scholarly journals Hexavalent Chromium: Analysis of the Mechanism of Groundwater Contamination in a Former Industrial Site in the Province of Vicenza (Northern Italy)

Author(s):  
Valentina Accoto ◽  
Pierluigi Bullo ◽  
Ruben Faccio ◽  
Leonardo Mason ◽  
Andrea Sottani

The study consisted in the analysis of the mobilization mechanisms of hexavalent chromium (Cr(VI)) into groundwater from a decommissioned contaminated factory. The site is located in the Province of Vicenza and formerly was a chrome-plating plant. The subsoil consists predominantly of gravelly deposits with a thickness of at least one hundred meters. An unconfined aquifer is present with water table at about 23 m depth bgl. During the seven years of monitoring (2008-2014), the fluctuation of groundwater level was more than 6 m; hydraulic conductivity is about 1.0E-03 m/s and groundwater seepage velocity about 12 m/day. At the area of the source of contamination, the unsaturated soil is contaminated by hexavalent chromium throughout the thickness: concentrations range from 200 to 500 mg/kg. At the bottom of zone of groundwater level fluctuation, the hexavalent chromium concentration decreases to below the detection limit. The available data (e.g. hexavalent chromium concentrations in groundwater, groundwater level, local rainfall) give the opportunity to assess the effects, on the magnitude of groundwater contamination, of the effective infiltration versus the fluctuation of groundwater level. The main analysis was performed on a statistical basis, in order to find out which of the two factors was most likely related to the periodic peaks of hexavalent chromium concentration in groundwater. Statistical analysis results were verified by a mass balance. Data show that at the site both the effective infiltration through the unsaturated zone and the leaching of soil contaminated by groundwater, when it exceeds a certain piezometric level, lead to peak concentrations of hexavalent chromium, even if with characteristics and effects different.

2013 ◽  
Vol 368-370 ◽  
pp. 1697-1700
Author(s):  
Long Zhang ◽  
Xue Wen Lei ◽  
Qing Shang Meng

Based on the characteristics of frequent land subsidence events caused by groundwater level fluctuation in coastal cities in China and studying on the quaternary sedimentary soft clay in Shanghai, the effects of groundwater level fluctuation on the deformation of soft clay is simulated by Geo-Studio finite element software. It has summarized the law of deformation, effective stress with the change of groundwater level fluctuation, especially the process of dissipation of pore water pressure with the groundwater level fluctuation. The low can be sued as a reference for similar engineering and land subsidence prevention.


2021 ◽  
Vol 13 (1) ◽  
pp. 1-20
Author(s):  
Abdelwassie Hussien ◽  
Tesfamichael Gebreyohannes ◽  
Miruts Hagos ◽  
Gebremedhin Berhane ◽  
Kassa Amare ◽  
...  

Due to the ever-increasing demand for water in Aynalem catchment and its surrounding, there has been an increased pressure on the Aynalem well field putting the sustainability of water supply from the aquifer under continuous threat. Thus, it is vital to understand the water balance of the catchment to ensure sustainable utilization of the groundwater resource. This in turn requires proper quantification of the components of water balance among which recharge estimation is the most important. This paper estimates the groundwater recharge of the Aynalem catchment using high-resolution hydro-meteorological data. Daily precipitation and temperature measurement data for years 2001-2018; groundwater level fluctuation records collected at every 30 minutes; and soil and land use maps were used to make recharge estimations. In the groundwater level fluctuation, three boreholes were monitored, but only two were utilized for the analysis because the third was under operation and does not represent the natural hydrologic condition. Thornthwaite soil moisture balance and groundwater level fluctuation methods were applied to determine the groundwater recharge of the Aynalem catchment. Accordingly, the annual rate of groundwater recharge estimated based on the soil-water balance ranges between 7mm/year and 138.5 mm/year with the weighted average value of 89.04 mm/year. The weighted average value is considered to represent the catchment value because the diverse soil and land use/cover types respond differently to allow the precipitation to recharge the groundwater. On the other hand, the groundwater recharge estimated using the groundwater level fluctuation method showed yearly groundwater recharge of 91 to 93 mm/year. The similarity in the groundwater recharge result obtained from both methods strengthens the acceptability of the estimate. It also points out that the previously reported estimate is much lower (36 to 66 mm/year).


Water ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 826 ◽  
Author(s):  
Wu ◽  
Hsieh

Sloping unconfined aquifers are commonly seen and well investigated in the literature. In this study, we propose a generalized integral transformation method to solve the linearized Boussinesq equation that governs the groundwater level in a sloping unconfined aquifer with an impermeable bottom. The groundwater level responses of this unconfined aquifer under temporally uniform recharge or nonuniform recharge events are discussed. After comparing with a numerical solution to the nonlinear Boussinesq equation, the proposed solution appears better than that proposed in a previous study. Besides, we found that the proposed solutions reached the convergence criterion much faster than the Laplace transform solution did. Moreover, the application of the proposed solution to temporally changing rainfall recharge is also proposed to improve on the previous quasi-steady state treatment of an unsteady recharge rate.


Sign in / Sign up

Export Citation Format

Share Document