Sulfide mineral chemistry and platinum-group minerals of the UG-2 chromitite in the northern limb of the Bushveld Igneous Complex, South Africa

ABSTRACT The UG-2 chromitite layer, with its elevated platinum-group element content, is a key marker horizon in the eastern and western limbs of the Bushveld Igneous Complex and the largest platinum-group element chromite-hosted resource of its kind in the world. In contrast, much less is known about its stratigraphic equivalent in the northern limb, the “UG-2 equivalent” (UG-2E) chromitite. Recent studies on chromite mineral chemistry show similarities between the UG-2 and sections of the UG-2E, but also that the UG-2E was partially contaminated by assimilation of local metasedimentary rocks. Here, we provide a detailed characterization of sulfide minerals and platinum-group minerals in a suite of samples from the UG-2E and compare the results with data obtained from a reference suite of samples from the UG-2. Results from petrographic observations, electron probe microanalysis, laser ablation-inductively coupled plasma-mass spectrometry, quantitative evaluation of materials by scanning electron microscopy, and δ34S isotopes show that: (1) sulfide minerals in the UG-2E and UG-2 consist mainly of pentlandite-chalcopyrite-pyrrhotite, but pyrrhotite is significantly more abundant in the UG-2E and almost absent in the UG-2; (2) iron contents in pentlandite from the UG-2E are significantly higher than in the UG-2; (3) platinum-group element contents within sulfide minerals are different between the two chromitites; (4) UG-2E platinum-group minerals are dominated by arsenides and bismuthotellurides, and by alloys and platinum-group element-sulfide minerals in the UG-2; (5) sulfide mineral chemistry and δ34S values indicate some crustal contamination of the UG-2E; and (6) sulfide mineral and secondary silicate mineral textures in both the UG-2E and UG-2 are indicative of minor, millimeter- to centimeter-scale, hydrothermal alteration. From our observations and results, we consider the UG-2E chromitite in the northern limb to be the equivalent to the UG-2 in the eastern and western limbs that has been contaminated by assimilation of Transvaal Supergroup footwall rocks during emplacement. The contamination resulted in UG-2E sulfide mineral elemental contents and platinum-group mineral types and abundances that are distinct from those of the UG-2 in the rest of the Bushveld.

An Insight to the Sedimentological Developments of Quaternary Detritus Ring Fluvial Network, Altun Kupri Paleolake, NE IRAQ

During the Quaternary, an active basin in the shape of open lake originated along the Lesser Zab river at Altun Kupri area. The radial complex of fluvial deposit morphologically initiated by the coarse detritus material, that were transported by the Lesser Zab river and other surrounded valleys in a shape of delta towards the proximal part of coastal plain and the fine sediment to the distal part of it. The coarse one prograde along the fine gradually resulting in the accumulation of about 60 m thickness of continuous Pleistocene fluvial succession mostly of coarse grained sediments with minor sand, silt and clay intervals and some tongues and bands of calcareous mud. The bulk of basin fill is made of two depositional systems, the western and southwestern side was filled up by progradation delta systems, but the northern side was gradually filled up by fluvial sediment of Lesser Zab channel. The water impounded in this lake because of Awanah anticline as a ridge in front of the lake which is open with output channel that crosses the shallow gorge and the gorge became deeper and deeper gradually till the water drooped from the lake. There are several possibilities that this ring shape depression of Altun Kupri paleolake generated, first: the depression at Altun Kupri is formed as a result of dissolving lenses of Anhydrite and gypsum of the Fat’ha Formation beneath the northern limb of Awanah Anticline after the collapse of the cavity roof. second: the presence of ring shape cliffs of about 50m thick and depression is bounded by 8km in diameter of cross bedded conglomerates and sandstone and the third: the depression of Altun Kupri paleolake can be developed by meteoritic impact, with several sedimentological and structural evidence such as a delta distributary fan, and there was a hanging terrace at a high level along the gorge

Gliding and overthrust nappe tectonics of the Barberton Greenstone Belt revisited: A review of deformation styles and processes

