scholarly journals Natural Dyes: From Cotton Fabrics to Solar Cells

2021 ◽  
Author(s):  
Indriana Kartini ◽  
Adhi Dwi Hatmanto

This article will discuss natural dyes’ role, from colouring the cotton fabrics with some functionality to harvesting sunlight in the dye-sensitized solar cells. Natural dye colourants are identical to the low light- and wash-fastness. Therefore, an approach to improving the colourant’s physical properties is necessary. Colouring steps employing silica nanosol and chitosan will be presented. The first part will be these multifunctional natural dye coatings on cotton fabrics. Then, functionality such as hydrophobic surfaces natural dyed cotton fabrics will be discussed. Natural dyes are also potential for electronic application, such as solar cells. So, the second part will present natural dyes as the photosensitizers for solar cells. The dyes are adsorbed on a semiconductor oxide surface, such as TiO2 as the photoanode. Electrochemical study to explore natural dyes’ potential as sensitizer will be discussed, for example, natural dyes for Batik. Ideas in improving solar cell efficiency will be discussed by altering the photoanode’s morphology. The ideas to couple the natural dyes with an organic–inorganic hybrid of perovskite and carbon dots are then envisaged.

Energies ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4863
Author(s):  
Shahzadi Tayyaba ◽  
Muhammad Waseem Ashraf ◽  
Muhammad Imran Tariq ◽  
Maham Akhlaq ◽  
Valentina Emilia Balas ◽  
...  

In this research article, the authors have discussed the simulation, analysis, and characterization of calcium-doped zinc oxide (Ca-doped-ZnO) nanostructures for advanced generation solar cells. A comparative study has been performed to envisage the effect of Ca-doped ZnO nanoparticles (NP), seeded Ca-doped ZnO nanorods (NR), and unseeded Ca-doped ZnO NR as photoanodes in dye-sensitized solar cells. Simulations were performed in MATLAB fuzzy logic controller to study the effect of various structures on the overall solar cell efficiency. The simulation results show an error of less than 1% in between the simulated and calculated values. This work shows that the diameter of the seeded Ca-doped ZnO NR is greater than that of the unseeded Ca-doped ZnO NR. The incorporation of Ca in the ZnO nanostructure is confirmed using XRD graphs and an EDX spectrum. The optical band gap of the seeded substrate is 3.18 eV, which is higher compared to those of unseeded Ca-doped ZnO NR and Ca-doped ZnO NP, which are 3.16 eV and 3.13 ev, respectively. The increase in optical band gap results in the improvement of the overall solar cell efficiency of the seeded Ca-doped ZnO NR to 1.55%. The incorporation of a seed layer with Ca-doped ZnO NR increases the fill factor and the overall efficiency of dye-sensitized solar cells (DSSC).


RSC Advances ◽  
2016 ◽  
Vol 6 (88) ◽  
pp. 85125-85134 ◽  
Author(s):  
S. Akın ◽  
S. Açıkgöz ◽  
M. Gülen ◽  
C. Akyürek ◽  
S. Sönmezoğlu

In this study, nine different natural dyes having various anchoring groups were extracted from various plants and used as photo-sensitizers in DSSC applications. The photovoltaic parameters were investigated as a function of these anchoring groups.


2019 ◽  
Vol 21 (14) ◽  
pp. 7534-7543 ◽  
Author(s):  
Lorenzo Veronese ◽  
Elsa Quartapelle Procopio ◽  
Thomas Moehl ◽  
Monica Panigati ◽  
Kazuteru Nonomura ◽  
...  

We report dinuclear hydrido-carbonyl rhenium complexes employed in DSSCs for the first time. An improved performance in solar cell efficiency was achieved by molecular design.


