23Na Nmr

In an effort to introduce N-chloroarylsulphonamides of different oxydising strengths, sixteen sodium salts of N-chloro-mono- and di-substituted benzenesulphonamides of the configuration, 4- X-C6H4SO2NaNCl (where X = H; CH3; C2H5; F; Cl; Br; I or NO2) and i-X, j-YC6H3SO2NaNCl (where i-X, j-Y = 2,3-(CH3)2; 2,4-(CH3)2; 2,5-(CH3)2; 2-CH3,4-Cl; 2-CH3,5-Cl; 3-CH3,4-Cl; 2,4- Cl2 or 3,4-Cl2) are prepared, characterized through their infrared spectra in the solid state and NMR spectra in solution. The υN-Cl frequencies vary in the range 950 - 927 cm−1. Effects of substitution in the benzene ring in terms of electron donating and electron withdrawing groups have been considered, and conclusions drawn. The chemical shifts of aromatic protons and carbon-13 in all the N-chloroarylsulphonamides have been calculated by adding substituent contributions to the shift of benzene. Considering the approximation employed the agreement between the calculated and experimental chemical shift values for different protons or carbon-13 is quite good. Effects of phenyl ring substitution on chemical shift values of both 1H and 13C are also graphically represented in terms of line diagrams.

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On the assignment of 119Sn resonances of bis[dicarboxylatotetraorganodistannoxanes] in solution and solid state 119Sn NMR spectra

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(97)00569-x ◽

1998 ◽

Vol 552 (1-2) ◽

pp. 177-186 ◽

Cited By ~ 35

Author(s):

François Ribot ◽

Clément Sanchez ◽

Abdelkrim Meddour ◽

Marcel Gielen ◽

Edward R.T Tiekink ◽

...

Keyword(s):

Solid State ◽

Nmr Spectra ◽

119Sn Nmr

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Spectroscopic studies of some Pd(II), Pt(II), Ag(I), and Au(III) complexes of 4,6-diamino-2-thiopyrimidine and 4,6-diamino-2-methylthiopyrimidine. Structure and binding site determination

Canadian Journal of Chemistry ◽

10.1139/v88-042 ◽

1988 ◽

Vol 66 (2) ◽

pp. 249-255 ◽

Cited By ~ 20

Author(s):

M. D. Gutiérrez ◽

R. López ◽

M. A. Romero ◽

J. M. Salas

Keyword(s):

Magnetic Susceptibility ◽

Solid State ◽

Nmr Spectra ◽

Spectroscopic Studies ◽

Spectroscopic Techniques ◽

Conductivity Measurements ◽

Sulphur Atom ◽

H Nmr ◽

Ring Nitrogen ◽

Ring Nitrogen Atom

Interaction of Pd(II), Pt(II), Ag(I), and Au(III) with 4,6-diamino-2-thiopyrimidine (DATP) and 4,6-diamino-2-methyl-thiopyrimidine (DAMTP) in aqueous medium resulted in the formation of new complexes which have been characterized by elemental analysis, ir, 1H-nmr spectroscopic techniques, magnetic susceptibility measurements in the solid state, and conductivity measurements in DMF solution. The ir and 1H-nmr spectra were consistent with coordination involving the non-protonated ring nitrogen atom, the exocyclic sulphur atom, or N,S-chelation.

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Study of structure of bis(triphenylstannyl) chromate(VI) by infrared, Mössbauer, and 1H, 13C and 119Sn NMR spectra

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19841497 ◽

1984 ◽

Vol 49 (6) ◽

pp. 1497-1504 ◽

Cited By ~ 3

Author(s):

Karel Handlíř ◽

Jaroslav Holeček ◽

Milan Nádvorník ◽

Antonín Lyčka ◽

Milan Hucl

Keyword(s):

Solid State ◽

Molecular Complex ◽

Equatorial Plane ◽

Nmr Spectra ◽

Three Dimensional ◽

119Sn Nmr ◽

Bridge Oxygen ◽

The Common ◽

Ester Molecule ◽

Oxygen Atoms

The infrared, Mössbauer, and 1H, 13C and 119 Sn NMR spectra have been used to study the structure of bis(triphenylstannyl) chromate(VI) in solid state and in solvents of both noncoordinating and coordinating types. In solid state the compound forms a three-dimensional polymer: the tetrahedral CrO4 group and trans-trigonally bipyramidal (C6H5)3SnO2 grouping are connected mutually symmetrically by bridges represented by the common oxygen atoms. The three phenyl groups in the (C6H5)3SnO2 grouping are located in the equatorial plane of the trigonal bipyramide which is completed by two bridge oxygen atoms in axial positions. Solutions in noncoordinating solvents contain monomeric bis(triphenylstannyl) chromate(VI). The ester molecule contain two tetrahedral, (C6H5)3SnO groups bound by oxygen bridges to a CrO4 group which shows the C2v symmetry. In coordinating solvents the title compound forms a molecular complex having the coordination number 5 at the central tin atom.