Interpretations of the structural/tectonic evolution of the Barberton Greenstone Belt (BGB) and its surrounding granitoid rocks remain controversial, with proponents for both horizontal thrust-accretion (plate tectonic) and partial convective overturn (vertical tectonic) models. Here, an area of complex folds that was used to support the operation of plate tectonic-derived gliding and overthrust nappe tectonics is re-investigated in detail and placed within the broader structural development of the BGB and surrounding granitoid domains via a re-analysis of structures, and geochronological, stratigraphic and metamorphic data across the whole of this important geological terrain. The results of detailed field mapping show that the complex folds, which occur on the northern limb of the 20 km wavelength, vertically plunging, Onverwacht Anticline, do not represent a re-folded, originally recumbent, isoclinal fold, as previously interpreted. Instead, the folds represent a moderately shallow east-plunging fold train that formed from a single episode of deformation. Fold asymmetry is consistent with formation during originally north-side-up reverse shear on bounding faults, consistent with the offset direction required to explain the fault-repeated slices of Mendon Formation + Fig Tree Group rocks that uniquely occur across the northern limb of the Onverwacht Anticline. More broadly, a review of the BGB and surrounding granitoid rocks show that formation was likely through two discrete, ~120 Ma long, episodes of mantle upwelling, or plume, magmatism, each of which led to crustal melting and partial convective overturn (PCO), a tectonic mechanism that arises from the gravity-driven interaction between dense, upper crustal greenstones and partially melted, more buoyant, granitoid-dominated middle crust. The first mantle upwelling episode, at 3 530 to 3 410 Ma, commenced with long-lived eruption of ultramafic-mafic lavas of the Sandspruit, Theespruit, Komati, and lower Hooggenoeg formations (3 530 to 3 470 Ma). Heat from this magmatic event gave rise to partial melting of the crust that, combined with fractionation of mafic magma chambers produced widespread felsic magmatism at 3 470 to 3 410 Ma (upper Hooggenoeg Formation and Buck Reef Chert), the latter parts of which were accompanied by the formation of D1 dome-and-keel structures via PCO in deeper-levels of the crust represented by the Stolzburg Domain in the far southwest part of the belt. The second mantle upwelling, or plume, episode commenced at 3 334 to 3 215 Ma with the eruption of ultramafic-mafic lavas of the Kromberg, Mendon and Weltevreden formations. Heat from this magmatic event gave rise to renewed partial melting of the crust that, combined with fractionation of mafic magma chambers, produced widespread felsic magmatism at 3 290 to 3 215 Ma. A second, longer-lived and more complex, multi-stage episode of PCO (D2-D4) accompanied deposition of the Fig Tree and Moodies groups from 3 250 to 3 215 Ma. Late D5 deformation accompanied emplacement of the Mpulizi and Piggs Peak batholiths at ca. 3.01 Ga, as previously identified. The Inyoka and Kromberg faults, which separate domains with distinct structural styles, represent neither terrane boundaries nor suture zones, but rather axial faults that separate deformed but generally inward-facing greenstone panels that sank inwards off rising granitoid domains that surround the BGB.

The use of high-resolution stratigraphy and derived lithoclasts to document structural inversion; a case study from the Paleogene, Isle of Wight, U.K.

The effects of structural inversion, generated by the Pyrenean Orogeny on the southerly bounding faults of the Hampshire Basin (Needles and Sandown Faults) on Eocene sedimentation in the adjacent regions were studied in outcrops by sedimentary logging, dip records and the identification of lithoclasts reworked from the crests of anticlines generated during inversion. The duration and precise age of hiatuses associated with inversion was identified using bio- and magnetostratigraphy, in comparison with the Geologic Time Scale 2020. The succession on the northern limb of the Sandown Anticline (Whitecliff Bay) includes five hiatuses of varying durations which together formed a progressive unconformity developed during the Lutetian to Priabonian interval (35-47Ma). Syn-inversion deposits thicken southwards towards the southern margin of the Hampshire Basin and are erosionally truncated by unconformities. The effects of each pulse of inversion are recorded by successively shallower dips and the age and nature of clasts reworked from the crest of the Sandown Anticline. Most individual hiatuses are interpreted as minor unconformities developed subsequent to inversion, rather than eustatically-generated sequence boundaries:transgressive surfaces. In contrast, the succession north of the Needles Fault (Alum Bay) does not contain hiatuses of magnitude or internal unconformities. In the north-west of the island, subsidiary anticlinal and synclinal structures developed in response to Eocene inversion events by the reactivation of minor basement faults. The new dates of the Eocene inversion events correspond closely with radiometric ages derived from fracture vein-fill calcites in Dorset, to the west (36-48Ma).

Introduction to the special issue on the Flatreef PGE-Ni-Cu deposit, northern limb of the Bushveld Igneous Complex

More than 30 years ago, Cox and Singer (1986) suggested that magmatic platinum-group element (PGE)-Ni-Cu deposits are amongst the best understood of ore deposits, yet the origin of PGE mineralization in the Bushveld Igneous Complex (BIC) remains controversial after a century of study. In the northern limb of the BIC, the unravelling of ore formation proved particularly difficult due to relatively poor outcrop, which is typically affected by contamination of the intruding magmas with the host rocks and expressed in the form of abundant xenoliths, footwall rafts and disturbance of magmatic stratigraphy. In this thematic issue, we present contributions on the Flatreef, a recently discovered world-class PGE-Ni-Cu deposit constituting a downdip extension of the mineralized unit of the Platreef of the northern limb. Two deep shafts are currently being sunk, making the Flatreef one of the most significant new mine development on the Bushveld in several decades.

