Manganese mobility in soils under the impact of alkaline dust emission

Author(s):  
Halina Dąbkowska-Naskręt ◽  
Hanna Jaworska
2019 ◽  
Vol 19 (17) ◽  
pp. 11199-11212 ◽  
Author(s):  
Ana Stojiljkovic ◽  
Mari Kauhaniemi ◽  
Jaakko Kukkonen ◽  
Kaarle Kupiainen ◽  
Ari Karppinen ◽  
...  

Abstract. We have numerically evaluated how effective selected potential measures would be for reducing the impact of road dust on ambient air particulate matter (PM10). The selected measures included a reduction of the use of studded tyres on light-duty vehicles and a reduction of the use of salt or sand for traction control. We have evaluated these measures for a street canyon located in central Helsinki for four years (2007–2009 and 2014). Air quality measurements were conducted in the street canyon for two years, 2009 and 2014. Two road dust emission models, NORTRIP (NOn-exhaust Road TRaffic Induced Particle emissions) and FORE (Forecasting Of Road dust Emissions), were applied in combination with the Operational Street Pollution Model (OSPM), a street canyon dispersion model, to compute the street increments of PM10 (i.e. the fraction of PM10 concentration originating from traffic emissions at the street level) within the street canyon. The predicted concentrations were compared with the air quality measurements. Both road dust emission models reproduced the seasonal variability of the PM10 concentrations fairly well but under-predicted the annual mean values. It was found that the largest reductions of concentrations could potentially be achieved by reducing the fraction of vehicles that use studded tyres. For instance, a 30 % decrease in the number of vehicles using studded tyres would result in an average decrease in the non-exhaust street increment of PM10 from 10 % to 22 %, depending on the model used and the year considered. Modelled contributions of traction sand and salt to the annual mean non-exhaust street increment of PM10 ranged from 4 % to 20 % for the traction sand and from 0.1 % to 4 % for the traction salt. The results presented here can be used to support the development of optimal strategies for reducing high springtime particulate matter concentrations originating from road dust.


2018 ◽  
Author(s):  
Ana Stojiljkovic ◽  
Mari Kauhaniemi ◽  
Jaakko Kukkonen ◽  
Kaarle Kupiainen ◽  
Ari Karppinen ◽  
...  

Abstract. We have evaluated numerically how effective a few selected measures would be for reducing road dust. The selected measures included the reduction of the use of studded tyres in light-duty vehicles and phasing-out of salt or sand in traction control. We have evaluated these measures for a street canyon location in central Helsinki, for four years (2007–2009 and 2014). Air quality measurements were conducted in the street canyon for two years, 2009 and 2014. Two road dust emission models, NORTRIP and FORE, were applied in combination with the street canyon dispersion model OSPM to compute the street increments of PM10 within the street canyon. The predicted concentrations were compared with the air quality measurements. Both models reproduced the seasonal variability of the PM10 concentrations but under-predicted the yearly mean values. It was found that the largest reductions of concentrations could potentially be achieved by reducing the fraction of vehicles that use studded tyres. For instance, a 30 % percent decrease in the number of vehicles using studded tyres would result in an average decrease of the non-exhaust increment of PM10 from 10 to 22 %, depending on the model used and the year considered. The corresponding decrease after removal of sanding and salting would be from 4 % and 20 % and from 0.1 % to 4 %, respectively. The results can be used for finding optimal strategies for reducing the high springtime particulate matter concentrations originated from road dust.


2004 ◽  
Vol 217 ◽  
pp. 114-115
Author(s):  
L. Montier ◽  
M. Giard

Recent observations at low and high redshift seem to confirm the presence of dust at very low abundances in the InterGalactic Medium (IGM) and especially in the IntraCluster Medium (ICM). We have studied the impact of this dust on the IGM, in terms of heating and cooling. on one hand, with an analytical model of dust emission, we have proved that the dust can be considered as the dominant cooling agent of the ICM at large scale, when the temperature is greater than T = 107 K. on the other hand, with a strong UV Background and a low temperature (Te ≤ 105 K), dust grains become an efficient heating agent of the IGM. These two opposite effects may have played an important role regarding structure formation of the Universe at large and small scales.


