Characterization of Siliceous Nodules in Western Kefalonia Ιsland Greece: An Initial Approach to Their Formation and Diagenetic Characteristics

In this study, siliceous nodules from the world-famous Myrtos beach, as well as from Avithos beach, in the western flanks of Kefalonia Island in Greece are examined by means of petrographical, mineralogical, geochemical and micropaleontological methods. The objectives of this study are to characterize the textural and compositional features of the nodules, with the aim to provide an initial interpretation of their origin and their diagenetic evolution. The studied siliceous nodules are hosted within Lower Cretaceous thin-bedded limestones at Myrtos and Upper Eocene limestones at Avithos. Nodules from both areas display a characteristic concentric texture at a macroscopic and microscopic scale. They both have a dense fine-grained siliceous sedimentary fabric, composed mainly of microcrystalline or cryptocrystalline quartz and moganite with common residual calcite in the case of Avithos. These results, and in particular the shape of the nodules, along the textural and compositional characteristics, indicate different conditions of formation in the two localities, both during the early epigenetic stages, as well as later during the diagenetic processes. Myrtos nodules originated from Si-precursors deposited in a pelagic environment, going through intense Si-replacement. Avithos nodules were deposited in a more proximal environment, being influenced by a less intense silicification. Nevertheless, the higher degree of recrystallization of Avithos samples indicates a syn- or post-diagenetic tectonic activity that resulted in the circulation of geothermal fluids. The conclusions drawn from this work demonstrate the usefulness of thorough studies of siliceous nodules in order to get a more comprehensive understanding of the initial depositional conditions, as well as diagenetic pathways and processes.

Past ecosystems drive the evolution of the early diverged Symphyta (Hymenoptera: Xyelidae) since the earliest Eocene

Paleoxyela nearctica gen. et sp. nov., is described from the upper Eocene of Florissant Formation in Colorado. We placed Paleoxyela gen. nov. in the subfamily Macroxyelinae and the tribe Macroxyelini based on the numerous wing venation characters visible on the specimen. Proxyelia pankowskii gen. et sp. nov. is described from the lower Eocene Fossil Lake deposits of the Green River Formation in Wyoming. We placed Proxyelia gen. nov. in the subfamily Macroxyelinae and the tribe Xyeleciini based on the numerous wing venation characters visible on the specimen. These new records of the family Xyelidae are of particular importance to better understand the past diversity of the clade and propose hypotheses about their diversification. Extant Xyelidae inhabit temperate Northern Hemisphere forests, and most of their larvae feed on conifers, which may explain why they are relatively poorly diversified compared to the other symphytan families. We suggest that the global decline in conifers and the reduced diversity of extant host trees partly explain the diversity of extant Xyelidae. We correlate the biome repartition during the Eocene to that of the extant xyelid.

A new species of the genus Holocentropus (Trichoptera: Polycentropodidae) from Rovno amber

A new caddisfly species Holocentropus tutkaktut sp. nov. (Polycentropodidae) is described from Priabonian Rovno amber (Upper Eocene, 33.9–37.8 million years old). With the new species, the family Polycentropodidae is represented in Rovno amber by 19 species, and the genus Holocentropus McLachlan, 1878, by nine species.

Rare Earth Elements Enrichment in the Upper Eocene Tošići-Dujići Bauxite Deposit, Croatia, and Relation to REE Mineralogy, Parent Material and Weathering Pattern

Tošići-Dujići bauxite deposit, situated in Dalmatian inlands, Croatia, contains minor remaining bauxite reserves. The deposit lies on Lower Eocene foraminiferal limestone and is covered by Upper Eocene Promina sediments. Bauxite samples were analyzed for textural, mineralogical, and geochemical features in order to determine absolute REE abundances and their relation to mineralogy, as well as to devise the origin of REE enrichment and to trace weathering and bauxitization paths of the parent material. The samples show total REE abundances up to 3500 mg/kg with significant HREE enrichment in some cases. All samples are gibbsitic with hematite and anatase as major phases. Kaolinite occurs in most of the samples, and goethite, böhmite, and nordstrandite are minor phases. Monazite-(Ce) and xenotime-(Y) were identified as detrital REE minerals as well as authigenic florencite-(Ce). In the REE most abundant sample, REE are most likely bound to Fe- and Ti-oxide phases as suggested by correlation analysis. Chemical weathering proxies show intensive weathering. Geochemical and textural data imply that the REE enrichment is influenced by intensive weathering (CIA 97.87–99.26) of detrital material, and also by possible deposition/redeposition of residual material potentially derived and mobilized from various sedimentary rocks of the area.

Upper Eocene planktonic foraminifera from northern Saudi Arabia: implications for stratigraphic ranges

The Rashrashiyah Formation of the Sirhan Basin in northern Saudi Arabia contains diverse assemblages of planktonic foraminifera. We examined the biostratigraphy, stratigraphic range and preservation of upper Eocene planktonic foraminifera. Assemblages are well-preserved and diverse, with 40 species and 11 genera. All samples are assigned to the Priabonian Globigerinatheka semiinvoluta Highest Occurrence Zone (E14), consistent with calcareous nannofossil biostratigraphy indicating Zone CNE17. Well-preserved planktonic foraminifera assemblages from the lower part of the upper Eocene are rare worldwide. Our study provides new insights into the stratigraphic ranges of many species. We find older (Zone E14) stratigraphic occurrences of several species of Globoturborotalita previously thought to have evolved in the latest Eocene (Zone E15, E16) or Oligocene; these include G. barbula, G. cancellata, G. gnaucki, G. pseudopraebulloides, and G. paracancellata. Older stratigraphic occurrences for Dentoglobigerina taci and Subbotina projecta are also found, and Globigerinatheka kugleri occurs at a younger stratigraphic level than previously proposed. Our revisions to stratigraphic ranges indicate that the late Eocene had a higher tropical–subtropical diversity of planktonic foraminifera than hitherto reported.