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IR and 13C, 17O, and 119Sn NMR spectra of some bis(1-butyl)tin(IV) carboxylates of dicarboxylic acids

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19911908 ◽

1991 ◽

Vol 56 (9) ◽

pp. 1908-1915 ◽

Cited By ~ 18

Author(s):

Jaroslav Holeček ◽

Antonín Lyčka ◽

Milan Nádvorník ◽

Karel Handlíř

Keyword(s):

Infrared Spectroscopy ◽

Nmr Spectroscopy ◽

Dicarboxylic Acid ◽

Nmr Spectra ◽

Dicarboxylic Acids ◽

119Sn Nmr ◽

Carboxylic Groups ◽

Cyclic Oligomers ◽

The Media ◽

Oxygen Atoms

Infrared spectroscopy and multinuclear (13C, 17O, and 119Sn NMR spectroscopy have been used to study the structure of bis(1-butyl)tin(IV) carboxylates of dicarboxylic acids (1-C4H9)2. Sn(X(COO)2), where X = (CH2)n (n = 0-8), CH=CH (cis and trans) and C6H4 (ortho and para).The crystalline compounds are formed by linear or cyclic oligomers or polymers whose basic building units represent a grouping composed of the central tin atom substituted by two 1-butyl groups and coordinated with both oxygen atoms of two anisobidentate carboxylic groups derived from different molecules of a dicarboxylic acid. The environment of the tin atom has a shape of a trapezoidal bipyramid. When dissolvet in non-coordinating solvents, the compounds retain the oligomeric character with unchanged structure of environment of the central tin atom. In the media of coordinating solvents the bis(1-butyl)tin(IV) carboxylates of dicarboxylic acids form complexes whose central hexacoordinated tin atom binds two molecules of the solvent trough their donor atoms. Carboxylic groups form monodenate linkages in these complexes.

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Al/Ga-Doped Li7La3Zr2O12 Garnets as Li-Ion Solid-State Battery Electrolytes: Atomistic Insights into Local Coordination Environments and Their Influence on 17O, 27Al, and 71Ga NMR Spectra

Journal of the American Chemical Society ◽

10.1021/jacs.9b12685 ◽

2020 ◽

Vol 142 (6) ◽

pp. 3132-3148 ◽

Cited By ~ 2

Author(s):

Bora Karasulu ◽

Steffen P. Emge ◽

Matthias F. Groh ◽

Clare P. Grey ◽

Andrew J. Morris

Keyword(s):

Solid State ◽

Nmr Spectra ◽

Local Coordination ◽

Solid State Battery ◽

Li Ion

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Inkjet Printing of Polypyrrole Electroconductive Layers Based on Direct Inks Freezing and Their Use in Textile Solid-State Supercapacitors

Materials ◽

10.3390/ma14133577 ◽

2021 ◽

Vol 14 (13) ◽

pp. 3577

Author(s):

Zbigniew Stempien ◽

Mohmmad Khalid ◽

Marcin Kozanecki ◽

Paulina Filipczak ◽

Angelika Wrzesińska ◽

...

Keyword(s):

Solid State ◽

Inkjet Printing ◽

Surface Resistance ◽

Spectroscopic Studies ◽

Polymerization Temperature ◽

Textile Fabrics ◽

Symmetric Supercapacitor ◽

Novel Method ◽

A Current ◽

Standard Support

In this work, we propose a novel method for the preparation of polypyrrole (PPy) layers on textile fabrics using a reactive inkjet printing technique with direct freezing of inks under varying temperature up to −16 °C. It was found that the surface resistance of PPy layers on polypropylene (PP) fabric, used as a standard support, linearly decreased from 6335 Ω/sq. to 792 Ω/sq. with the decrease of polymerization temperature from 23 °C to 0 °C. The lowest surface resistance (584 Ω/sq.) of PPy layer was obtained at −12 °C. The spectroscopic studies showed that the degree of the PPy oxidation as well as its conformation is practically independent of the polymerization temperature. Thus, observed tendences in electrical conductivity were assigned to change in PPy layer morphology, as it is significantly influenced by the reaction temperature: the lower the polymerization temperature the smoother the surface of PPy layer. The as-coated PPy layers on PP textile substrates were further assembled as the electrodes in symmetric all-solid-state supercapacitor devices to access their electrochemical performance. The electrochemical results demonstrate that the symmetric supercapacitor device made with the PPy prepared at −12 °C, showed the highest specific capacitance of 72.3 F/g at a current density of 0.6 A/g, and delivers an energy density of 6.12 Wh/kg with a corresponding power density of 139 W/kg.

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