2018 ◽  
Vol 2018 ◽  
pp. 1-7
Author(s):  
Fahd M. Rajab

A dye monolayer formation on a semiconductor surface is critical for efficient dye-sensitized solar cells. The role of dye is to absorb light and convert it to photoelectrons, which are injected into the semiconductor conduction band as device current. We measured dye N719 adsorption via optical techniques including indirect nanoplasmonic sensing. The adsorption rate constant of dye N719 in mimic TiO2 photoelectrodes is determined as ka = 983 M−1 s−1. Dye adsorption for ruthenium dyes N3, N749, and Z907, coated onto TiO2 photoelectrodes of varying thicknesses ranging from 3 μm to 10 μm, was conducted and related to fabricated dye-sensitized solar cell efficiency. Analytical studies included scanning electron microscopy and ellipsometry, X-ray diffraction, and UV-Vis spectroscopy, as well as quantum efficiency and current-voltage device characterizations. The results show greatest enhancement of device performance for dye N719 in spite of multilayer formation, which often is underestimated when addressing the dynamic competing factors that reverse thick-film device performance.


2017 ◽  
Vol 17 (2) ◽  
pp. 30 ◽  
Author(s):  
Natalita Maulani Nursam ◽  
Ade Istiqomah ◽  
Jojo Hidayat ◽  
Putri Nur Anggraini ◽  
Shobih

Dye-sensitized solar cells (DSSC) are widely developed due to their attractive appearance and simple fabrication processes. One of the challenges that arise in the DSSC fabrication involves high material cost associated with the cost of conductive substrate. DSSC with monolithic configuration was then developed on the basis of this motivation. In this contribution, titanium dioxide-based monolithic type DSSCs were fabricated on a single fluorine-doped transparent oxide coated glass using porous ZrO2 as spacer. Herein, the catalytic material for the counter-electrode was varied using carbon composite and platinum in order to analyze their effect on the solar cell efficiency. Four-point probe measurement revealed that the carbon composite exhibited slightly higher conductivity with a sheet resistance of 9.8 Ω/sq and 10.9 Ω/sq for carbon and platinum, respectively. Likewise, the photoconversion efficiency of the monolithic cells with carbon counter-electrode almost doubled the efficiency of the cells with platinum counter-electrode. Our results demonstrate that carbon could outperform the performance of platinum as catalytic material in monolithic DSSC.


2019 ◽  
Vol 9 (12) ◽  
pp. 2515 ◽  
Author(s):  
María José García-Salinas ◽  
María Jesús Ariza

We present a study about the sensitizers extracted from natural resources. This paper focuses on how to select, extract and characterize natural dyes, giving some guides to establish a protocol for the whole process of fabricating and using these dyes. The influence of the extraction solvent and method, and of parameters such as pH are analyzed. Also, dye precursor and dye extract stability have been studied, as well as how the dye adsorbs onto substrates and the effect of mixing or concentrating the extracts. Results concerning betalain pigments present in bougainvillea and beetroot extracts, and anthocyanins in eggplant extracts, analyzed by using UV-Vis spectrometry, are included. As an example of application, we report procedures intended to test and enhance the dye potential as a main component of dye-sensitized solar cells (DSSCs). DSSCs mimic nature’s photosynthesis and have some advantages like an easy and low-cost fabrication procedure. Their efficiency depends on its design and fabrication process and also on the different components involved. Hence, optimizing each component is essential to achieve the best performance, and thus the dye used as a sensitizer is crucial. We fabricate cells by using a simple procedure: As the interest is focused on the sensitizer, the same consecutive steps are followed, varying only the dye extract. Among all the natural-dyes tested, beetroot extract reaches up to 0.47% cell efficiency, which is near the highest values found in literature for this pigment.


2018 ◽  
Vol 1 (2) ◽  
pp. 301-305 ◽  
Author(s):  
Maxwell T. Robinson ◽  
Marie E. Armbruster ◽  
Avi Gargye ◽  
David E. Cliffel ◽  
G. Kane Jennings

Optik ◽  
2021 ◽  
pp. 167331
Author(s):  
Shalini Singh ◽  
Ishwar Chandra Maurya ◽  
Shubham Sharma ◽  
Shiva Prakash Singh Kushwaha ◽  
Pankaj Srivastava ◽  
...  

2015 ◽  
Vol 3 (4) ◽  
pp. 281-291 ◽  
Author(s):  
Mario Alejandro Mejía Escobar ◽  
Frankin Jaramillo

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