Laser Cladding Cermet Coatings on Niobium Substrate

Pure niobium substrates were coated using laser cladding method. Pure molybdenum, Yttria Stabilized Zirkonia (YSZ) and corundum (Al2O3) powders were used as coating materials. Coatings were deposited on specimens as seperate paths with 3÷10mm width and 40mm of length. Two different laser power 3kW and 4kW were tested during deposition. In order to assess the quality of the Mo-YSZ and Mo-Al2O3 coatings, the light microscopy, Scanning Electron Microscopy (SEM), chemical analysis (EDS) and Vickers hardness test investigation were performed. The surface roughness and wear volume were also measured. As a result of YSZ-Mo powder cladding on the Nb substrate the composite layers were obtained without cracks and porosity not exceeding 1 μm. In addition, an increase in hardness of about 450 HV0.5 was revealed. As a result of Al2O3-Mo powder cladding on the Nb substrate the composite layers with many voids and cracks were obtained for each of the cladding variants.

Metal-Ceramic Beads Based on Niobium and Alumina Produced by Alginate Gelation

Full metal-ceramic composite beads containing different amounts of niobium and alumina, particularly 100 vol% alumina, 100 vol% niobium, and 95/5 vol% niobium/alumina, were produced by the alginate gelation process. The suspension for bead fabrication contained sodium alginate as gelling agent and was added dropwise into a calcium chloride solution to trigger the consolidation process. After debinding in air, sintering of the composite beads was performed under inert atmosphere. Samples in green and sintered state were analyzed by digital light microscopy and scanning electron microscopy equipped with energy dispersive X-ray spectroscopy. Investigations by mercury intrusion porosimetry revealed that pure alumina beads featured smaller pores compared to composite beads, although the open porosities were comparable. The fracture strength was evaluated on single beads. Contrary to the pure alumina, the composite beads showed a clear plastic deformation. Pure niobium beads showed a ductile behavior with very large deformations. XRD analyses revealed the presence of calcium hexaluminate and beta-alumina as minor phases in the alumina beads, while the composite ones contained about 25 wt% of impurities. The impurities comprised NbO arising from the oxidation, and β-Nb2C, from the reaction with the residual sodium alginate.

Corrosion Behavior of Niobium-Coated 316L Stainless Steels as Metal Bipolar Plates for Polymer Electrolyte Membrane Fuel Cells

Niobium was coated on 316L stainless steel by pulsed direct-current (DC) magnetron sputtering to improve corrosion behavior. The applied bias voltage highly affected the microstructure and crystallographic features, which lead to improved corrosion behavior. Due to the increased bias voltage, the microstructure of the niobium coating layer presented a smaller crystallite size and a densified structure, which obviously reduced the number of pinholes in the coated layer. Additionally, an increase in the degree of orientation toward the (110) plane, the most densely packed plane, lead to reduced dissolution of metal ions. Therefore, a pure niobium coating layer effectively protected the metal bipolar plate from a highly corrosive environment of polymer electrolyte membrane fuel cell (PEMFC) stacks. In particular, higher bias voltages of 600 and 800 V induced improved corrosion resistance, which satisfied the demand for the bipolar plate.

Considerations on the Influence of the Tool/Sheet Contact Conditions for Incremental Forming of Niobium Sheets

Niobium is a ductile transition metal of growing interest for several technological applications, thanks to its intriguing characteristics, among them high melting point, moderate density, good ductility, high corrosion resistance and superconductivity. By contrast, its use is limited by some weaknesses lied to the mechanical properties, which can undermine the quality of the surfaces worked by metal forming processes. Sheets of pure Niobium can be used for the manufacture of extremely customized components and a flexible process like the incremental sheet forming fits well with this manufacturing philosophy; in fact, this technique does not require complicated tools and/or dedicated equipment and is capable to respond quickly to the market demands. The scope of this paper is to investigate the influence of the tool/sheet contact conditions on different features like the forming loads, the surface quality and the occurrence of failures, when pure Niobium rolled sheets are formed incrementally. To this aim, the simplest variant of incremental sheet forming, namely single point incremental forming, was considered by using a common fixed end forming tool with hemispherical head. The process was carried out under dry and lubricated tool/sheet contact conditions, following the indications from a preliminary campaign of wear tests conducted by a pin-on-disk apparatus. The experimental campaign highlights the strong influence of the tool/sheet contact conditions and the importance of a correct choice of them on the features investigated, in order to limit the forming forces and the risk of failure, as well as to preserve the surface quality of the components made by incremental sheet forming of Niobium.