2012 ◽  
Vol 12 (21) ◽  
pp. 10209-10237 ◽  
Author(s):  
K. Wang ◽  
Y. Zhang ◽  
A. Nenes ◽  
C. Fountoukis

Abstract. The US Environmental Protection Agency's (EPA) Community Multiscale Air Quality (CMAQ) modeling system version 4.7 is further developed to enhance its capability in simulating the photochemical cycles in the presence of dust particles. The new model treatments implemented in CMAQ v4.7 in this work include two online dust emission schemes (i.e., the Zender and Westphal schemes), nine dust-related heterogeneous reactions, an updated aerosol inorganic thermodynamic module ISORROPIA II with an explicit treatment of crustal species, and the interface between ISORROPIA II and the new dust treatments. The resulting improved CMAQ (referred to as CMAQ-Dust), offline-coupled with the Weather Research and Forecast model (WRF), is applied to the April 2001 dust storm episode over the trans-Pacific domain to examine the impact of new model treatments and understand associated uncertainties. WRF/CMAQ-Dust produces reasonable spatial distribution of dust emissions and captures the dust outbreak events, with the total dust emissions of ~111 and 223 Tg when using the Zender scheme with an erodible fraction of 0.5 and 1.0, respectively. The model system can reproduce well observed meteorological and chemical concentrations, with significant improvements for suspended particulate matter (PM), PM with aerodynamic diameter of 10 μm, and aerosol optical depth than the default CMAQ v4.7. The sensitivity studies show that the inclusion of crustal species reduces the concentration of PM with aerodynamic diameter of 2.5 μm (PM2.5) over polluted areas. The heterogeneous chemistry occurring on dust particles acts as a sink for some species (e.g., as a lower limit estimate, reducing O3 by up to 3.8 ppb (~9%) and SO2 by up to 0.3 ppb (~27%)) and as a source for some others (e.g., increasing fine-mode SO42− by up to 1.1 μg m−3 (~12%) and PM2.5 by up to 1.4 μg m−3 (~3%)) over the domain. The long-range transport of Asian pollutants can enhance the surface concentrations of gases by up to 3% and aerosol species by up to 20% in the Western US.


2019 ◽  
Author(s):  
Jennie Bukowski ◽  
Susan C. van den Heever

Abstract. Along the coasts of the Arabian Peninsula, convective dust storms are a considerable source of mineral dust to the atmosphere. Reliable predictions of convective dust events are necessary to determine their effects on air quality, visibility, and the radiation budget. In this study, the Weather Research and Forecasting Model coupled with Chemistry (WRF-Chem) is used to simulate a 2016 summertime dust event over the Arabian Peninsula and examine the variability in dust fields and associated vertical transport due to the choice of convective parameterization and explicit versus parameterized convection. Simulations are run at 45 km and 15 km grid spacing with multiple cumulus parameterizations, and are compared to a 3 km simulation that permits explicit convective processes. Five separate cumulus parameterizations at 15 km grid spacing were tested to quantify the spread across different parameterizations. Finally, the impact these variations have on radiation, specifically aerosol heating rates is also investigated. On average, in these simulations the explicit case produces higher quantities of dust than the parameterized cases in terms of dust uplift potential, vertical dust concentrations, and vertical dust fluxes. Major drivers of this discrepancy between the simulations stem from the explicit case exhibiting higher surface windspeeds during convective activity, lower dust emission wind threshold velocities due to drier soil, and more frequent, stronger vertical velocities which transport dust aloft and increase the atmospheric lifetime of these particles. For aerosol heating rates in the lowest levels, the shortwave effect prevails in the explicit case with a net cooling effect, whereas a longwave net warming effect is present in the parameterized cases. The spread in dust concentrations across cumulus parameterizations at the same grid resolution (15 km) is an order of magnitude lower than the impact of moving from parameterized to explicit convection. We conclude that tuning dust emissions in coarse resolution simulations can only improve the results to first-order and cannot fully rectify the discrepancies originating from disparities in the representation of convective dust transport.


2020 ◽  
Vol 633 ◽  
pp. A47 ◽  
Author(s):  
V. Hocdé ◽  
N. Nardetto ◽  
E. Lagadec ◽  
G. Niccolini ◽  
A. Domiciano de Souza ◽  
...  

Context. The infrared (IR) excess of classical Cepheids is seldom studied and poorly understood despite observational evidence and the potential for its contribution to induce systematics on the period-luminosity (PL) relation used in the calibration of the extragalactic distance scale. Aims. This study aims to understand the physical origin of the IR excess found in the spectral energy distribution (SED) of 5 Cepheids: RS Pup (P = 41.46d), ζ Gem (P = 10.15d), η Aql (P = 7.18d), V Cen (P = 5.49d) and SU Cyg (P = 3.85d). Methods. A time series of atmospheric models along the pulsation cycle were fitted to a compilation of data, including optical and near-IR photometry, Spitzer spectra (secured at a specific phase), interferometric angular diameters, effective temperature estimates, and radial velocity measurements. Herschel images in two bands were also analyzed qualitatively. In this fitting process, based on the SPIPS algorithm, a residual was found in the SED, whatever the pulsation phase, and for wavelengths larger than about 1.2 μm, which corresponds to the so-determined infrared excess of Cepheids. This IR excess was then corrected from interstellar medium absorption in order to infer the presence (or absence) of dust shells and was, ultimately, used in order to fit a model for a shell of ionized gas. Results. For all Cepheids, we find a continuum IR excess increasing up to approximately −0.1 magnitudes at 30 μm, which cannot be explained by a hot or cold dust model of CircumStellar Environment (CSE). However, a weak but significant dust emission at 9.7 μm is found for ζ Gem, η Aql and RS Pup, while clear interstellar clouds are seen in the Herschel images for V Cen and RS Pup. We show, for the first time, that the IR excess of Cepheids can be explained by free–free emission from a thin shell of ionized gas, with a thickness of ≃15% of the star radius, a mass of 10−9−10−7M⊙ and a temperature ranging between 3500 and 4500 K. Conclusions. The presence of a thin shell of ionized gas around Cepheids must be tested with interferometers operating in the visible or mid-IR, or using radio telescopes. The impact of such CSEs of ionized gas on the PL relation of Cepheids also calls for further investigation.


