scholarly journals Multivariate Optimization of a Simultaneous Cloud Point Extraction Procedure of Cd, Cu and Ni from Sediments Samples and Determination by ICP OES

Author(s):  
Leandro dos Santos ◽  
Queila O. dos Santos ◽  
Islania Moreno ◽  
Cléber G. Novaes ◽  
Márcio J. S. dos Santos ◽  
...  
2012 ◽  
Vol 4 (9) ◽  
pp. 2809 ◽  
Author(s):  
Fernanda dos Santos Depoi ◽  
Fabrina R. S. Bentlin ◽  
Marco Flôres Ferrão ◽  
Dirce Pozebon

2011 ◽  
Vol 8 (4) ◽  
pp. 1588-1595 ◽  
Author(s):  
Shahnaz Abedi ◽  
Farzin Nekouei

A surfactant mediated cloud point extraction (CPE) procedure has been developed to remove color from wastewater containing direct yellow 12 (Chrysophenine G), using triton x-100 (TX-100) as nonionic surfactant. The effects of the concentration of the surfactant, pH, temperature and salt concentration on the different concentration of dye have been studied and optimum conditions were obtained for the removal of direct yellow 12 (DY 12). The concentration of DY 12 in the dilute phase was measured using UV-Vis spectrophotometer. It was found that the separation of phases was complete and the recovery of DY 12 was very effective in the presence of NaCl as an electrolyte. The results showed that up to 600 mg L−1of DY 12 can quantitatively be removed (>96%) by Cloud point extraction procedure in a single extraction using optimum conditions.


2014 ◽  
Vol 97 (4) ◽  
pp. 1202-1205 ◽  
Author(s):  
Lijin Zhang ◽  
Fang Chen ◽  
Wenhuan Zhang ◽  
Canping Pan

Abstract A cloud-point extraction (CPE) method with Triton X-114 has been developed for analysis of six organophosphorus pesticides (OPPs) in apples and pears. In this CPE procedure, the effects of the surfactant volume, mass of sodium chloride, equilibrium temperature, equilibrium time, and pH on the extraction procedure were investigated. Under the optimal CPE conditions, the analytes were enriched 20-fold and the LODs dropped to 0.44–5.20 μg/kg. Furthermore, the proposed extraction method was validated by the correlation coefficient (R2) of the calibration curve, repeatability (RSD, n = 6), and fortified recoveries, which were 0.9967–0.9993, 2.7–6.5, and 74.7–104.5%, respectively. Based on these results, it could be concluded that the proposed CPE method with Triton X-114 was suitable for the effective extraction and enrichment of OPP residues in the apple and pear samples.


2010 ◽  
Vol 95 (2) ◽  
pp. 306-310 ◽  
Author(s):  
Raúl A. Gil ◽  
José A. Salonia ◽  
José A. Gásquez ◽  
Alejandro C. Olivieri ◽  
Roberto Olsina ◽  
...  

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