Vector-like quarks decaying into singly and doubly charged bosons at LHC

We investigate the production of vector-like quarks with charge 5/3 at the LHC and their subsequent decays into new singly or doubly charged bosons plus a heavy quark (top or bottom). In particular, we explore final states with same-sign di-leptons (electron or muon pairs), with the leptons coming from the decay of the new bosons and, in the case of production of singly charged bosons, from top quarks as well. These processes are predicted by classes of models based on extensions of the gauge group of the Standard Model, such as the 331 Model, where the electroweak symmetry is described by SU(3)L × U(1)X, X being a new abelian charge. For this purpose, a CMS search for vector-like partners with charge 5/3 decaying into Wt is recast to obtain model-independent bounds and projected reaches at future luminosity stages of the LHC. The results are then interpreted as mass bounds for the new particles predicted in the 331 Model and as a constraint on the scale of its spontaneous symmetry breaking. The complete set of model-independent results are provided as recast efficiencies, to allow for reinterpretation in different scenarios.

The Role of Counterions in Intermolecular Radical Coupling of Ru-bda Catalysts

Intermolecular radical coupling (also interaction of two metal centers I2M) is one of the main mechanisms for O–O bond formation in water oxidation catalysts. For Ru(bda)L2 (H2bda = 2,2′-bipyridine-6,6′-dicarboxylate, L = pyridine or similar nitrogen containing heterocyclic ligands) catalysts a significant driving force in water solution is the hydrophobic effects driven by the solvent. The same catalyst has been successfully employed to generate N2 from ammonia, also via I2M, but here the solvent was acetonitrile where hydrophobic effects are absent. We used a classical force field for the key intermediate [RuVIN(bda)(py)2]+ to simulate the dimerization free energy by calculation of the potential mean force, in both water and acetonitrile to understand the differences and similarities. In both solvents the complex dimerizes with similar free energy profiles. In water the complexes are essentially free cations with limited ion paring, while in acetonitrile the ion-pairing is much more significant. This ion-pairing leads to significant screening of the charges, making dimerization possible despite lower solvent polarity that could lead to repulsion between the charged complexes. In water the lower ion pairing is compensated by the hydrophobic effect leading to favorable dimerization despite repulsion of the charges. A hypothetical doubly charged [RuVIIN(bda)py2]2+ was also studied for deeper understanding of the charge effect. Despite the double charge the complexes only dimerized favorably in the lower dielectric solvent acetonitrile, while in water the separated state is more stable. In the doubly charged catalyst the effect of ion-pairing is even more pronounced in acetonitrile where it is fully paired similar to the 1+ complex, while in water the separation of the ions leads to greater repulsion between the two catalysts, which prevents dimerization. Graphic Abstract

Formation and fragmentation of doubly and triply charged ions in the negative ion spectra of neutral N-glycans from viral and other glycoproteins

Structural determination of N-glycans by mass spectrometry is ideally performed by negative ion collision-induced dissociation because the spectra are dominated by cross-ring fragments leading to ions that reveal structural details not available by many other methods. Most glycans form [M – H]- or [M + adduct]- ions but larger ones (above approx. m/z 2000) typically form doubly charged ions. Differences have been reported between the fragmentation of singly and doubly charged ions but a detailed comparison does not appear to have been reported. In addition to [M + adduct]- ions (this paper uses phosphate as the adduct) other doubly, triply, and quadruply charged ions of composition [Mn + (H2PO4)n]n- have been observed in mixtures of N-glycans released from viral and other glycoproteins. This paper explores the formation and fragmentation of these different types of multiply charged ions with particular reference to the presence of diagnostic fragments in the CID spectra and comments on how these ions can be used to characterize these glycans. Graphical abstract

Production of the Doubly Charged Higgs Boson in Association with the SM Gauge Bosons and/or Other HTM Scalars at Hadron Colliders

We investigate an extension of the Standard Model with one additional triplet of scalar bosons. Altogether, the model contains four Higgs bosons. We analyze the associated production of the doubly charged scalar with the Standard Model gauge bosons and the remaining Higgs bosons of the model, which are: the light (SM) and heavy neutral scalars and a singly charged scalar. We estimate, in the context of the present (HL–LHC) and future (FCC–hh) hadron colliders, the most promising processes in which a single produced doubly charged Higgs boson is involved.

ON THE STARK BROADENING OF Ru III SPECTRAL LINES

Stark broadening parameters, full widths at half maximum (FWHM) and shifts for spectral lines within six multiplets of doubly charged ruthenium ions have been calculated, for an electron density of 1017 cm-3 and temperature range from 10 000 K to 160 000 K. Calculations have been performed with the simplified modified semiempirical (SMSE) approach. In the case of two multiplets, it is possible to apply the full modified semiempirical method. The corresponding calculations have been performed and results are compared in order to test and determine the accuracy of the SMSE approach. The results are also used for the consideration of Stark width and shift regularities in Ru III spectrum.