Nurturing Plasmonic Properties of Nanocomposite Thin Films: The Importance of Optimum Oblate Shape

Metal nanoparticles (MNPs) embedded dielectric thin films are very crucial for many optoelectronic applications. This report investigates various ways of tuning the plasmonic properties of such nanocomposite thin films. For this, the well-known plasmon resonance condition was first generalized to include the shape and volume fraction of MNPs. This was followed by deriving an empirical formula for the resonance position (λR) which was worked out to be the positive root of a quadratic equation. The coefficients of the deduced quadratic relation involve the parameters obtained from the empirical fit to some of the experimental dielectric functions of MNPs available in literature. The derived working formula enables research community to tune the LSPR of nanocomposites in the whole range of visible wavelengths. The derived formula also concluded that with known lower volume fractions, shape of MNPs affects λR the most, compared to the other parameters. The derived formula was validated by calculating the full extinction spectra. It was shown for the first time that there exists an optimum value of oblate shape to give maximum resonance for a given nanocomposite.

Z(5): Critical Point Symmetry for the Prolate to Oblate Nuclear Shape Phase Transition

A critical point symmetry for the prolate to oblate shape phase transition is intro­ duced, starting from the Bohr Hamiltonian and approximately separating variables for γ=30°. Parameter-free (up to overall scale factors) predictions for spectra and B(E2) transition rates are found to be in good agreement with experimental data for 194Pt, which is supposed to be located very close to the prolate to oblate critical point, as well as for its neighbours (192Pt, 196Pt).

Effects of pH on the Shape of Alginate Particles and Its Release Behavior

A vast majority of alginate particles exist as spheres in most practical uses, and both the particle shape and size are the key factors dominating the applications and performance of alginate gels. Therefore, it becomes an issue of great interest to investigate the aspheric alginate particles. As the first step, various shaped alginate particles were formed due to various pH values in gelation solutions. It was experimentally demonstrated that a low pH brought about an oblate shape, and particularly lower concentrations of both alginate and divalent cations resulted in a flattened oblate shape. Ba2+acting as a cross-linker had a less impact on the particle shape than Ca2+due to a higher affinity in alginate intermolecular cross-linking. With a larger surface area, an oblate particle offered a higher release rate than a spheric one.