Assessing the extent of local crust assimilation within the Flatreef, northern limb of the Bushveld Igneous Complex, using sulfur isotopes and trace element geochemistry

The proximity to metasedimentary footwall rocks relative to platinum group element (PGE) mineralized intrusive rocks in the northern limb of the Bushveld Igneous Complex (BIC) has resulted in complex local contamination in the intrusions. To assess the extent of incorporation of non-magmatic material and its effects on PGE mineralization, major element, trace element, and S isotopic data were collected from drill core UMT094 on the Turfspruit farm, where core logging has shown that the mineralized Platreef, forming the Flatreef deposit, is located stratigraphically well above local sedimentary footwall rocks. The S isotopic data combined with whole rock geochemistry data (including CaO/Al2O3, (V/Ti)PM, (Ni/Cr)PM, S/Se, loss on ignition) were used to assess incorporation of a range of local footwall material. The δ34S data show a steady decrease from the footwall assimilation zone (δ34S typically + 8 to + 9‰, maximum 12‰) to near constant δ34S values (δ34S < + 4‰) below the main PGE reef. Similar values have been documented for the Merensky Reef in the eastern and western limbs of the BIC (δ34S ~ 0 to + 3.5‰). Other geochemical parameters, such as S/Se and CaO/Al2O3, also match the ranges documented for the Merensky Reef elsewhere in the BIC. In addition, parameters such as whole rock V/Ti, normalized to primitive mantle (V/Ti)PM, are shown to be useful indicators of contamination and the type of contaminant with 1 < (V/Ti)PM < 2 for uncontaminated magmatic units; [V/Ti]pm > 2 for shale assimilation; and [V/Ti]pm < 1 for carbonate assimilation. The results suggest that the main PGE mineralization in the Flatreef deposit formed without significant in situ contamination and that the primary mechanism of PGE mineralization in the Platreef at Turfspruit was no different than the mechanism that generated the Merensky Reef in the eastern and western limbs of the BIC.

Non-Sequential Injection of PGE-rich Ultramafic Sills in the Platreef Unit at Akanani, Northern Limb of the Bushveld Complex: Evidence from Sr and Nd Isotopic Systematics

The Platreef Unit is a deceptively complex sequence of layered cumulates located in the northern limb of the 2·055 Ga-old Bushveld Complex. The unit contains the Platreef, a thick, richly mineralized stratabound PGE orebody which differs markedly from the comparatively thin, predominantly stratiform Merensky Reef found in the Upper Critical Zone of the eastern and western limbs. The Platreef Unit is interpreted as a localized facies of the Upper Critical Zone, despite layering being neither as systematic nor as clearly defined as in the equivalent stratigraphy found in the other limbs. The Platreef Unit in the Akanani project area includes well-defined layers of feldspathic harzburgite and norite, in addition to the ubiquitous feldspathic orthopyroxenite–melanorite that characterizes other sections. The paucity of floor-rock xenoliths is an additional feature. The relatively well-developed nature of the layering and paucity of xenoliths in the Platreef Unit at Akanani is explained by separation of the unit from the floor of the intrusion by a thick succession of ultramafics assigned to the Lower Critical Zone. We identify three lithological subgroups in the Platreef Unit at Akanani. They do not define an upward-younging stratigraphy. The primary stratigraphy, or PU1 subunit, is dominated by multiple layers of feldspathic orthopyroxenite, melanorite, and norite. This subunit built up from incremental addition of relatively small magma pulses. Repeated magma replenishment induced concomitant partial melting of earlier-formed layers. The PU1 subunit includes thin chromite stringers that contain Cr-spinels with unusual, amoeboidal textures consistent with several stages of growth and re-equilibration. The feldspathic harzburgite of the younger PU2 subunit was emplaced non-sequentially into the already complexly-layered PU1 subunit as a series of sinuous lenses or syn-intrusive sills. One of the PU2 sills contains the richest and most consistent of the mineralized sections at Akanani, i.e., the Main Mineralized Reef (MMR). The irregularly-developed pegmatoidal lithologies of the PU3 subunit are ascribed to recrystallization of earlier-formed cumulates (PU1 and PU2). Whole rock isotopic data for a section of the Platreef Unit, together with the overlying Lower Main Zone and underlying Lower Critical Zone, mostly from drill-hole ZF-1, demonstrate a complex pattern in both Sr87/Sr86 initial ratios and ϵNd values. These patterns are consistent with multiple lineages of parental magmas. The Lower Main Zone and the majority of the Platreef Unit are characterized by anomalously high Sr initial ratios (with a large degree of scatter) and low ϵNd values (relatively tightly constrained). Harzburgite layers from the Lower Critical Zone have a low Sr initial ratio and a relatively high ϵNd value. The new isotopic data suggest these sequences crystallized from multiple magma batches, broadly constrained within the U-type (ultramafic) and A-type (tholeiitic) lineages, derived from mantle sources and/or staging chambers which experienced varying degrees of crustal contamination. The MMR crystallized from a specific pulse of the U-type magma lineage characterized by a high Sr87/Sr86 initial ratio (average of 0·71113) and a markedly low ϵNd value (average of -11·35). The olivine-saturated magmas associated with the MMR were derived from a localized mantle source and yet underwent an unusually high degree of crustal contamination. Some layered PGE orebodies in the Bushveld Complex, including the Platreef and Merensky Reef, were emplaced as syn-magmatic sills which crystallized from anomalously PGE-rich parental magmas with an unique isotopic fingerprint.