Manifold curvature and Ehrenfest forces with a moving basis

Known force terms arising in the Ehrenfest dynamics of quantum electrons and classical nuclei, due to a moving basis set for the former, can be understood in terms of the curvature of the manifold hosting the quantum states of the electronic subsystem. Namely, the velocity-dependent terms appearing in the Ehrenfest forces on the nuclei acquire a geometrical meaning in terms of the intrinsic curvature of the manifold, while Pulay terms relate to its extrinsic curvature.

Еffect of graphene filler oxidation on the thermal destruction of epoxy-graphene composites

The participation of the electronic subsystem of graphene nanoparticles in heat transfer on the interfaphase surface with epoxy polymer, its participation in the thermodestruction processes of epoxy matrix and the concentration interval of the subsystem's influence on the thermal destruction of the polymer matrix are investigated. For such purpose, epoxy resin composites with oxidized and non-oxidized graphene nanoparticles have been used.The particles were obtained by electrochemical method and those are characterized by the same dispersion and analogical of defect spectra. The particles have the same crystal structure, however in composites with oxidized graphene, the participation of the electronic subsystem in thermophysical processes on the interfacial surface is blocked by the atomic layer of adsorbed oxygen. Сomposites of epoxy resin filled with the same particles of nonoxidized and oxidized nanoparticles in the filler content 0.0, 1.0, 2.0, and 5.0 wt%. The multilayered graphene particles were studied by X-ray diffraction analysis (XRD) and Raman spectroscopy (RS) methods. It was shown that the graphene particles are the 2D dimensional structures with about of 100 layers. Desorption curves of epoxy and its composites have been obtained using a programmable thermal desorption mass-spectroscopic (TDMS) technique for fragments with 15≤ m/z ≤108 and temperature interval 35 - 800 оС. The activation energy of desorption was determined from the Wigner-Polanyi equation as 35 - 150 kJ/mol, temperature and mass dependences of the quantity of desorbed atomic fragments have been calculated. It were established the graphene electron subsystem takes part in polymer structure thermodestruction for epoxy composites with nonoxidized graphene enhancing their heat resistance at graphene content С ≤ 1 wt%. With increasing filler content, the thermodestruction behavior in pristine epoxy and its composites with nonoxidized and oxidized graphene is analogical. The thermodestruction characterizes by the stepwise variations in the desorption intensity of atomic fragments. The electron subsystem of graphene particles does not participate in the heat resistance variations.

The Development of a High Performance Digital RF Transmitter for NMR

<p>This Master’s thesis consists of the development of a Nuclear Magnetic Resonance (NMR) Radio Frequency (RF) transmitter, which is a core electronic subsystem of an NMR system. The main purpose of this research is to contribute to the application of NMR, which is a new sensing technology that has yet to be fully implemented into the everyday world. One of the barriers to adopting this technology is its complexity. However, the invention of high speed digital FPGAs (Field Programmable Gate Array) such as the Spartan series has made it easier to develop high performance NMR systems over recent years. The major contribution to this research is the development of faster digital signal processing hardware, and methodologies that have been implemented on a single chip. This has reduced the size and the cost of the electronic subsystem and contributed towards the evolution of NMR as a general tool. This thesis introduces the concept of implementing a high-speed NMR RF multi-frequency transmitter by using multiple Direct Digital Synthesis (DDS) cores to generate sine-waves, which range from 100 kHz to 750 MHz. The research required three stages to be achieved, beginning with conceptual design of a high-speed transmitter using MATLAB-Simulink, RTL-level (Register-Transfer Level) simulation and hardware implementation, which included hardware testing on a prototype board. This Master’s research is to seek a solution to building a multi-core DDS module in an FPGA device. In other words, the research work focuses on finding an alternative solution to constructing a DDS system. The project involves building up the VHSIC Hardware Description Language (VHDL) program to work beyond the hardware limitation of an FPGA device. Hence, the final solution does not consider any noise impact due to the structure of the developed system.</p>

The Development of a High Performance Digital RF Transmitter for NMR

<p>This Master’s thesis consists of the development of a Nuclear Magnetic Resonance (NMR) Radio Frequency (RF) transmitter, which is a core electronic subsystem of an NMR system. The main purpose of this research is to contribute to the application of NMR, which is a new sensing technology that has yet to be fully implemented into the everyday world. One of the barriers to adopting this technology is its complexity. However, the invention of high speed digital FPGAs (Field Programmable Gate Array) such as the Spartan series has made it easier to develop high performance NMR systems over recent years. The major contribution to this research is the development of faster digital signal processing hardware, and methodologies that have been implemented on a single chip. This has reduced the size and the cost of the electronic subsystem and contributed towards the evolution of NMR as a general tool. This thesis introduces the concept of implementing a high-speed NMR RF multi-frequency transmitter by using multiple Direct Digital Synthesis (DDS) cores to generate sine-waves, which range from 100 kHz to 750 MHz. The research required three stages to be achieved, beginning with conceptual design of a high-speed transmitter using MATLAB-Simulink, RTL-level (Register-Transfer Level) simulation and hardware implementation, which included hardware testing on a prototype board. This Master’s research is to seek a solution to building a multi-core DDS module in an FPGA device. In other words, the research work focuses on finding an alternative solution to constructing a DDS system. The project involves building up the VHSIC Hardware Description Language (VHDL) program to work beyond the hardware limitation of an FPGA device. Hence, the final solution does not consider any noise impact due to the structure of the developed system.</p>

Modeling and investigating of the influence of surface roughness on the strength of electrically conductive fiber

In the framework of the model of locally inhomogeneous electrically conductive nonferromagnetic solid, the near-surface inhomogeneity in a solid cylinder is investigated. It is shown that such inhomogeneity is characterized by three characteristic sizes associated with the structural inhomogeneity of the material, the roughness of the real surface and the electronic subsystem. The charge distribution features a double electric layer. The size effect of fiber strength and its dependence on geometric inhomogeneity parameters of the surface are studied.

Features of the Electronic Structure of Excited Quadrupolar Molecules in Non-Polar Solvents

Interactions of the electronic subsystem of the quadrupolar fluorophore with intramolecular highfrequency antisymmetric vibrations and solvent polarization are responsible for charge transfer symmetry breaking (SB), which is observed after optical excitation of such molecules in polar solvents. It is known that although these two interactions are mathematically described in similar ways, only the interaction of the fluorophore with solvent orientational polarization can create a state with broken symmetry if this interaction is strong enough. Nevertheless, the interaction of a quadrupolar fluorophore with intramolecular highfrequency antisymmetric vibrations in nonpolar solvents leads to a considerable reconstruction of the electronic subsystem. The analysis of the excited state of quadrupolar molecules in nonpolar solvents performed in this study reveals that such molecules can behave like quantum twostate systems, that is, as a quasispin s = 1/2, having an electric dipole moment instead of a magnetic one. This feature of excited quadrupolar molecules may be of interest to emerging technologies of molecular electronics.

Гибридный фотоприемник среднего инфракрасного диапазона на основе полупроводниковых квантовых ям

A hybrid mid-infrared photodetector has been implemented, in which silicon carbide (SiC) particles are used to increase the interaction of the electromagnetic field with the electronic subsystem of quantum wells. On the basis of direct measurements of infrared photoconductivity and calculations within the framework of the finite difference method in the time domain, it is shown that this approach makes it possible to increase the sensitivity of such infrared photodetector to electromagnetic radiation by reversing the direction of polarization of the electric field, including in the near zone of SiC particles.