scholarly journals Measurement of Transient Photo-Induced Changes in Thin Films at J-PARC — Time-Resolved Neutron Reflectivity Measurements of Silver Photo-Diffusion into Ge-Chalcogenide Films

Author(s):  
Yoshifumi Sakaguchi ◽  
Hidehito Asaoka ◽  
Yuki Uozumi ◽  
Yukinobu Kawakita ◽  
Takayoshi Ito ◽  
...  
2014 ◽  
Vol 92 (7/8) ◽  
pp. 654-658 ◽  
Author(s):  
Y. Sakaguchi ◽  
H. Asaoka ◽  
Y. Uozumi ◽  
Y. Kawakita ◽  
T. Ito ◽  
...  

To better understand the dynamics of silver photodiffusion into amorphous chalcogenide (Ch) films, it is informative to probe the time-dependent distribution of silver in the films while they are simultaneously exposed to visible light. Time-resolved neutron reflectometry is particularly well-suited to this purpose because it can follow time-dependent changes in the multilayer structure (Ag/Ag–Ch/Ch) while excluding the possibility of probe beam induced changes. This paper reports the results of time-resolved neutron reflectivity measurements of two Ag/GexS1−x(x = 0.2 and 0.4) films as they are exposed to a visible light source. Analysis showed that silver diffusion occurs via two distinct processes: a fast diffusion that takes place during the first 2 and 10 min of sample illumination for the x = 0.2 and 0.4 films, respectively; and a subsequent slower change that is observed over the next 18 min (x = 0.2 film) and 107 min (x = 0.4 film). These results suggest the formation of a relatively stable Ag-rich phase in the reaction layer followed by slower diffusion at the interface between Ag-rich and Ag-poor layers. Fourier transform analysis shows that the position of the interface is essentially fixed — a conclusion that contradicts the “diffusion front” model that has been previously postulated.


1992 ◽  
Vol 25 (10) ◽  
pp. 2619-2623 ◽  
Author(s):  
Lei Jong ◽  
Eli M. Pearce ◽  
T. K. Kwei ◽  
W. A. Hamilton ◽  
G. S. Smith ◽  
...  

2006 ◽  
Vol 20 (14) ◽  
pp. 821-833 ◽  
Author(s):  
ARIF NESRULLAJEV ◽  
ŞENER OKTIK

In this work, the effect of thin films on the thermotropic and thermo-optical properties and peculiarities of the phase transitions between the smectic A and isotropic liquid have been investigated. Peculiarities of the heterophase regions of the straight smectic A-isotropic liquid and reverse isotropic liquid-smectic A phase transitions have been studied. Change of morphologic properties of the heterophase regions, shift of the phase transition temperatures and the change of temperature widths of these heterophase regions under thin film influence have been observed.


2019 ◽  
Vol 669 ◽  
pp. 520-524
Author(s):  
Baptiste Bérenguier ◽  
Nicolas Barreau ◽  
Alexandre Jaffre ◽  
Daniel Ory ◽  
Jean-François Guillemoles ◽  
...  

2017 ◽  
Vol 111 (8) ◽  
pp. 082907 ◽  
Author(s):  
Seiji Nakashima ◽  
Osami Sakata ◽  
Hiroshi Funakubo ◽  
Takao Shimizu ◽  
Daichi Ichinose ◽  
...  

2012 ◽  
Vol 566 ◽  
pp. 145-149
Author(s):  
Hirotaka Tanabe ◽  
Keiji Ogawa ◽  
Yui Izumi ◽  
Tohru Takamatsu ◽  
Heisaburo Nakagawa ◽  
...  

In our previous study, it has been shown that improvement of the adhesive strength and substrate hardness of ceramic coated steels without compromising the film hardness can be achieved by applying laser quenching. In the present research, in order to demonstrate further development of this method, the fracture strength of laser-irradiated ceramic thin films (CrAlN, TiAlN and CrN) was investigated by sphere indentation testing. To prevent heat-induced changes in the substrate hardness, a cemented carbide WC-Co rather than steel was used as substrate material. While the fracture strength of each film decreased significantly through furnace heat treatment, it remained almost unchanged in case of the laser irradiated films. Laser quenching has been shown to effectively reduce the fracture strength loss of the ceramic thin films in coated steels.


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