The effect of the dispersion and piping of clay fines — colloid mobilization — as a means of remediating subsurface contamination was investigated. Prior colloid mobility research has focused on mitigating colloidal movement to reduce contaminant transport or monitoring colloids to determine the extent of mobility and contamination transport. To date, limited work has been performed to evaluate remediation efficiency associated with the removal of clay-sized (colloidal) particles and related sorbed contamination. Laboratory flow-through tests were performed on a glacial till from a radioactive cesium contaminated site. Post-testing analysis comprised mass balance checks, grain-size distribution testing, and microscopic analysis of removed particles. Results showed the potential of initiating and maintaining clay dispersion and piping, thus establishing a means to mobilize colloids and subsequently remove them from the subsurface environment. Beneficial effects of hydraulic gradient and ionic strength manipulations were influenced by soil properties, such as cation exchange capacity, clay content, and average pore diameter. In general, colloid mobilization testing results found that extreme levels of mobilization typically resulted in particle trapping and an overall reduction in colloidal removal, while the effect of more moderate levels was mobilization with increased rates of removal.
Colloid mobilization in an undisturbed sediment core under semiarid recharge rates