2001 ◽  
Vol 372 (2) ◽  
pp. 406-426 ◽  
Author(s):  
H. Roussel ◽  
M. Sauvage ◽  
L. Vigroux ◽  
A. Bosma ◽  
C. Bonoli ◽  
...  

2012 ◽  
Vol 12 (5) ◽  
pp. 13457-13514 ◽  
Author(s):  
K. Wang ◽  
Y. Zhang ◽  
A. Nenes ◽  
C. Fountoukis

Abstract. The US Environmental Protection Agency (EPA)'s Community Multiscale Air Quality (CMAQ) modeling system version 4.7 is further developed to enhance its capability in simulating the photochemical cycles in the presence of dust particles. The new model treatments implemented in CMAQ v4.7 in this work include two online-dust emission schemes, nine dust-related heterogeneous reactions, an updated aerosol inorganic thermodynamic module ISORROPIA II with an explicit treatment of crustal species, and the interface between ISORROPIA II and the new dust treatments. The resulting improved CMAQ (referred to as CMAQ-Dust), offline-coupled with the Weather Research and Forecast model (WRF), are applied to the April 2001 dust storm episode over the trans-Pacific domain to examine the impact of new model treatments and understand associated uncertainties. WRF/CMAQ-Dust produces reasonable spatial distribution of dust emissions and captures the dust outbreak events, with the total dust emissions of ∼111 and 223 Tg when the erodible fraction is assumed to be 0.5 and 1.0, respectively, for the April 2001 episode. The model system can reproduce well observed meteorological and chemical concentrations, with significant improvements for suspended particulate matter (PM), PM with aerodynamic diameter of 10 μm and aerosol optical depth than default CMAQ v4.7. The sensitivity studies show that the inclusion of crustal species reduces the concentration of PM with aerodynamic diameter of 2.5 μm (PM2.5) over polluted areas. The heterogeneous chemistry occurring on dust particles acts as a sink for some species (e.g., as a lower limit estimate, O3 by up to 3.8 ppb (∼9%) and SO2 by up to 0.3 ppb (∼27%)) and as a source for some others (e.g., fine-mode SO42− by up to 1.1 μg m−3 (∼12%) and PM2.5 by up to 1.4 μg m−3 (∼3%) over the domain. The long-range transport of Asian pollutants can enhance the background concentrations of gases by up to 3% and aerosol species by up to 20% in the US.


2022 ◽  
Vol 924 (1) ◽  
pp. L9
Author(s):  
Sunao Hasegawa ◽  
Michaël Marsset ◽  
Francesca E. DeMeo ◽  
Schelte J. Bus ◽  
Masateru Ishiguro ◽  
...  

Abstract Dust emission was detected on main-belt asteroid 596 Scheila in 2010 December and was attributed to the collision of a few-tens-of-meters projectile on the surface of the asteroid. In such an impact, the ejected material from the collided body is expected to mainly come from its fresh, unweathered subsurface. Therefore, it is expected that the surface of 596 was partially or entirely refreshed during the 2010 impact. By combining spectra of 596 from the literature and our own observations, we show that the 2010 impact event resulted in a significant slope change in the near-infrared (0.8–2.5 μm) spectrum of the asteroid, from moderately red (T type) before the impact to red (D type) after the impact. This provides evidence that red carbonaceous asteroids become less red with time due to space weathering, in agreement with predictions derived from laboratory experiments on the primitive Tagish Lake meteorite, which is spectrally similar to 596. This discovery provides the very first telescopic confirmation of the expected weathering trend of asteroids spectrally analog to Tagish Lake and/or anhydrous chondritic porous interplanetary dust particles. Our results also suggest that the population of implanted objects from the outer solar system is much larger than previously estimated in the main belt, but many of these objects are hidden below their space-weathered surfaces.


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